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51.
The impact of diffuse pollution, agricultural land use and climate change on the long-term response of subsurface–surface water quality is not well understood, but is a prerequisite for evaluation of water management options. The goal of this study is to model geochemical evolution of water chemistry from the infiltration through soil into the unsaturated zone, transport through bedrocks and granular aquifers to a river in order to identify zones of steep concentration gradients and high dynamics under transient flow conditions. A numerical model was constructed comprising a 2-D 1,500 m × 150 m vertical cross-section of typical sedimentary rock formations, a glacio-fluvial quaternary gravel aquifer in the valley and soil layers. The model coupled saturated/un-saturated flow and reactive transport under steady state and transient conditions. Geochemical interactions, include intra-aqueous kinetic reactions of oxygen with dissolved organic matter, as well as kinetics of carbonate dissolution/precipitation. This model section was chosen to provide insight in to the principal processes and time scales affecting water chemistry along different flow paths. The numerical simulator MIN3P was used, a finite volume program for variably saturated subsurface flow and multi-component reactive transport. The results show that subsurface water residence times range from approximately 2 to 2,000 years. Different zones are to be expected with respect to the development of mineral equilibria; namely, purely atmospherically influenced, as well as open and closed system carbonate dissolution. Short-term responses to daily averaged changes in precipitation, however, are only visible to some extent in the shallower and near-river parts of flow system and solute loads. This can most likely be explained by directional changes in flow paths, indicating that equilibrium geochemical condition predominate at the hillslope scale, i.e. water quality depends on transport pathways rather than on kinetic effects. The extent of reducing conditions is controlled by the presence of organic-rich layers (i.e. peat deposits), the dissolution kinetics of aquifer organic matter and the subsequent mixing with oxygenated water by hydrodynamic dispersion.  相似文献   
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The Orbetello lagoon, one of the largest Western Mediterranean lagoons, was affected by high algal blooms and severe anoxic crises in 1992 and 1993, with fish mortality throughout most of the lagoon and a drastic reduction of benthic species. Many measures were undertaken between 1994 and 1996 to remove the severe eutrophication of this lagoon. Such measures included harvesting of the floating seaweed biomass, removal of all wastewater and sea channel enlargement by dredging activity. The aim of the present research was to study the macrozoobenthic assemblage in 1999 and to compare it with previous research in order to assess the recovery of the lagoon. A total of 106 taxa and 45,175 individuals were collected in three areas (sea inlets, western and eastern lagoon) having different organic matter loading during winter and summer. The results of multivariate and correlation analyses indicated that trophic status and its seasonal dynamics were crucial in determining species distribution among the different areas. Moreover, comparison of the macrozoobenthic structure between winter 1995 and 1999 showed differences in species composition and structural parameters in the western and eastern lagoon, where a clear recovery of benthic assemblages was observed in 1999. However, the dominance of opportunistic species in most of the lagoon and the decrease in some structural parameters during summer suggested that this basin still presented signs of disturbance in 1999, six years after the last extended anoxic crises and even after completion of the restoration measures carried out in the environment. It was hypothesized that a secondary disturbance, sustained by a high seasonal release of nutrients from the sediments, could create considerable deviations from the expected improvement in benthic conditions.  相似文献   
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The Sun Watcher with Active Pixels and Image Processing (SWAP) is an EUV solar telescope onboard ESA’s Project for Onboard Autonomy 2 (PROBA2) mission launched on 2 November 2009. SWAP has a spectral bandpass centered on 17.4 nm and provides images of the low solar corona over a 54×54 arcmin field-of-view with 3.2 arcsec pixels and an imaging cadence of about two minutes. SWAP is designed to monitor all space-weather-relevant events and features in the low solar corona. Given the limited resources of the PROBA2 microsatellite, the SWAP telescope is designed with various innovative technologies, including an off-axis optical design and a CMOS–APS detector. This article provides reference documentation for users of the SWAP image data.  相似文献   
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We monitored the concentrations of copper, lead and cadmium in seawater, in suspended particulate matter (SPM) and in bacteria, phyto- and zooplankton communities separated from abiogenic particles, over a one year cycle in two coupled Mediterranean coastal ecosystems (Little Bay (LiB) and Large Bay (LaB)). Metals were present in seawater in the order Cu > Pb > Cd in both bays and showed important variations within the same month than among months. In LiB, their concentrations were between 0.62 and 2.82 μg Cu l−1, 0.16 and 19 μg Pb l−1 and 0.007 and 0.14 μg Cd l−1, respectively, whereas in LaB, they were between 0.23 and 2.11 μg Cu l−1, 0.09 and 0.76 μg Pb l−1 and not detected and 0.65 μg Cd l−1. SPM play an important role on metal adsorption, especially for copper. Bioaccumulation factors showed that bacteria and phytoplankton accumulate metals whereas zooplankton tends to biodiminish them in the plankton food web.  相似文献   
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Shelf ridges are sedimentary bodies formed on the continental shelf due to transgressive reworking (tidal or storm) of lowstand deposits. Common on modern shelves, they are under‐represented in the geological record due to a lack of recognition criteria and facies model. This article proposes a new facies and architectural model for shelf ridges, linked to their inception–evolution–abandonment cycle and the process regime of the basin. The model is mainly based on new outcrop data and interpretations from three sandstone bodies of the Almond Formation, an overall transgressive interval during the infill of the Campanian Western Interior Seaway. Building from the case study, and ancient and modern examples, six characteristics are proposed for the recognition of ancient shelf ridges. Shelf ridges: (i) are encased between thick marine mudstone intervals; (ii) have a basal unconformity that erodes into marine muds or into the remnants of a previous shoreline; (iii) have a non‐erosional upper boundary that transitions into marine muds; (iv) are characterized by clean and well‐sorted sandstones, often cross‐bedded; (v) contain fully marine ichnofauna; and (vi) present compound architectures with large accretion surfaces and lower order structures. Although shelf ridges have been described in previous studies as generated exclusively by either tidal or storm currents, it is clear, from modern examples and the case study, that these two processes can be recorded and preserved in a single shelf ridge. The stratigraphy of these sandstone bodies is therefore much more complex than previously recognized, bearing the signature of changing tidal and storm intensity through time. Because they are developed during transgressions, shelf ridges are commonly subject to strong changes in process regime as sea‐level changes can easily affect the oceanographic conditions and the morphology of the basin. For this reason, shelf ridges can provide the best record of shelf process variability during transgressions.  相似文献   
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A comparison between theGeneral Catalogue of Cool Carbon Stars (CCS) and theAFGL Catalogue has been performed.Eighty-five stars have been found in common between the two lists. Eighty-four stars which were present in Baumert's comparison between CCS and the 2 Sky Survey have no counterpart in the AFGL. Four new tentative identifications are given. The analysis of the two colours diagrams K-[4.2 ] vs. I-K and I-[4.2 ] vs. [4.2 ]-[11 ] led to the conclusion that all the infrared emission from the sources seems to come from a single circumstellar shell.  相似文献   
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