Multi-metal contaminant dynamics in temporarily flooded soil under sulfate limitation   总被引：3，自引：0，他引：3  

Frank-Andreas Weber  Andreas Voegelin  Ruben Kretzschmar 《Geochimica et cosmochimica acta》2009,73(19):5513-5527

In many river basins, floodplain soils have accumulated a variety of metal contaminants, which might be released during periods of flooding. We investigated the dynamics of copper, cadmium, lead, zinc, and nickel in a contaminated freshwater floodplain soil under a realistic sulfate-limited flooding regime in microcosm experiments. We found that most contaminants were initially mobilized by processes driven by the reductive dissolution of Fe(III) and Mn(IV, III) (hydr)oxides. Subsequently, bacterial sulfate respiration resulted in the transformation of the entire available sulfate (2.3 mmol/kg) into chromous reducible sulfur (CRS). Cu K-edge X-ray absorption fine structure (XAFS) spectroscopy revealed that the soil Cu speciation changed from predominantly Cu(II) bound to soil organic matter (SOM) intermittently to 14% metallic Cu(0) and subsequently to 66% copper sulfide (Cu_xS). These Cu_xS precipitates accounted for most of the formed CRS, suggesting that Cu_xS was the dominant sulfide phase formed in the flooded soil. Sequential metal extractions, in agreement with CRS results, suggested that easily mobilizable Cd was completely and Pb partially sequestered in sulfide precipitates, controlling their dissolved concentrations to below detection limits. In contrast, Zn and Ni (as well as Fe) were hardly sequestered into sulfide phases, so that micromolar levels of dissolved Zn and Ni (and millimolar dissolved Fe(II)) persisted in the reduced soil. The finding that Cu, Cd, and Pb were sequestered (but hardly any Zn, Ni, and Fe) is consistent with the thermodynamically predicted sulfide ladder following the increasing solubility products of the respective metal sulfides. The observation that Cd and Pb were sequestered in sulfides despite the presence of remaining SOM-bound Cu(II) suggested that the kinetics of Cu(II) desorption, diffusion, and/or Cu_xS precipitation interfered with the sulfide ladder. We conclude that the dynamics of multiple metal contaminants are intimately coupled under sulfate limitation by the relative thermodynamic stabilities and formation kinetics of the respective metal sulfides.  相似文献   

New insights into the origin of perylene in geological samples   总被引：1，自引：0，他引：1  

Kliti Grice  Hong Lu  Pia Atahan  Muhammad Asif  Paul Greenwood  Ercin Maslen  Kenneth Williford 《Geochimica et cosmochimica acta》2009,73(21):6531-6543

The origin of the polycyclic aromatic hydrocarbon (PAH) perylene in sediments and petroleum has been a matter of continued debate. Reported to occur in Phanerozoic organic matter (OM), fossil crinoids and tropical termite mounds, its mechanism of formation remains unclear. While a combustion source can be excluded, structural similarities to perylene quinone-like components present in e.g. fungi, plants, crinoids and insects, potentially suggest a product-precursor relationship. Here, we report perylene concentrations, ¹³C/¹²C, and D/H ratios from a Holocene sediment profile from the Qingpu trench, Yangtze Delta region, China. Perylene concentrations differ from those of pyrogenic PAHs, and rise to prominence in a stratigraphic interval that was dominated by woody vegetation as determined by palynology including fungal spores. In this zone, perylene concentrations exhibit an inverse relationship to the lignin marker guaiacol, D/H ratios between −284‰ and −317‰, similar to the methoxy groups in lignin, as well as co-variation with spores from wood-degrading fungi. ¹³C/¹²C of perylene differs from that of land plant wax alkanes and falls in the fractionation range expected for saprophytic fungi that utilise lignin, which is isotopically lighter than cellulose and whole wood. During progressive lignin degradation, the relative carbon isotopic ratio of the perylene decreases. We therefore hypothesise a relationship of perylene to the activity of wood-degrading fungi. To support our hypothesis, we analysed a wide range of Phanerozoic sediments and oils, and found perylene to generally be present in subordinate amounts before the evolutionary rise of vascular plants, and to be generally absent from marine-sourced oils, few exceptions being attributed perhaps to a contribution of marine and/or terrestrial-derived fungi, anoxia (especially under marine conditions) and/or contamination of core material by fungi. A series of low-molecular-weight aromatic quinones bearing the perylene-backbone were detected in Devonian and Cretaceous sediments, potentially representing precursor components to perylene.  相似文献   

Clay minerals from the sedimentary cover from the Northwest Iberian shelf     

A. Oliveira  F. Rocha  A. Rodrigues  J. Jouanneau  A. Dias  O. Weber  C. Gomes 《Progress in Oceanography》2002,52(2-4)

The Northern Iberian margin is a typical example of a continental margin subjected to seasonal highly energetic regime (waves and tides) and receiving inputs of continental sediments via riverine discharges. The principal goal of this study has been to use clay minerals as indicators of sedimentary dynamics in the open shelf system. The distributions of clay mineral in the top layer of the sedimentary cover are shown to be related to their continental sources, but also reflect the influences of winter storms and longshore currents in determining the pathways of sediment transport.The mineralogical composition of the material issuing from the rivers is very similar to the general mineralogical composition of the fine fractions of the seabed sediments. Those deposits that are directly influenced by riverine discharges have higher contents of kaolinite (>20%), whereas those that are not have higher contents of illite (>80%). The available data indicate no significant quantities of terrigenous particles are being discharged from the Spanish rias. Therefore, we conclude that physical processes are controlling the clay mineral distributions and that, despite contributions from the Minho River, the main source of fine detrital particles to the shelf region is the Douro River discharge. These particles settle on the middle shelf, below the 60 m isobath. During storm events these particles are re-suspended and advected northwards to the Galician shelf or into deeper domains. Thus the distributions of the clays indicate there is a net transport of fine sediments both northwards and off-shelf.  相似文献   

Correlation Between the Sunspot Number,the Total Solar Irradiance,and the Terrestrial Insolation     

A. Hempelmann  W. Weber 《Solar physics》2012,277(2):417-430

Our study deals with the correlations between the solar activity on the one hand and the solar irradiance above the Earth’s atmosphere and at ground level on the other. We analyzed the combined ACRIM I+II time series of the total solar irradiance (TSI), the Mauna Loa time series of terrestrial insolation data, and data of terrestrial cosmic ray fluxes. We find that the correlation between the TSI and the sunspot number is strongly non-linear. We interpret this as the net balance between brightening by faculae and darkening by sunspots where faculae dominate at low activity and sunspots dominate at high activity. Such a behavior is hitherto known from stellar analogs of the Sun in a statistical manner. We perform the same analysis for the Mauna Loa data of terrestrial insolation. Here we find that the linear relation between sunspot number and insolation shows more than 1% rise in insolation by sunspot number variations which is much stronger than for the TSI. Our conclusion is that the Earth atmosphere acts as an amplifier between space and ground, and that the amplification is probably controlled by solar activity. We suspect the cosmic rays intensity as the link between solar activity and atmospheric transparency. A Fourier analysis of the time series of insolation shows three dominant peaks: 10.5, 20.4, and 14.0 years. As a matter of fact, the cosmic rays data show the same pattern of significant peaks: 10.7, 22.4, and 14.9 years. This analogy supports our idea that the cosmic rays variation has influence on the transparency of the Earth atmosphere.  相似文献   

Die Protoblastese     

Maximilian Weber 《International Journal of Earth Sciences》1924,14(4):337-351

Ohne Zusammenfassung  相似文献   

Macroseepage of methane and light alkanes at the La Brea tar pits in Los Angeles     

Derek?Weber  Bertha?A.?Marquez  Charnise?Taylor  Paul?Raya  Paul?Contreras  David?Howard  Ikenna?Nwachuku  Katie?Fusco  Fernanda?Morales  Lambert?A.?DoezemaEmail author 《Journal of Atmospheric Chemistry》2017,74(3):339-356

Geologic seepage of methane and light (C₂-C₅) alkanes was measured at the La Brea Tar Pits in Los Angeles. Samples were collected using flux chambers with stainless steel canisters and analyzed using gas chromatography. Average seepage rates from individual seepage sites were 970 ± 330 mg/h of methane, 14.0 ± 5.5 mg/h of ethane, 9.1 ± 3.7 mg/h of propane, 3.7 ± 1.6 mg/h of i-butane, 0.33 ± 0.16 mg/h of n-butane, 260 ± 120 μg/h of i-pentane, and 5.3 ± 1.9 μg/h of n-pentane, while maximum seepage rates exceeded 17 g/h of methane, 270 mg/h of ethane, 190 mg/h of propane, 95 mg/h of i-butane, 10 mg/h of n-butane, 7 mg/h of i-pentane, and 0.1 mg/h of n-pentane. These absolute fluxes have an additional unknown amount of error associated with them due to sampling methodology, and should be taken as the lower limit of emissions. Samples collected revealed generally dry gas, with high methane emissions relative to the light alkanes. Overall emissions from the tar pits were found to come not only from the active geologic seepage, but also from the outgassing of the standing asphalt at the site. Using the gas ratios, which are negligibly affected by errors introduced by sampling methodology, observed in this study, daily emissions of C₂ – C₅ alkanes from the La Brea area were estimated to be 4.7 ± 1.6 Mg, which represents 2–3 % of total emissions in the entire Los Angeles region.  相似文献   

Remarks on the Definition and Estimation of Friction Velocity   总被引：3，自引：1，他引：2  

Rudolf O. Weber 《Boundary-Layer Meteorology》1999,93(2):197-209

One of the mainscaling parameters in similarity theory of the atmospheric boundary layer is friction velocity. Unfortunately, several definitions of friction velocity exist in the literature. Some authors use the component of the horizontal Reynolds stress vector in the direction of the mean wind vector to define friction velocity. Others define the friction velocity by means of the absolute value of the horizontal Reynolds stress vector. The two definitions coincide only if the direction of the mean wind vector is parallel to the horizontal Reynolds stress vector. In general, the second definition gives larger values for the friction velocity. Over complex terrain the situation is further complicated by the fact that the terrain following flow is not necessarily horizontal. Thus, several authors have proposed to use terrain following coordinate systems for the definition of friction velocity. By means of a large dataset of fast-response wind measurements with an ultrasonic anemometer the friction velocities resulting from the different definitions are compared. Furthermore, it is shown that friction velocity can be well estimated from horizontal wind speed, and even better from simple horizontal or vertical turbulence parameters.  相似文献   

The behavior of total lightning activity in severe Florida thunderstorms     

Earle Williams  Bob Boldi  Anne Matlin  Mark Weber  Steve Hodanish  Dave Sharp  Steve Goodman  Ravi Raghavan  Dennis Buechler 《Atmospheric Research》1999,51(3-4)

The development of a new observational system called LISDAD (Lightning Imaging Sensor Demonstration and Display) has enabled a study of severe weather in central Florida. The total flash rates for storms verified to be severe are found to exceed 60 fpm, with some values reaching 500 fpm. Similar to earlier results for thunderstorm microbursts, the peak flash rate precedes the severe weather at the ground by 5–20 min. A distinguishing feature of severe storms is the presence of lightning ‘jumps' — abrupt increases in flash rate in advance of the maximum rate for the storm. The systematic total lightning precursor to severe weather of all kinds — wind, hail, tornadoes — is interpreted in terms of the updraft that sows the seeds aloft for severe weather at the surface and simultaneously stimulates the ice microphysics that drives the intracloud lightning activity.  相似文献   

Hierarchically nested river landform sequences. Part 2: Bankfull channel morphodynamics governed by valley nesting structure          下载免费PDF全文

Gregory B. Pasternack  Dastagir Baig  Matthew D. Weber  Rocko A. Brown 《地球表面变化过程与地形》2018,43(12):2519-2532

River corridors exhibit landforms nested within landforms repeatedly down spatial scales. In Pasternack et al. ( 2018 ), a new, scale‐independent, hierarchical river classification was developed that uses five landform types to map the domains of a single fluvial process – flow convergence routing – at each of three–five spatial scales. Given those methods, this study investigated the details of how flow convergence routing organizes nested landform sequences. The method involved analyzing landform abundance, sequencing, and hierarchical nesting along the 35 km gravel/cobble lower Yuba River in California. Independent testing of flow convergence routing found that hydraulic patterns at every flow matched the essential predictions from classification, substantiating the process–morphology link. River width and bed elevation sequences exhibit large, nonrandom, and linked oscillations structured to preferentially yield wide bars and constricted pools at base flow and bankfull flow. At a flow of 8.44 times bankfull, there is still an abundance of wide bar and constricted pool landforms, but larger topographic drivers also yield an abundance of nozzle and oversized landforms. The nested structure of flow convergence routing landforms reveals that base flow and bankfull landforms are nested together within specific floodprone valley landform types, and these landform types control channel morphodynamics during moderate to large floods. As a result, this study calls into question the prevailing theory that the bankfull channel of a gravel/cobble river is controlled by in‐channel, bankfull, and/or small flood flows. Such flows may initiate sediment transport, but they are too small to control landform organization in a gravel/cobble river with topographic complexity. Copyright © 2018 John Wiley & Sons, Ltd.  相似文献   

Deriving fragility functions from bilinearized capacity curves for earthquake scenario modelling using the conditional spectrum     

Clotaire Michel  Helen Crowley  Pia Hannewald  Pierino Lestuzzi  Donat Fäh 《Bulletin of Earthquake Engineering》2018,16(10):4639-4660

The development of fragility curves to perform seismic scenario-based risk assessment requires a fully probabilistic procedure in order to account for uncertainties at each step of the computation. This is especially true when developing fragility curves conditional on an Intensity Measure that is directly available from a ground-motion prediction equation. In this study, we propose a new derivation method that uses realistic spectra instead of design spectral shapes or uniform hazard spectra and allows one to easily account for the features of the site-specific hazard that influences the fragility, without using non-linear dynamic analysis. The proposed method has been applied to typical school building types in the city of Basel (Switzerland) and the results have been compared to the standard practice in Europe. The results confirm that fragility curves are scenario dependent and are particularly sensitive to the magnitude of the earthquake scenario. The same background theory used for the derivation of the fragility curves has allowed an innovative method to be proposed for the conversion of fragility curves to a common IM (i.e. spectral acceleration or PGA). This conversion is the only way direct comparisons of fragility curves can be made and is useful when inter-period correlation cannot be used in scenario loss assessment. Moreover, such conversion is necessary to compare and verify newly developed curves against those from previous studies. Conversion to macroseismic intensity is also relevant for the comparison between mechanical-based and empirical fragility curves, in order to detect possible biases.  相似文献