Preface to the special issue “Strategic applications of real-time risk mitigation strategies and tools: case studies and lessons learned in REAKT”     

Carlo Cauzzi  Paolo Gasparini  Stefan Wiemer  Jochen Zschau 《Bulletin of Earthquake Engineering》2016,14(9):2437-2439

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Modeling the Permeability Loss of Metallic Iron Water Filtration Systems     

Sabine Caré  Richard Crane  Paolo S. Calabrò  Antoine Ghauch  Emile Temgoua  Chicgoua Noubactep 《洁净——土壤、空气、水》2013,41(3):275-282

Over the past 30 years the literature has burgeoned with in situ approaches for groundwater remediation. Of the methods currently available, the use of metallic iron (Fe⁰) in permeable reactive barrier (PRB) systems is one of the most commonly applied. Despite such interest, an increasing amount of experimental and field observations have reported inconsistent Fe⁰ barrier operation compared to contemporary theory. In the current work, a critical review of the physical chemistry of aqueous Fe⁰ corrosion in porous media is presented. Subsequent implications for the design of Fe⁰ filtration systems are modeled. The results suggest that: (i) for the pH range of natural waters (>4.5), the high volumetric expansion of Fe⁰ during oxidation and precipitation dictates that Fe⁰ should be mixed with a non‐expansive material; (ii) naturally occurring solute precipitates have a negligible impact on permeability loss compared to Fe⁰ expansive corrosion; and (iii) the proliferation of H₂ metabolizing bacteria may contribute to alleviate permeability loss. As a consequence, it is suggested that more emphasis must be placed on future work with regard to considering the Fe⁰ PRB system as a physical (size‐exclusion) water filter device.  相似文献   

Redox-controlled iron isotope fractionation during magmatic differentiation: an example from the Red Hill intrusion, S. Tasmania   总被引：1，自引：1，他引：0  

Paolo A. Sossi  John D. Foden  Galen P. Halverson 《Contributions to Mineralogy and Petrology》2012,164(5):757-772

This study presents accurate and precise iron isotopic data for 16 co-magmatic rocks and 6 pyroxene–magnetite pairs from the classic, tholeiitic Red Hill sill in southern Tasmania. The intrusion exhibits a vertical continuum of compositions created by in situ fractional crystallisation of a single injection of magma in a closed igneous system and, as such, constitutes a natural laboratory amenable to determining the causes of Fe isotope fractionation in magmatic rocks. Early fractionation of pyroxenes and plagioclase, under conditions closed to oxygen exchange, gives rise to an iron enrichment trend and an increase in $ f_{{{\text{O}}_{2} }} $ of the melt relative to the Fayalite–Magnetite–Quartz (FMQ) buffer. Enrichment in Fe³⁺/ΣFe_melt is mirrored by δ⁵⁷Fe, where ^VIFe²⁺-bearing pyroxenes partition ⁵⁷Fe-depleted iron, defining an equilibrium pyroxene-melt fractionation factor of $ \Updelta^{57} {\text{Fe}}_{{{\text{px}} - {\text{melt}}}} \le - 0.25\,\permille \times 10^{6} /T^{2} $ . Upon magnetite saturation, the $ f_{{{\text{O}}_{2} }} $ and δ⁵⁷Fe of the melt fall, commensurate with the sequestration of the oxidised, ⁵⁷Fe-enriched iron into magnetite, quantified as $ \Updelta^{57} {\text{Fe}}_{{{\text{mtn}} - {\text{melt}}}} = + 0.20\,\permille \times 10^{6} /T^{2} $ . Pyroxene–magnetite pairs reveal an equilibrium fractionation factor of $ \Updelta^{57} {\text{Fe}}_{{{\text{mtn}} - {\text{px}}}} \approx + 0.30\,\permille $ at 900–1,000?°C. Iron isotopes in differentiated magmas suggest that they may act as an indicator of their oxidation state and tectonic setting.  相似文献   

Syn-thrust deformation across a transverse zone: the Grem–Vedra fault system (central Southern Alps, N Italy)     

Andrea Zanchi  Paolo D’Adda  Stefano Zanchetta  Fabrizio Berra 《Swiss Journal of Geoscience》2012,105(1):19-38

The lateral continuity of the E?CW trending thrust sheets developed within the Lower to Middle Triassic cover of the central Southern Alps (Orobic belt) is disturbed by the occurrence of several N?CS trending transverse zones, such as the poorly known Grem?CVedra Transverse Zone (GVTZ). The GVTZ developed during the emplacement of the up to six S-verging thrust sheets consisting of Lower to Middle Triassic units, occurring immediately south of the Orobic Anticlines. The transverse zone, active during thrust emplacement related to the early Alpine compressions which pre-date the Adamello intrusion, includes three major vertical shear zones, the Grem, Pezzel and Zuccone faults. The major structure of the transverse zone is the dextral Grem fault, forming a deep lateral ramp between thrust sheets 3 and 5. A similar evolution also occurred along the Zuccone and Pezzel faults, which show a left-lateral displacement of syn-thrust folds. The Grem fault was later reactivated as an oblique tear fault during the emplacement of the Orobic Anticlines, due to back-thrusting along out-of-sequence thrust surfaces (Clusone fault). Transpressional deformations along the fault zone are recorded by the rotation of major syn-thrust folds, which also suggest a horizontal offset close to 0.5?km. Records of the first stage of evolution of the Grem fault are better preserved along its northern segment, and structural relationships suggest that it propagated southward and downward in the growing thrust stack. The study of the meso and megascopic structures developed along the GVTZ constrains the evolution of the transverse zone, illustrating the complex deformational phenomena occurring in a transpressional regime. The GVTZ probably reflects the existence of pre-existing tectonic lineaments with a similar orientation. Evidence of pre-existing structures are not preserved in the exposed units, nevertheless the N?CS extensional fault systems that characterize the Norian to Jurassic rifting history of the Lombardian basin are valid candidates.  相似文献   

Natural and anthropogenic sources of total suspended particulate and their contribution to the formation of black crusts on building stone materials of Catania (Sicily)     

Giuseppe Montana  Luciana Randazzo  Paolo Mazzoleni 《Environmental Earth Sciences》2012,67(4):1097-1110

Blackening and disaggregation of exposed surfaces of stone monuments are well-known effects of stone decay taking place in polluted urban environments all over the world. This paper aims to assess the contribution of natural and anthropogenic sources of total suspended particulate (TSP) causing permanent damage (black crusts) to the stone monuments of Catania (Sicily), one of the most popular ??cities of art?? of southern Italy. Atmospheric pollution of Catania, a typical Mediterranean coastal town, is mainly contributed by vehicle exhaust emissions rather than industrial ones. Episodically, the city also suffers gaseous and ash emissions (plumes) from the nearby Mount Etna volcano. Thus, to discriminate between natural and anthropogenic contributions to stone decay on Catania monuments, black crusts and TSP were sampled within the urban area and subjected to specific analytical procedures (optical microscopy, X-ray powder diffraction, Fourier transformed infrared spectroscopy, scanning electron microscopy equipped with energy dispersive spectrometry, ionic chromatography and dual inlet mass spectrometry). Mineralogical, chemical and isotopic characterization of black crusts and TSP provided new insights concerning the partition of sulfate sources in this particular urban context. The influence of Mount Etna emissions on both TSP and black crusts compositions was shown. Nevertheless, the key role of anthropogenic sources in the total sulfate budget was confirmed, while sea spray and volcanic emissions were found to make subordinate contributions. Quantitative data useful for the identification of the threshold pollution levels for preventive conservation of Catania monuments were obtained.  相似文献   

Flash flood sediment transport in a steep sand-bed ephemeral stream     

Paolo BILLI 《国际泥沙研究》2011,26(2):193-209

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Predicting the equilibrium bed slope in natural streams using a stochastic model for incipient sediment motion     

Vito Ferro  Paolo Porto 《地球表面变化过程与地形》2011,36(8):1007-1022

In this paper, a method to predict the equilibrium bed slope in natural streams based on the incipient motion criterion is proposed. The method is based on the criterion suggested by Gessler to simulate the grain size distribution of the armour coat using the concept of critical shear stress of a sediment mixture. In particular, a different expression of the probability for a single particle size to be part of the armour coat is firstly proposed; then, a simple two‐steps criterion is suggested to estimate the safety factor required by the proposed approach. The method is applied in three different Italian regions (Calabria, Basilicata, and Tuscany) and required several field campaigns involving the survey of 251 stream reaches upstream of grade‐control structures. The area including five Calabrian streams is firstly used to test the suitability of the two‐steps approach. In this area, considering the detailed information about the particle size of bed material, the effect of using a simplified grain size distribution for each torrent is also checked. The method is then applied within the two additional areas (Basilicata and Tuscany) in order to check the geographic influence on the prediction of the stable longitudinal profile. A comparison between measured and estimated values of the equilibrium bed slope showed a good agreement for the Calabrian streams, where the number of the investigated stream reaches is greater, and satisfactory results for the torrents located in Basilicata and Tuscany where the field data set is more limited. The overall results encourage the extension of the proposed method to additional field data and suggest the use of this approach by hydraulic designers in order to stabilize the longitudinal profile of natural streams. Copyright © 2011 John Wiley & Sons, Ltd.  相似文献   

A parameterization of the wavelength of tidal dunes     

Paolo Blondeaux  Giovanna Vittori 《地球表面变化过程与地形》2011,36(9):1152-1161

The idealized model of Besio et al. (On the formation of sand waves and sand banks. Journal of Fluid Mechanics 2006; 557: 1–17) is used to predict the wavelength of tidal dunes (sand waves) generated by tidal currents in estuaries and shallow seas. The predictions are then analysed and a formula is proposed to estimate the wavelength of tidal dunes as a function of the parameters of the problem. The wavelength of the dunes is found to increase when the water depth is increased and/or the strength of the tidal current is decreased. On the other hand, the size of the bottom material (if medium sand is considered) and the tidal ellipticity are found to have a relatively small influence on the length of the bottom forms. The formula proposed provides results which are consistent with field observations of different authors. Copyright © 2011 John Wiley & Sons, Ltd.  相似文献   

Diagnosing vertical motion in the Equatorial Atlantic   总被引：2，自引：0，他引：2  

Hervé Giordani  Guy Caniaux 《Ocean Dynamics》2011,61(12):1995-2018

Estimating the vertical velocity (w) in the oceanic upper-layers is a key issue for understanding the cold tongue development in the Eastern Equatorial Atlantic. In this methodological paper, we develop an expanded and general formulation of the vertical velocity equation based on the primitive equation (PE) system, in order to gain new insight into the physical processes responsible for the Equatorial and Angola upwellings. This approach is more accurate for describing the real ocean than simpler considerations based on just the wind-driven patterns of surface layer divergence. The w-sources/forcings are derived from the PE w-equation and diagnosed from a realistic ocean simulation of the Equatorial Atlantic. Sources of w are numerous and express the high complexity of terms related to the turbulent momentum flux, to the circulation and to the mass fields, some of them depending explicitly on w and others not. The equatorial upwelling is found to be mainly induced by the (i) the zonal turbulent momentum flux, (ii) the curl of turbulent momentum flux and (iii) the imbalance between the circulation and the pressure fields. The Angola upwelling in the eastern part of the basin is controlled by strong curl of turbulent momentum flux. A strong cross-regulation is evidenced between the w-forcings independent of w and dependent on w, which suggests an equatorial balanced-dynamics. The w-forcing depending on w represents the negative feedback of the ocean to the w-forcing independent of w: in the equatorial band, this adjustment is led by non-linear processes and by vortex stretching outside.  相似文献   

Introspection on improper seismic retrofit of Basilica Santa Maria di Collemaggio after 2009 Italian earthquake     

Gian Paolo Cimellaro  Andrei M. Reinhorn  Alessandro De Stefano 《地震工程与工程振动(英文版)》2011,10(1):153-161

The 2009 L’Aquila, Italy earthquake highlighted the seismic vulnerability of historic masonry building structures due to improper "strengthening" retrofit work that has been done in the last 50 years. Italian seismic standards recommend the use of traditional reinforcement techniques such as replacing the original wooden roof structure with new reinforced concrete (RC) or steel elements, inserting RC tie-beams in the masonry and new RC floors, and using RC jacketing on the shear walls. The L’Aquila earthquake revealed the numerous limitations of these interventions, because they led to increased seismic forces (due to greater additional weight) and to deformation incompatibilities of the incorporated elements with the existing masonry walls. This paper provides a discussion of technical issues pertaining to the seismic retrofit of the Santa Maria di Collemaggio Basilica and in particular, the limitations of the last (2000) retrofit intervention. Considerable damage was caused to the church because of questionable actions and incorrect and improper technical choices.  相似文献