The major ion, δCa, δCa, and δMg geochemistry of granite weathering at pH = 1 and T = 25 °C: power-law processes and the relative reactivity of minerals     

Jong-Sik Ryu  Andrew D. Jacobson  Craig Lundstrom 《Geochimica et cosmochimica acta》2011,75(20):6004-7046

We dissolved Boulder Creek Granodiorite in a plug flow reactor for 5794 h at pH = 1 and T = 25 °C. The primary purpose of the experiment was to identify controls on dissolved δ^44/40Ca, δ^44/42Ca, and δ^26/24Mg values during granite weathering. Herein, we also examine the origin of Ca and Mg isotopic variability among minerals composing the Boulder Creek Granodiorite, and we constrain fundamental characteristics of granite weathering important for quantifying the elemental and isotopic geochemistry of the reactor output. Nine Ca-bearing minerals display an 8.80‰ range of δ^44/40Ca values and a 0.51‰ range of δ^44/42Ca values. Three Mg-bearing minerals display a 1.53‰ range of δ^26/24Mg values. These ranges expressed at the mineralogical scale are higher than the ranges thus far reported for bulk igneous rocks. Most of the δ^44/40Ca variability reflects ⁴⁰Ca enrichment in K-feldspar, and to a lesser extent, biotite, due to the radioactive decay of ⁴⁰K over the 1.7 Ga age of the rock, whereas the entire range of δ^44/42Ca values reflects mass-dependent isotope fractionation during igneous differentiation and crystallization. The range of δ^26/24Mg values may represent either fractionation during the chloritization of biotite or interaction of the Boulder Creek Granodiorite with Mg-rich metamorphic fluids having low δ^26/24Mg values.The elemental and isotopic composition of the reactor output varied substantially during the experiment. We synthesize the mineralogical and fluid data using coupled mass-conservation equations solved at non-steady-state. Model calculations reveal an intricate balance between increasing specific surface area and decreasing mineral concentrations. While surface area normalized dissolution rate constants were time-invariant, specific surface area increased as a power-law function of time through positive feedbacks between mechanical disaggregation, chemical dissolution, and mineral depletion. Variations in dissolved δ^44/40Ca, δ^44/42Ca, and δ^26/24Mg values reflect conservative mixing rather than fractionation. Apatite and calcite initially control δ^44/40Ca and δ^44/42Ca values, followed by biotite, titanite, epidote, hornblende, and plagioclase. The release of radiogenic ⁴⁰Ca clearly defines the period where biotite dissolution dominates. The brucite layer of chlorite initially controls δ^26/24Mg values, followed by biotite, the TOT layer of chlorite, and hornblende. Through direct isotopic tracking, these results demonstrate that trace minerals, such as apatite and calcite in the case of Ca and brucite in the case of Mg, dominate elemental release during the incipient stages of granite weathering. The results further show that biotite dissolution dominates the middle stages of granite weathering and that plagioclase dissolution only becomes important during relatively late stages. The Ca and Mg isotope variations associated with these stages are distinct and potentially resolvable in soil mineral weathering studies.  相似文献   

Probabilistic evaluation of primary consolidation settlement of Songdo New City by using kriged estimates of geologic profiles     

Donghee Kim  Dongwoo Ryu  Changho Lee  Woojin Lee 《Acta Geotechnica》2013,8(3):323-334

The uncertainty in the spatial distributions of consolidation settlement (s _c) and time (t _p) for Songdo New City is evaluated by using a probabilistic procedure. Ordinary kriging and three theoretical semivariogram models are used to estimate the spatial distributions of geo-layers which affect s _c and t _p in this study. The spatial map of mean (μ) and standard deviation (σ) for s _c and t _p are determined by using a first-order second moment method based on the evaluated statistics and probability density functions (PDFs) of soil properties. It is shown that the coefficients of variation (COVs) of the compression ratio [C _c/(1 + e ₀)] and the coefficient of consolidation (c _v) are the most influential factors on the uncertainties of s _c and t _p, respectively. The μ and σ of the s _c and t _p, as well as the probability that s _c exceeds 100 cm [P(s _c > 100 cm)] and the probability that t _p exceeds 36 months [P(t _p > 36 months)] in Sect. 1, are observed to be larger than those of other sections because the thickness of the consolidating layer in Sect. 1 is the largest in the entire study area. The area requiring additional fill after the consolidation appears to increase as the COV of C _c/(1 + e ₀) increases and as the probabilistic design criterion (α) decreases. It is also shown that the area requiring the prefabricated vertical drains installation increases as the COV of c _v increases and as the α decreases. The design procedure presented in this paper could be used in the decision making process for the design of geotechnical structures at coastal reclamation area.  相似文献   

The default methods in the 2019 Refinement drastically reduce estimates of global carbon sinks of harvested wood products     

Kayo  Chihiro  Kalt  Gerald  Tsunetsugu  Yuko  Hashimoto  Seiji  Komata  Hirotaka  Noda  Ryu  Oka  Hiroyasu 《Carbon balance and management》2021,16(1):1-12

With a lack of United States federal policy to address climate change, cities, the private sector, and universities have shouldered much of the work to reduce carbon dioxide (CO2) and other greenhouse gas emissions. This study aims to determine how landcover characteristics influence the amount of carbon (C) sequestered and respired via biological processes, evaluating the role of land management on the overall C budget of an urban university. Boston University published a comprehensive Climate Action Plan in 2017 with the goal of achieving C neutrality by 2040. In this study, we digitized and discretized each of Boston University’s three urban campuses into landcover types, with C sequestration and respiration rates measured and scaled to provide a University-wide estimate of biogenic C fluxes within the broader context of total University emissions. Each of Boston University’s three highly urban campuses were net sources of biogenic C to the atmosphere. While trees were estimated to sequester 0.6 ± 0.2 kg C m−2 canopy cover year−1, mulch and lawn areas in 2018 emitted C at rates of 1.7 ± 0.4 kg C m−2 year−1 and 1.4 ± 0.4 kg C m−2 year−1, respectively. C uptake by tree canopy cover, which can spatially overlap lawn and mulched landcovers, was not large enough to offset biogenic emissions. The proportion of biogenic emissions to Scope 1 anthropogenic emissions on each campus varied from 0.5% to 2%, and depended primarily on the total anthropogenic emissions on each campus. Our study quantifies the role of urban landcover in local C budgets, offering insights on how landscaping management strategies—such as decreasing mulch application rates and expanding tree canopy extent—can assist universities in minimizing biogenic C emissions and even potentially creating a small biogenic C sink. Although biogenic C fluxes represent a small fraction of overall anthropogenic emissions on urban university campuses, these biogenic fluxes are under active management by the university and should be included in climate action plans.  相似文献   

Numerical simulation of impact loads using a particle method     

B.-H. Lee  J.-C. Park  M.-H. Kim  S.-J. Jung  M.-C. Ryu  Y.-S. Kim 《Ocean Engineering》2010,37(2-3):164-173

The violent free-surface motions interacting with structures are investigated using the moving particle semi-implicit (MPS) method, which was originally proposed by Koshizuka and Oka (1996) for incompressible flow simulation. In the present numerical method, a more efficient algorithm for Lagrangian moving particles is used for solving various highly nonlinear free-surface problems without using the Eulerian approach or the grid system. Therefore, the convection terms and time derivatives in the Navier–Stokes equation can be calculated more directly without any numerical diffusion, instabilities, or topological failure. In particular, the MPS method is applied to the simulation of liquid-entry and slamming problems, such as wet-drop (liquid–liquid collision) tests in an LNG tank and slamming loads (solid–liquid collision) on rigid plates with various incident angles. The numerical results are in good agreement with available experimental data.  相似文献   

Geological and Geotechnical Characteristics of Marine Clays at the Busan New Port     

S. G. Chung  C. K. Ryu  K. Y. Jo  D. Y. Huh 《Marine Georesources & Geotechnology》2013,31(3):235-251

ABSTRACT

Despite a number of geotechnical investigations that have been carried out in the Busan new port area of South Korea, the local practicing engineers have been unable to deduce successfully the geotechnical properties of the clays due to their spatial variation. In the area, clay deposits, so-called Pusan clays, are unusually thick, varying from 20 m to 70 m in thickness. For this study, comprehensive geological and geotechnical investigations were carried out with sophisticated sampling techniques, in situ and laboratory tests as well as geological analyses at an additional three locations. As a result of the investigations, it was found that depositional environments are closely related to the relative changes in sea level and have different features depending on location and depth. The clays consist of soft and stiff clays in the upper and the lower layers, respectively, which are classified as normally consolidated and cemented clay. Moreover, most of the geotechnical properties undergo small changes due to their depositional environment. Information about these effects would be quite helpful to understand the spatial variation of geotechnical properties as well as the effect of sample disturbance. Some correlations which reflect the geological history of the deposts were conducted for physical indexes and mechanical properties.  相似文献   

Geochemical characterization of the organic matter, pore water constituents and shallow methane gas in the eastern part of the Ulleung Basin, East Sea (Japan Sea)     

Ji-Hoon  Kim  Myong-Ho  Park  Urumu  Tsunogai  Tae-Jin  Cheong  Byong-Jae  Ryu  Young-Joo  Lee  Hyun-Chul  Han  Jae-Ho  Oh  Ho-Wan  Chang 《Island Arc》2007,16(1):93-104

Abstract Geochemical analyses of sediments, pore water and headspace gas of the piston cores taken from the eastern part of Ulleung Basin of the East Sea (Japan Sea) were carried out to assess the origin of the sedimentary organic matter and interstitial fluid. Several tephra layers within the core are identified as the Ulleung‐Oki (10.1 ka), the Aira‐Tanzawa (23 ka) and the Ulleung‐Yamato (30.9 ka) tephras. With the exception of these volcanic layers, the cores consist predominantly of muddy sediments that contain >0.5% total organic carbon. Atomic C/N ratios and δ¹³C_org values suggest that the organic matter originated from marine algae rather than from land vascular plants, whereas Rock‐Eval pyrolysis suggests that the organic matter is thermally immature and comes from a land vascular plant (Type III). These conflicting results seem to be caused by the heavy oxidization of the marine organic matter. Sulphate concentration profiles of pore waters show strongly linear depletion (r² > 0.97) with sediment depth. The estimated sulphate–methane interface (SMI) depth using the sulphate concentration gradient was nearly 3.5 m below seafloor (mbsf) in the southern part of the study area, and deeper than 6 mbsf in the northern part of the area. The difference in SMI depths is likely associated with the amount of the methane flux. The methane concentration below the SMI in the two southern cores increases rapidly, implying the occurrence of methanogenesis and anaerobic methane oxidation (AMO). In contrast, the two northern cores have a low methane concentration below the SMI. values measured from all cores were in the range of −83.5 to −69.5‰, which suggests that the methane derives from a methanogenic microbe. values become decreased toward SMI, but increased below SMI; therefore, has eventually the minimum value near the SMI. The values are also decreased when the methane concentration is increased. These phenomena support the typical occurrence of AMO in the study area.  相似文献   

Sequence stratigraphy and hydrocarbon potential of the southern Tyee basin,Oregon Coast Range,USA     

Inchang Ryu  Heejung JangSujeong Lee 《Journal of Geochemical Exploration》2009

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Identification of sources affecting water chemistry in the Nakdong River,South Korea     

Woo-Jin Shin  Jong-Sik Ryu  Ji-Sook Min  Kwang-Sik Lee 《Environmental Earth Sciences》2017,76(10):376

The sources impacting the water chemistry of the Nakdong River (NR) in South Korea were investigated in order to examine the pollution mechanism including the fate and transport of the contaminants and how much such sources may affect its main channel of water resource. Water samples were collected between 2007 and 2008 from 8 sites along a 510 km downstream transect of the NR, and chemical and isotopic compositions of the water samples were evaluated to identify natural and anthropogenic sources contributing to the water chemistry of the NR. The results showed that the major ion concentrations were mainly controlled by chemical weathering that occurred in the watershed, in which a silicate weathering is more dominant than a carbonate weathering. The ⁸⁷Sr/⁸⁶Sr ratios of the water samples were in a range from 0.71043 to 0.71520 within those of the Mesozoic volcanogenic sedimentary rocks long developed in the watershed, thereby supporting the fact that the water chemistry is governed by a chemical weathering. The δ³⁴S values varied in a narrow range of 1.8–3.1‰, regardless of spatial and seasonal variations. Mass balance calculations indicated that the contributions of chemical weathering and anthropogenic sources during summer time increased along a downstream transect, from 67.3 ± 1.3 to 73.6 ± 0.5% and from 6.0 to 15.7%, respectively. In contrast, the contribution of chemical weathering during winter time decreased from 82.7 ± 0.8 to 72.5 ± 0.3%, while anthropogenic contribution increased up to 22.2%. These results indicated that the water chemistry of the NR was mainly caused by a chemical weathering, followed by anthropogenic inputs and rainwater. This study will provide baseline information for comparing the water quality issue before and after the implementation of the Four Rivers Restoration Project of South Korea.  相似文献   

Sources of dissolved ions revealed by chemical and isotopic tracers in the Geum River,South Korea     

Woo-Jin Shin  Jong-Sik Ryu  Youngyun Park  Kwang-Sik Lee 《Environmental Earth Sciences》2017,76(14):488

Water samples were collected in the main channel of the Geum River, South Korea, and measured dissolved elemental concentrations and isotopic compositions of nitrate in order to identify the factors controlling water chemistry. Elemental concentrations significantly increased location-wise after the confluence from urban areas, indicating the changes in solute sources from chemical weathering to anthropogenic inputs such as manure, fertilizers, and sewage. In particular, the effect of sewage input is manifested in the concentrations of Cl^?, SO₄ ^2?, and Na⁺, while the NO₃ ^? concentration is influenced mainly by soil inputs with minor contributions from manure and fertilizer because both δ¹⁵N–NO₃ and δ¹⁸O–NO₃ indicate NO₃ ^? mostly consists of soil-derived nitrates in the upper reaches but manure/sewage nitrates in the lower reaches. The relative proportion of three factors, Cl^?, Ca²⁺+Mg²⁺, and NO₃ ^?, indicates that water chemistry in the upstream is controlled by the soil weathering but that in the downstream by the sewage. Seasonally, water chemistry during summer is dominated by the soil weathering due to the flushing effect but that during winter by the sewage. This study suggests that the relative proportion of three factors can be used for tracing natural and anthropogenic sources in water chemistry.  相似文献   

A Middle Ordovician Drowning Unconformity on the Northeastern Flank of the Okcheon (Ogcheon) Belt, South Korea     

In-Chang Ryu  Chang Whan Oh  Sung Won Kim 《Gondwana Research》2005,8(4):511-528

The Maggol Limestone of Ordovician age was deposited in the Taebaeksan (Taebacksan) Basin which occupies the northeastern flank of the Okcheon (Ogcheon) Belt of South Korea. Carbonate facies analysis in conjunction with conodont biostratigraphy suggests that an overall regression toward the top of the Maggol Limestone probably culminated in subaerial exposure of platform carbonates in the early Middle Ordovician (earliest Darriwilian). Elsewhere this subaerial exposure event is manifested as a major paleokarst unconformity at the Sauk-Tippecanoe sequence boundary beneath the Middle Ordovician succession and its equivalents, most in notably North America and North China. Due to its global extent, this paleokarst unconformity has been viewed as a product of second- or third-order eustatic sea level fall during the early Middle Ordovician. The Sauk-Tippecanoe sequence boundary in South Korea, however, appears to be a discrete marine-flooding surface in the upper Maggol Limestone. Strata beneath this surface represent by a thinning-upward stack of exposure-capped tidal flat-dominated cycles that are closely associated with multiple occurrences of paleokarst-related solution-collapse breccias. This marine-flooding surface is onlapped by a thick succession of thin-bedded micritic limestone that is eventually overlain by a Middle Ordovician condensed section. This physical stratigraphic relationship suggest that second- and third-order eustatic sea level fall may have been significantly tempered by regional tectonic subsidence near the end of Maggol deposition. The tectonic subsidence is also evidenced by the occurrence of coeval off-platform lowstand siliciclastic quartzite lenses as well as debris flow carbonate breccias (i.e., the Yemi Breccia) in the basin. With continued tectonic subsidence, a subsequent rise in the eustatic cycle caused drowning and deep flooding of the carbonate platform, forming a discrete marine-flooding surface that may be referred to as a drowning unconformity. This tectonic interpretation contrasts notably with the slowly subsiding carbonate platform model for the basin as has been previously suggested. Thus, it is proposed that the Taebaeksan Basin in the northeastern flank on the Okcheon Belt evolved from a slowly subsiding carbonate platform to a rapidly subsiding intracontinental rift basin during the early Middle Ordovician.  相似文献