Estimating a Lagrangian Length Scale Using Measurements of CO2 in a Plant Canopy     

Shannon E. Brown  Jon S. Warland  Eduardo A. Santos  Claudia Wagner-Riddle  Ralf Staebler  Meaghan Wilton 《Boundary-Layer Meteorology》2013,147(1):83-102

Analytical Lagrangian equations capable of predicting concentration profiles from known source distributions offer the opportunity to calculate source/sink distributions through inverted forms of these equations. Inverse analytical Lagrangian equations provide a practical means of estimating source profiles using concentration and turbulence measurements. Uncertainty concerning estimates of the essentially immeasurable Lagrangian length scale ( ${\mathcal{L}}$ ), a key input, impedes the operational practicality of this method. The present study evaluates ${\mathcal{L}}$ within a corn canopy by using field measurements to constrain an analytical Lagrangian equation. Measurements of net CO₂ flux, soil-to-atmosphere CO₂ flux, and in-canopy profiles of CO₂ concentration provided the information required to solve for ${\mathcal{L}}$ in a global optimization algorithm for 30-min time intervals. For days when the canopy was a strong CO₂ sink, the optimization frequently located ${\mathcal{L}}$ profiles that follow a convex shape. A constrained optimization then fit the profile shape to a smooth sigmoidal equation. Inputting the optimized ${\mathcal{L}}$ profiles in the forward and inverse Lagrangian equations leads to strong correlations between measured and calculated concentrations and fluxes. Coefficients of the sigmoidal equation were specific to each 30-min period and did not scale with any measured variable. Plausible looking ${\mathcal{L}}$ profiles were associated with negative bulk Richardson number values. Once the canopy senesced, a simple eddy diffusivity profile sufficed to relate concentrations and sources in the analytical Lagrangian equations.  相似文献   

Geochemical studies of impact breccias and country rocks from the El'gygytgyn impact structure,Russia          下载免费PDF全文

Ulli Raschke  Ralf Thomas Schmitt  Iain McDonald  Wolf Uwe Reimold  Dieter Mader  Christian Koeberl 《Meteoritics & planetary science》2015,50(6):1071-1088

The complex impact structure El'gygytgyn (age 3.6 Ma, diameter 18 km) in northeastern Russia was formed in ~88 Ma old volcanic target rocks of the Ochotsk‐Chukotsky Volcanic Belt (OCVB). In 2009, El'gygytgyn was the target of a drilling project of the International Continental Scientific Drilling Program (ICDP), and in summer 2011 it was investigated further by a Russian–German expedition. Drill core material and surface samples, including volcanic target rocks and impactites, have been investigated by various geochemical techniques in order to improve the record of trace element characteristics for these lithologies and to attempt to detect and constrain a possible meteoritic component. The bedrock units of the ICDP drill core reflect the felsic volcanics that are predominant in the crater vicinity. The overlying suevites comprise a mixture of all currently known target lithologies, dominated by felsic rocks but lacking a discernable meteoritic component based on platinum group element abundances. The reworked suevite, directly overlain by lake sediments, is not only comparatively enriched in shocked minerals and impact glass spherules, but also contains the highest concentrations of Os, Ir, Ru, and Rh compared to other El'gygytgyn impactites. This is—to a lesser extent—the result of admixture of a mafic component, but more likely the signature of a chondritic meteoritic component. However, the highly siderophile element contribution from target material akin to the mafic blocks of the ICDP drill core to the impactites remains poorly constrained.  相似文献   

The behavior of Mg, Fe, and Ni during the replacement of olivine by orthopyroxene: experiments relevant to mantle metasomatism     

Ralf Milke  Rainer Abart  Lukas Keller  Dieter Rhede 《Mineralogy and Petrology》2011,103(1-4):1-8

Replacement of olivine by orthopyroxene is a frequently observed phenomenon in mantle metasomatism. In order to study element redistribution in SiO₂ metasomatism we synthesised orthopyroxene reaction rims at the contacts between forsterite-rich olivine and quartz. The orthopyroxene rims grew from the original quartz-olivine interface into both directions implying counterdiffusion of iron/magnesium and silicon. Following local equilibrium partitioning the X_Fe is lower in the orthopyroxene than in the reactant olivine at the olivine-orthopyroxene replacement front. The resulting local iron excess is compensated by formation of orthopyroxene with a higher X_Fe at the quartz-orthopyroxene interface, which is out of equilibrium with the reactant olivine. This is facilitated through short circuit diffusion along grain boundaries within the orthopyroxene rim. Due to the low capacity of orthopyroxene to accommodate Ni, this component is forced to diffuse back into the olivine producing a Ni enriched zone ahead of the replacement front. This leads to Ni contents in the orthopyroxene rim, which are higher than what is expected in equilibrium with the unaltered olivine. Taking quartz as a proxy for a silica rich fluid or liquid metasomatising agent, we conclude that the overall element fractionation between olivine and the silica rich phase may deviate from equilibrium partitioning so that the Fe and Ni concentrations in the orthopyroxene which is in contact with quartz are higher than in equilibrium with the reactant olivine. This indicates that kinetic fractionation is important for the chemical evolution of both the mantle rocks and the metasomatising agents.  相似文献   

Clump lifetimes and the initial mass function     

Paul C. Clark  Ralf S. Klessen  Ian A. Bonnell 《Monthly notices of the Royal Astronomical Society》2007,379(1):57-62

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Collisional processes at the junction of the Aleutian–Kamchatka arcs: new evidence from fission track analysis and field observations     

Ralf Freitag  Christoph Gaedicke  Boris Baranov  & Nikolay Tsukanov 《地学学报》2001,13(6):433-442

The Aleutian island arc collides with the Kuril–Kamchatka arc in the area of the Cape Kamchatka peninsula. Field studies of neotectonic structures and apatite fission track analysis provide evidence for crustal plate shortening onshore the Cape Kamchatka peninsula. Tectonic blocks show differential mean exhumation rates varying from 0.18 ± 0.04 mm yr⁻¹ in the north up to 1.2 ± 0.18 mm yr⁻¹ in the south of the peninsula. A few of the fission track length data point to an unsteady exhumation rate. The blocks are separated by major dextral fault zones splaying off from Aleutian island arc fault zones. Across the western segment of the North American–Pacific Plate boundary the strain is partitioned along the fault zones and increases from north to south. Results from this study suggest that indentation and accretion of island arc fragments has recently occurred in the southeastern part of the Cape Kamchatka peninsula.  相似文献   

Use of four-dimensional ground penetrating radar and advanced visualization methods to determine subsurface fluid migration     

Ralf Birken  Roelof Versteeg 《Journal of Applied Geophysics》2000,43(2-4)

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Carbonatite melt inclusions in coexisting magnetite,apatite and monticellite in Kerimasi calciocarbonatite,Tanzania: melt evolution and petrogenesis   总被引：1，自引：0，他引：1  

Tibor Guzmics  Roger H. Mitchell  Csaba Szabó  Márta Berkesi  Ralf Milke  Rainer Abart 《Contributions to Mineralogy and Petrology》2011,161(2):177-196

Kerimasi calciocarbonatite consists principally of calcite together with lesser apatite, magnetite, and monticellite. Calcite hosts fluid and S-bearing Na–K–Ca-carbonate inclusions. Carbonatite melt and fluid inclusions occur in apatite and magnetite, and silicate melt inclusions in magnetite. This study presents statistically significant compositional data for quenched S- and P-bearing, Ca-alkali-rich carbonatite melt inclusions in magnetite and apatite. Magnetite-hosted silicate melts are peralkaline with normative sodium-metasilicate. On the basis of our microthermometric results on apatite-hosted melt inclusions and forsterite–monticellite phase relationships, temperatures of the early stage of magma evolution are estimated to be 900–1,000°C. At this time three immiscible liquid phases coexisted: (1) a Ca-rich, P-, S- and alkali-bearing carbonatite melt, (2) a Mg- and Fe-rich, peralkaline silicate melt, and (3) a C–O–H–S-alkali fluid. During the development of coexisting carbonatite and silicate melts, the Si/Al and Mg/Fe ratio of the silicate melt decreased with contemporaneous increase in alkalis due to olivine fractionation, whereas the alkali content of the carbonatite melt increased with concomitant decrease in CaO resulting from calcite fractionation. Overall the peralkalinity of the bulk composition of the immiscible melts increased, resulting in a decrease in the size of the miscibility gap in the pseudoquaternary system studied. Inclusion data indicate the formation of a carbonatite magma that is extremely enriched in alkalis with a composition similar to that of Oldoinyo Lengai natrocarbonatite. In contrast to the bulk compositions of calciocarbonatite rocks, the melt inclusions investigated contain significant amount of alkalis (Na₂O + K₂O) that is at least 5–10 wt%. The compositions of carbonatite melt inclusions are considered as being better representatives of parental magma composition than those of any bulk rock.  相似文献   

Petroleum source rocks of the Tarfaya Basin and adjacent areas, Morocco     

Victoria F. Sachse  Ralf Littke  Sabine Heim  Oliver Kluth  Jürgen Schober  Lahcen Boutib  Haddou Jabour  Ferdinand Perssen  Sven Sindern 《Organic Geochemistry》2011,42(3):209-227

This work characterizes the source rock potential of the Tarfaya Basin and enabled us to reconstruct its geochemical history. Outcrop samples covering different stratigraphic intervals, plus the northwestern part of the Zag/Tindouf Basin (Bas Draa area), were analyzed for total organic carbon (C_org) and total inorganic carbon contents and total sulfur content. Rock-Eval analysis and vitrinite reflectance measurements were performed on 56 samples chosen on the basis C_org content. A set of 45 samples were extracted and non-aromatic hydrocarbons were analyzed by way of gas chromatography-flame ionization detection (GC-FID) and GC-mass spectrometry (GC-MS). Non-isothermal open system pyrolysis at different heating rates was applied to obtain kinetic parameters for modelling petroleum generation from four different source rocks.High quality petroleum source rocks with high C_org content and hydrogen index (HI) values were found for samples of Eocene, Coniacian, Turonian and Cenomanian age. Most samples were carbonate rich and organic/sulfur values were high to moderate. Various maturity parameters indicated immature or possibly early mature organic matter. Based on organic geochemical and petrological data, the organic matter is of marine/aquatic origin (Cenomanian) or a mixture of aquatic and terrigenous material (Eocene). The Early Cretaceous interval did not contain high quality source rocks, but indications of petroleum impregnation were found.  相似文献   

Comparison of precipitation in the regional climate model BALTIMOS to radar observations     

Andi Walther  Marc Schröder  Jürgen Fischer  Ralf Bennartz 《Theoretical and Applied Climatology》2014,118(4):627-640

Observational data and simulations of the regional climate system Baltic integrated model system (BALTIMOS) were used to study precipitation in the Baltic Sea and its drainage basin with a special focus on the diurnal cycle. The study includes a general evaluation of BALTIMOS precipitation, showing that BALTIMOS has too many light rain events causing an overestimation of the total annual precipitation amount. The diurnal cycle as well as its spatial distribution was analysed. BALTIMOS captures the broad characteristics: a significant diurnal variability with an afternoon peak above land and weak variability with a nocturnal peak above sea. An algorithm to distinguish between frontal and convective precipitation was applied to examine the diurnal cycle more thoroughly. The local solar time of maximum rain in summer is about 1 to 2 h earlier in BALTIMOS than in radar observations of precipitation.  相似文献   

HydrIS: An open source GIS decision support system for groundwater management (Morocco)     

Hassane Jarar Oulidi  Ralf Löwner  Lahcen Benaabidate  Joachim Wächter 《地球空间信息科学学报》2013,16(3):212-216

A regional groundwater management system has been elaborated, integrating Relational Database Management System (RDBMS) and various web services. It consists of web geospatial application so-called HydrIS (Hydrogeological Information System) based on Open Source components and technologies, leading to a feasible and low-cost solution. Therefore, HydrIS permits delivery of data from a number of heterogeneous sources to standards supported by the Open Geospatial Consortium (OGC). The protocols used for exchanging data are also derived from OGC standards, i.e., WMS (Web Mapping Service), WFS (Web Feature Service), and WCS (Web Coverage Service). Finally, a geoportal was developed, which consists of client-applications that communicate with different Web Services (WMS, WCS, and WFS) through http-requests.  相似文献