Simultaneous Determination of Total Carbon, Nitrogen, Hydrogen and Sulfur in Twenty-seven Geological Reference Materials by Elemental Analyser     

Ran Kubota 《Geostandards and Geoanalytical Research》2009,33(2):271-283

The contents of total carbon, hydrogen, nitrogen and sulfur in twenty-seven geological reference materials, issued by five producer organisations (USGS, CCRMP, ANRT, NIST and GSJ) were determined using an automated simultaneous elemental analyser following combustion. In order to complete gasification of C and N in some geological materials, the combustion temperature needed to be greater than 1150 °C. The calibrator prepared from known amounts of reagent material was not adopted for more than 1.2% m/m of H. Unrealistically high values in certain materials supposed to contain less than 1000 μg g⁻¹ S may be due mainly to memory effects. The limit of detection was 50 μg g⁻¹ for C and N, 500 μg g⁻¹ for H and 1000 μg g⁻¹ for S. Although the blank value of C and N was always stable and less than one third of the detection limit, it had a slightly higher value for N and S. By repeating long-term analysis, high reproducibility for each of the four elements was verified. The method has been applied satisfactorily to a variety of geological reference materials, and recommended values for C, H and N for most of the reference materials studied have been tabulated.  相似文献   

Reconstructions of annual discharge and equilibrium line altitude of glaciers at Qilian Shan,northwest China,from 1978 to 2002     

Akiko Sakai  Koji Fujita  Chiyuki Narama  Jumpei Kubota  Masayoshi Nakawo  Tandong Yao 《水文研究》2010,24(19):2798-2806

Discharge was calculated from a mountainous area, including discharge from glaciers, in the Qilian Shan (Qilian Mountains) of northwest China. The studied Yingluoxia basin is 9983 km² in area, with glaciers making up 0·3% of the basin. The calculation method was based on the heat balance, requiring only daily temperature and precipitation. Calculated annual discharge from the basin corresponded well with the observed data. Calculated annual discharge from glaciers was 3·6% of the total discharge from the basin. The temporal trend of the calculated equilibrium line altitude (ELA) at the July 1st Glacier (western side of the Yingluoxia basin) was similar to that of the observed ELA. The calculated annual mass balance of glaciers within the Yingluoxia basin has a larger negative value than the other glaciers in China, as the ratio of accumulation area to the total glacier area in the Yingluoxia basin is much lower than in neighbouring basins to the west. Copyright © 2010 John Wiley & Sons, Ltd.  相似文献   

A statistical method to get surface level air-temperature from satellite observations of precipitable water     

Pankajakshan Thadathil  Akira Shikauchi  Yasuhiro Sugimori  Masahisa Kubota 《Journal of Oceanography》1993,49(5):551-558

Ten-day mean surface level air-temperature from SSMI precipitable water (SSMI-T _a ) has been derived and compared with the temperature from two ocean data buoys (Buoy-T _a ) of Japan Meteorological Agency (JMA) for a period of six months (July–December, 1988). Statistical relations between air-temperature and mixing ratio, using data from ocean data buoys are used to derive air-temperature from mixing ratio, obtained from SSMI precipitable water. For getting the mixing ratio from precipitable water, regional mixing ratio-precipitable water relations have been used, instead of global relation proposed by Liu (1986). The rms errors (standard deviation of the difference between SSMI-T _a and Buoy-T _a ) for two buoy locations are found to be 1.15 and 1.12°C, respectively. Surface level temperature for the two buoy locations are also derived using direct regression relation between Buoy-T _a and precipitable water. The rms errors of the SSMI-T _a , in this case are found to be reduced to 1.0°C.  相似文献   

Global mapping of the degree of space weathering on asteroid 25143 Itokawa by Hayabusa/AMICA observations     

Masateru Ishiguro  Takahiro Hiroi  David J. Tholen  Sho Sasaki  Yuji Ueda  Tokuhiro Nimura  Masanao Abe  Beth E. Clark  Aya Yamamoto  Fumi Yoshida  Ryosuke Nakamura  Naru Hirata  Hideaki Miyamoto  Yasuhiro Yokota  Tatsuaki Hashimoto  Takashi Kubota  Akiko M. Nakamura  Robert W. Gaskell  Jun Saito 《Meteoritics & planetary science》2007,42(10):1791-1800

Abstract— We obtained color images of near‐Earth asteroid 25143 Itokawa by the Hayabusa multiband imaging camera to characterize the regional color properties. Images were obtained for the whole disk from the gate position (GP) and home position (HP) at a spatial resolution of 0.8–3.7 m/pixel. Whole‐disk spectra are adjusted to the telescopic data obtained by the University of Hawai'i's 88‐inch telescope using the Eight Color Asteroid Survey (ECAS) system. The disk‐resolved measurements show large variations in the three visible channels. We present a map of an index related to the degree of space weathering, which has been newly developed based on laboratory measurements. We find large variations in the degree of space weathering on Itokawa. Fresh materials are observed in regions of steep slopes and craters, whereas mature materials are ubiquitously distributed. This result suggests that pristine ordinary chondrite‐like materials have been exposed through weathered layers by excavation. By also examining close‐up images obtained during touchdown rehearsal, we find that most rocks in Itokawa's rough terrains are weathered. Instead of a regolith blanket, the surface of this small asteroid is covered with weathered rocks and gravels.  相似文献   

Trace elements and stable isotope ratios (δC and δN) in fish from deep-waters of the Sulu Sea and the Celebes Sea     

Kwadwo Ansong Asante  Tetsuro Agusa  Reiji Kubota  Hiroko Mochizuki  Shuhei Nishida  Suguru Ohta  Annamalai Subramanian 《Marine pollution bulletin》2010,60(9):1560-1570

Trace elements (TEs) and stable isotope ratios (δ¹⁵N and δ¹³C) were analyzed in fish from deep-water of the Sulu Sea, the Celebes Sea and the Philippine Sea. Concentrations of V and Pb in pelagic fish from the Sulu Sea were higher than those from the Celebes Sea, whereas the opposite trend was observed for δ¹³C. High concentrations of Zn, Cu and Ag were found in non-migrant fish in deep-water, while Rb level was high in fish which migrate up to the epipelagic zone, probably resulting from differences in background levels of these TEs in each water environment or function of adaptation to deep-water by migrant and non-migrant species. Arsenic level in the Sulu Sea fish was positively correlated with δ¹⁵N, indicating biomagnification of arsenic. To our knowledge, this is the first study on relationship between diel vertical migration and TE accumulation in deep-water fish.  相似文献   

Chemical speciation of arsenic in the livers of higher trophic marine animals     

Kubota R  Kunito T  Tanabe S 《Marine pollution bulletin》2002,45(1-12):218-223

Concentrations of total arsenic and individual arsenic compounds were determined in livers of cetaceans (Dall's porpoise and short-finned pilot whale), pinnipeds (harp and ringed seals), sirenian (dugong), and sea turtles (green and loggerhead turtles) to characterize arsenic accumulation profiles in higher trophic marine animals. Hepatic arsenic concentrations in sea turtles were highest among the species examined. Chemical speciation of arsenic revealed that arsenobetaine was the major arsenic compound in almost all the species. In contrast, arsenobetaine was a minor constituent in dugong. Dimethylarsinic acid, methylarsonic acid, arsenocholine, tetramethylarsonium ion, arsenite, and an unidentified arsenic compound were also detected as minor constituents. However, the composition of arsenic compounds was different among these species. These results might reflect the differences in the metabolism of arsenic and/or the compositions of arsenic compounds in their preys. To our knowledge, this is the first report on the large variation in the composition of arsenic species in liver of marine mammals and sea turtles.  相似文献   

The 17-month periodicity of sunspot activity   总被引：3，自引：0，他引：3  

M. Akioka  J. Kubota  M. Suzuki  K. Ichimoto  I. Tohmura 《Solar physics》1987,112(2):313-316

A statistical study of sunspot activity during 1969 to 1986 was carried out by using the number of sunspot groups and their areas. We found a 17-month periodicity, which is consistent with the 500-day periodicity of flare occurrence (Ichimoto et al., 1985).Contributions from the Kwasan and Hida Observatories, University of Kyoto, No. 281.  相似文献   

Accelerator analyses of tributyltin chloride associated with a tributyltin resistant marine microorganism     

Kubota N  Mimura H  Yamauchi T  Kitamura A 《Marine pollution bulletin》2004,48(7-8):800-805

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Evaluation of air-sea sensible and latent heat fluxes over the Japan Sea obtained from satellite,atmospheric reanalysis,and objective analysis products     

Hiroyuki Tomita  Tomoharu Senjyu  Masahisa Kubota 《Journal of Oceanography》2016,72(5):747-760

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Evaluation of Vector Winds Observed by NSCAT in the Seas around Japan     

Harunobu Masuko  Kohei Arai  Naoto Ebuchi  Masanori Konda  Masahisa Kubota  Kunio Kutsuwada  Teruko Manabe  Akira Mukaida  Tetsuo Nakazawa  Atsushi Nomura  Akira Shibata  Yoshihiko Tahara 《Journal of Oceanography》2000,56(5):495-505

In order to validate wind vectors derived from the NASA Scatterometer (NSCAT), two NSCAT wind products of different spatial resolutions are compared with observations by buoys and research vessels in the seas around Japan. In general, the NSCAT winds agree well with the wind data from the buoys and vessels. It is shown that the root-mean-square (rms) difference between NSCAT-derived wind speeds and the buoy observations is 1.7 ms^–1, which satisfies the mission requirement of accuracy, 2 ms^–1. However, the rms difference of wind directions is slightly larger than the mission requirement, 20°. This result does not agree with those of previous studies on validation of the NSCAT-derived wind vectors using buoy observations, and is considered to be due to differences in the buoy observation systems. It is also shown that there are no significant systematic trends of the NSCAT wind speed and direction depending on the wind speed and incidence angle. Comparison with ship winds shows that the NSCAT wind speeds are lower than those observed by the research vessels by about 0.7 ms^–1 and this bias is twice as large for data observed by moving ships than by stationary ships. This result suggests that the ship winds may be influenced by errors caused by ship's motion, such as pitching and rolling.  相似文献