Present weathering rates in a humid tropical watershed: Nsimi, South Cameroon   总被引：3，自引：0，他引：3  

Jean-Jacques Braun  Jules Remy Ndam Ngoupayou  Bernard Dupre  Jean-Loup Boeglin  Brunot Nyeck  Luc Sigha Nkamdjou  Jean-Pierre Muller 《Geochimica et cosmochimica acta》2005,69(2):357-387

The study of biogeochemical and hydrological cycles in small experimental watersheds on silicate rocks, common for the Temperate Zone, has not yet been widely applied to the tropics, especially humid areas. This paper presents an updated database for a six-year period for the small experimental watershed of the Mengong brook in the humid tropics (Nsimi, South Cameroon). This watershed is developed on Precambrian granitoids (North Congo shield) and consists of two convexo-concave lateritic hills surrounding a large flat swamp covered by hydromorphic soils rich in upward organic matter. Mineralogical and geochemical investigations were carried out in the protolith, the saprolite, the hillside lateritic soils, and the swamp hydromorphic soils. Biomass chemical analyses were done for the representative species of the swamp vegetation. The groundwater was analysed from the parent rock/saprolite weathering front to the upper fringe in the hillside and swamp system. The chemistry of the wet atmospheric and throughfall deposits and the Mengong waters was monitored.In the Nsimi watershed the carbon transfer occurs primarily in an organic form and essentially as colloids produced by the slow biodegradation of the swamp organic matter. These organic colloids contribute significantly to the mobilization and transfer of Fe, Al, Zr, Ti, and Th in the uppermost first meter of the swamp regolith. When the organic colloid content is low (i.e., in the hillside groundwater), Th and Zr concentrations are extremely low (<3 pmol/L, ICP-MS detection limits). Strongly insoluble secondary thorianite (ThO₂) and primary zircon (ZrSiO₄) crystals control their mobilization, respectively. This finding thus justifies the potential use of both these elements as inert elements for isoelement mass balance calculations pertaining to the hillside regolith.Chloride can not be used as a conservative tracer of hydrological processes and chemical weathering in this watershed. Biogenic recycling significantly influences the low-Cl input fluxes. Sodium is a good tracer of chemical weathering in the watershed. The sodium solute flux corrected from cyclic salt input was used to assess the chemical weathering rate. Even though low (2.8 mm/kyr), the chemical weathering rate predominates over the mechanical weathering rate (1.9 mm/kyr). Compared to the Rio Icacos watershed, the most studied tropical site, the chemical weathering fluxes of silica and sodium in the Mengong are 16 and 40 times lower, respectively. This is not only related to the protective role of the regolith, thick in both cases, but also to differences in the hydrological functioning. This is to be taken into account in the calculations of the carbon cycle balance for large surfaces like that of the tropical forest ecosystems on a stable shield at the global level.  相似文献   

Case studies on the origin of basalt     

Mark D. Feigenson  Albrecht W. Hofmann  Frank J. Spera 《Contributions to Mineralogy and Petrology》1983,84(4):382-389

The simplified model of basalt genesis described in Part I of this series, equilibrium partial melting followed by Rayleigh-type fractional crystallization, is applied to a stratigraphically controlled sequence of basalt flows from Kohala volcano. Major-element compositions were determined for 52 samples and show a time-stratigraphic progression from tholeiites through transitional basalts to alkali basalts. Twenty-six of these samples were analyzed by isotope dilution for K, Rb, Cs, Sr, Ba and the REE, 13 for⁸⁷Sr/⁸⁶Sr, and 19 for Co, Cr, Ni and V by atomic absorption. After a simple, first-order correction for the effects of fractional crystallization (involving mostly olivine and aluminous clinopyroxene), the major element concentrations cluster tightly, and the incompatible trace elements show monotonic increases in concentration as a function of stratigraphic height. The process identification plot shows that all the (fractionation corrected) melt compositions can be explained by equilibrium partial melting of compositionally identical batches of source material. The REE and Sr are fractionated because of the presence of residual clinopyroxene. Garnet may also be present but in much smaller amounts. In this respect our results differ significantly from those of Leeman et al. (1980). The calculated chondrite-normalized REE patterns of the source are nearly flat to slightly convex upward. Therefore there is no need to invoke special mechanisms, such as metasomatic REE preenrichment of the source, in order to explain the petrogenesis of the suite of lavas. Specifically, Ce concentrations ranging from 20 to 250 times chondritic are all explained by the same calculated source pattern having a chondrite-normalized ratio of Ce/Sm=0.9±0.2. However, the normalized ratio Ce/Ba?2 shows that the source is not simply primitive mantle.  相似文献   

Die Berechnung der Angströmschen Trübungskonstanten aus Sonnenstrahlungsmessungen in verschiedenen Filtergebieten     

Fritz H. W. Albrecht 《Pure and Applied Geophysics》1956,33(1):229-244

Zusammenfassung Zur Bearbeitung von mehreren hundert Messungen der direkten Sonnenstrahlung mit fünf verschiedenen Farbfiltern werden Neuberechnungen derAngstr?mschen Formel (Gleichung 1) für die einzelnen Wellenl?ngen mit insgesamt 144 verschiedenen Werten für die Luftmassem, den Wellenl?ngenexponenten α der Zerstreuungsfunktion, dem Trübungskoeffizienten β und dem WasserdampfgehaltW der Atmosph?re durchgeführt. Es wurde hierbei festgestellt, da? es m?glich ist, die Filterdifferenzen für die Spektralbereiche Blau, Gelb, Rot und zwei Infrarot durch einfache algebraische Formeln darzustellen (Gleichungen 3 und 5), aus denen α und β errechnet werden k?nnen (Gleichungen 6 und 7). Bezüglich des Wasserdampfgehaltes ergab sich, da? es nicht m?glich ist, die Wasserdampfabsorption durch ein einziges Gliedf(mW) darzustellen, das additiv zu dem Zerstreuungsterm derAngstr?mschen Formel hinzugefügt wird, wie es bisher meist geschah. Es wurde eine neue Fassung des additiven Gliedes für die Wasserdampfabsorptionf(α, β, m, mW) berechnet und durch eine Formel (12) wiedergegeben. Auf die Bedeutung der neuen Absorptionsfunktion des Wasserdampfes für die vom Verfasser kürzlich entwickelte Kalibrierung der Aktinometer aus dem Beobachtungsmaterial wird eingegangen (Gleichung 14). Zum Schlu? werden neue Gleichungen (20) entwickelt, die die Bestimmung von α im langwelligen Spektralgebiet der Sonnenstrahlung erm?glichen, in dem auch der Wasserdampf absorbiert. Dies ist wichtig, weil das α, das bisher nur aus dem kurzwelligen Teil des Sonnenspektrum bestimmt werden konnte, nicht notwendig übereinzustimmen braucht mit dem α im langwelligen Gebiet.

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Summary DeterminingAngstr?m’s turbidity constants from several hundred sets of readings of the solar radiation with five different glass filters,Angstr?m’s formula (equ. 1) was calculated for a total of 144 different values of air massesm, the wavelength exponent α of the scattering function, the turbidity coefficient β and water vapour content W of the atmosphere. It was found that it is possible to express the filter differences belonging to the spectral ranges blue, yellow, red, and two infrared ranges with simple algebraic formulae (equ. 3 and 5) which allow α and β to be calculated (equ. 6 and 7). With respect to the water vapour content it was pointed out that it is impossible to express, in the usual way, the water vapour absorption by a single termf(mW), which is added to the scattering term ofAngstr?m’s formula. A new form of the water vapour absorption was calculated and expressed as a formula (12). The significance of the new water vapour absorption function was discussed with reference to the author’s newly developed actinometer calibration from observational data (equ. 14). In conclusion new equations (20) were derived enabling to be determined in the long wave range of solar radiation, i.e. where the water vapour absorption exists. This is important because so far α could only be determined from the short wave range of solar radiation, which does not necessarily agree with that of the long wave range.

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Dr. Fritz H. W. Albrecht, 10, Belgravia Ave., Box Hill North E 12,Melbourne.  相似文献   

Metasomatism of ferroan granites in the northern Aravalli orogen,NW India: geochemical and isotopic constraints,and its metallogenic significance   总被引：1，自引：0，他引：1  

Parampreet Kaur  Naveen Chaudhri  Albrecht W. Hofmann  Ingrid Raczek  Martin Okrusch  Susanne Skora  Jürgen Koepke 《International Journal of Earth Sciences》2014,103(4):1083-1112

The late Palaeoproterozoic (1.72–1.70 Ga) ferroan granites of the Khetri complex, northern Aravalli orogen, NW India, were extensively metasomatised ~900 Ma after their emplacement, at around 850–830 Ma by low-temperature (ca. 400 °C) meteoric fluids that attained metamorphic character after exchanging oxygen with the surrounding metamorphic rocks. Albitisation is the dominant metasomatic process that was accompanied by Mg and Ca metasomatism. A two-stage metasomatic model is applicable to all the altered ferroan intrusives. The stage I is represented by a metasomatic reaction interface that developed as a result of transformation of the original microcline–oligoclase (An_12–14) granite to microcline–albite (An_1–3) granite, and this stage is rarely preserved. In contrast, the stage II metasomatic reaction front, where the microcline-bearing albite granite has been transformed to microcline-free albite granite, is readily recognisable in the field and present in most of the intrusives. Some of them lack an obvious reaction interface due to the presence of stage II albite granites only. When studied in isolation, these intrusives were incorrectly classified and their tectonic setting was misinterpreted. Furthermore, our results show that the mafic mineralogy of metasomatised granites has a significant impact on the characterisation of such rocks in the magmatic classification and discrimination diagrams. Nevertheless, the stage I metasomatised granites can be appropriately characterised in these diagrams, whereas the characterisation of the stage II granites will lead to erroneous interpretations. The close spatial association of these high heat producing ferroan granites with iron oxide–copper–gold (IOCG), U and REE mineralisation in the region indicates a genetic link between the metasomatism and the mineralisation. World-class IOCG, U and REE deposits are associated with metasomatised ferroan granites, suggesting that such a relationship may act as a critical first-order exploration target for undiscovered mineral deposits.  相似文献