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321.
We draw on published studies of floodplain organic carbon storage, wildfire-related effects on floodplains in temperate and high latitudes, and case studies to propose a conceptual model of the effects of wildfire on floodplain organic carbon storage in relation to climate and valley geometry. Soil organic carbon typically constitutes the largest carbon stock in floodplains in fire-prone regions, although downed wood can contain significant organic carbon. We focus on the influence of wildfire on soil organic carbon and downed wood as opposed to standing vegetation to emphasize the geomorphic influences resulting from wildfire on floodplain organic carbon stocks. The net effect of wildfire varies depending on site-specific characteristics including climate and valley geometry. Wildfire is likely to reduce carbon stock in steep, confined valley segments because increased water and sediment yields following fire create net floodplain erosion. The net effect of fire in partly confined valleys depends on site-specific interactions among floodplain aggradation and erosion, and, in high-latitude regions, permafrost degradation. In unconfined valleys in temperate latitudes, wildfire is likely to slightly increase floodplain organic carbon stock as a result of floodplain aggradation and wood deposition. In unconfined valleys in high latitudes underlain by permafrost, wildfire is likely in the short-term to significantly decrease floodplain organic carbon via permafrost degradation and reduce organic-layer thickness. Permafrost degradation reduces floodplain erosional resistance, leading to enhanced stream bank erosion and greater carbon fluxes into channels. The implications of warming climate and increased wildfires for floodplain organic carbon stock thus vary. Increasing wildfire extent, frequency, and severity may result in significant redistribution of organic carbon from floodplains to the atmosphere via combustion in all environments examined here, as well as redistribution from upper to lower portions of watersheds in the temperate zone and from floodplains to the oceans via riverine transport in the high-latitudes. © 2019 John Wiley & Sons, Ltd.  相似文献   
322.
Since the 1970s, multiple reconstruction techniques have been proposed and are currently used, to extrapolate and quantify eruptive parameters from sampled tephra fall deposit datasets. Atmospheric transport and deposition processes strongly control the spatial distribution of tephra deposit; therefore, a large uncertainty affects mass derived estimations especially for fall layer that are not well exposed. This paper has two main aims: the first is to analyse the sensitivity to the deposit sampling strategy of reconstruction techniques. The second is to assess whether there are differences between the modelled values for emitted mass and grainsize, versus values estimated from the deposits. We find significant differences and propose a new correction strategy. A numerical approach is demonstrated by simulating with a dispersal code a mild explosive event occurring at Mt. Etna on 24 November 2006. Eruptive parameters are reconstructed by an inversion information collected after the eruption. A full synthetic deposit is created by integrating the deposited mass computed by the model over the computational domain (i.e., an area of 7.5 × 104 km 2). A statistical analysis based on 2000 sampling tests of 50 sampling points shows a large variability, up to 50 % for all the reconstruction techniques. Moreover, for some test examples Power Law errors are larger than estimated uncertainty. A similar analysis, on simulated grain-size classes, shows how spatial sampling limitations strongly reduce the utility of available information on the total grain size distribution. For example, information on particles coarser than ?(?4) is completely lost when sampling at 1.5 km from the vent for all columns with heights less than 2000 m above the vent. To correct for this effect an optimal sampling strategy and a new reconstruction method are presented. A sensitivity study shows that our method can be extended to a wide range of eruptive scenarios including those in which aggregation processes are important. The new correction method allows an estimate of the deficiency for each simulated class in calculated mass deposited, providing reliable estimation of uncertainties in the reconstructed total (whole deposit) grainsize distribution.  相似文献   
323.
324.
The future status of the surface ocean around New Zealand was projected using two Earth System Models and four emission scenarios. By 2100 mean changes are largest under Representative Concentration Pathway 8.5 (RCP8.5), with a +2.5°C increase in sea surface temperature, and decreases in surface mixed layer depth (15%), macronutrients (7.5–20%), primary production (4.5%) and particle flux (12%). Largest macronutrient declines occur in the eastern Chatham Rise and subantarctic waters to the south, whereas dissolved iron increases in subtropical waters. Surface pH projections, validated against subantarctic time-series data, indicate a 0.335 decline to ~7.77 by 2100. However, projected pH is sensitive to future CO2 emissions, remaining within the current range under RCP2.6, but decreasing below it by 2040 with all other scenarios. Sub-regions vulnerable to climate change include the Chatham Rise, polar waters south of 50°S, and subtropical waters north of New Zealand, whereas the central Tasman Sea is least affected.  相似文献   
325.
The petrologic and oxygen isotopic characteristics of calcium‐aluminum‐rich inclusions (CAIs) in CO chondrites were further constrained by studying CAIs from six primitive CO3.0‐3.1 chondrites, including two Antarctic meteorites (DOM 08006 and MIL 090010), three hot desert meteorites (NWA 10493, NWA 10498, and NWA 7892), and the Colony meteorite. The CAIs can be divided into hibonite‐bearing inclusions (spinel‐hibonite spherules, monomineralic grains, hibonite‐pyroxene microspherules, and irregular/nodular objects), grossite‐bearing inclusions (monomineralic grains, grossite‐melilite microspherules, and irregular/nodular objects), melilite‐rich inclusions (fluffy Type A, compact type A, monomineralic grains, and igneous fragments), spinel‐pyroxene inclusions (fluffy objects resembling fine‐grained spinel‐rich inclusions in CV chondrites and nodular/banded objects resembling those in CM chondrites), and pyroxene‐anorthite inclusions. They are typically small (98.4 ± 54.4 µm, 1SD) and comprise 1.54 ± 0.43 (1SD) area% of the host chondrites. Melilite in the hot desert and Colony meteorites was extensively replaced by a hydrated Ca‐Al‐silicate during terrestrial weathering and converted melilite‐rich inclusions into spinel‐pyroxene inclusions. The CAI populations of the weathered COs are very similar to those in CM chondrites, suggesting that complete replacement of melilite by terrestrial weathering, and possibly parent body aqueous alteration, would make the CO CAIs CM‐like, supporting the hypothesis that CO and CM chondrites derive from similar nebular materials. Within the CO3.0‐3.1 chondrites, asteroidal alteration significantly resets oxygen isotopic compositions of CAIs in CO3.1 chondrites (?17O: ?25 to ?2‰) but left those in CO3.0‐3.05 chondrites mostly unchanged (?17O: ?25 to ?20‰), further supporting the model whereby thermal metamorphism became evident in CO chondrites of petrologic type ≥3.1. The resistance of CAI minerals to oxygen isotope exchange during thermal metamorphism follows in the order: melilite + grossite < hibonite + anorthite < spinel + diopside + forsterite. Meanwhile, terrestrial weathering destroys melilite without changing the chemical and isotopic compositions of melilite and other CAI minerals.  相似文献   
326.
The El Niño of 1997–98 was one of the strongest warming events of the past century; among many other effects, it impacted phytoplankton along the Peruvian coast by changing species composition and reducing biomass. While responses of the main fish resources to this natural perturbation are relatively well known, understanding the ecosystem response as a whole requires an ecotrophic multispecies approach. In this work, we construct trophic models of the Northern Humboldt Current Ecosystem (NHCE) and compare the La Niña (LN) years in 1995–96 with the El Niño (EN) years in 1997–98. The model area extends from 4°S–16°S and to 60 nm from the coast. The model consists of 32 functional groups of organisms and differs from previous trophic models of the Peruvian system through: (i) division of plankton into size classes to account for EN-associated changes and feeding preferences of small pelagic fish, (ii) increased division of demersal groups and separation of life history stages of hake, (iii) inclusion of mesopelagic fish, and (iv) incorporation of the jumbo squid (Dosidicus gigas), which became abundant following EN. Results show that EN reduced the size and organization of energy flows of the NHCE, but the overall functioning (proportion of energy flows used for respiration, consumption by predators, detritus and export) of the ecosystem was maintained. The reduction of diatom biomass during EN forced omnivorous planktivorous fish to switch to a more zooplankton-dominated diet, raising their trophic level. Consequently, in the EN model the trophic level increased for several predatory groups (mackerel, other large pelagics, sea birds, pinnipeds) and for fishery catch. A high modeled biomass of macrozooplankton was needed to balance the consumption by planktivores, especially during EN condition when observed diatoms biomass diminished dramatically. Despite overall lower planktivorous fish catches, the higher primary production required-to-catch ratio implied a stronger ecological impact of the fishery and stresses the need for precautionary management of fisheries during and after EN. During EN energetic indicators such as the lower primary production/total biomass ratio suggest a more energetically efficient ecosystem, while reduced network indicators such as the cycling index and relative ascendency indicate of a less organized state of the ecosystem. Compared to previous trophic models of the NHCE we observed: (i) a shrinking of ecosystem size in term of energy flows, (ii) slight changes in overall functioning (proportion of energy flows used for respiration, consumption by predators and detritus), and (iii) the use of alternate pathways leading to a higher ecological impact of the fishery for planktivorous fish.  相似文献   
327.
Mangrove forests are known to accomplish crucial ecosystem functions and services. They are nursery areas for fish, prawns and crabs, which provide coastal communities with a variety of food, timber and chemicals, and protect coasts from catastrophic events, such as tsunamis. Recently, a novel ecological service has been proposed for mangrove systems, namely natural wastewater treatment wetlands. This hypothesis was based on experimental data collected mainly in Chinese mangrove systems, which proved that mangrove soils were efficient in absorbing nutrients. Moreover, sewage loading seemed harmless to both plants and benthic communities in these systems. However, before promoting the use of natural mangroves as pollution buffers, or constructed mangrove wetlands as sewage treatment facilities, more data are needed on their overall tolerance to organic loading. Differences in macrobenthos patterns were thus investigated between peri-urban mangroves and sites not affected by sewage disposal in East Africa. We assessed differences in epifaunal assemblages, comprising crabs and molluscs, employing multivariate ACI unbalanced analyses to compare peri-urban mangrove swamps with those characteristic of non-urban mangroves with similar ecological traits. The sampling design was spatially nested, replicates being assessed at equatorial (southern Kenya) and subtropical (southern Mozambique) sites. The results manifested a consistent increase in crab biomass at the peri-urban sites in both Kenya and Mozambique. Moreover, the peri-urban systems were richer than the non-urban mangroves, both in terms of fiddler crabs (Uca spp.) which feed on benthic microalgae and bacteria, and sesarmids, such as Perisesarma guttatum and Neosarmatium meinerti, which feed on both substratum and leaf litter. The abundance of gastropods, in contrast, decreased significantly, especially in Kenya, mainly due to the disappearance of the mud whelk Terebralia palustris. The results thus indicate that, in East African mangrove systems, domestic wastewater has detectable effects on crabs and molluscs, suggesting their usefulness as bioindicators of its effects in mangroves. Transformed benthic patterns at the peri-urban sites indicated the need for further study of the actual potential of natural mangrove forests to absorb pollution in sewage treatment.  相似文献   
328.
Although riparian zones are well known to reduce nitrogen (N) and phosphorus (P) runoff to streams, they also have the potential to affect greenhouse gas (CO2, N2O, and CH4) fluxes to the atmosphere. Following large storms, soil biogeochemical conditions often become more reduced, especially in oxbow depressions and side channels, which can lead to hot moments of greenhouse gas production. Here, we investigate the impact of the remnants of Hurricane Irene and Tropical Storm Lee on riparian zone hydrology (water table: WT), and biogeochemistry (oxidation‐reduction potential [ORP], dissolved oxygen [DO], NO3?, PO43?, CO2, N2O, CH4). Results indicate that large storms have the potential to reset WT levels for weeks to months. Overbank flooding at our site following Irene and Lee led to the infiltration of well‐oxygenated water at depth (higher DO and ORP) while promoting the development of anoxic conditions within soil aggregates near the soil surface (increased N2O and CH4 fluxes). A short‐term increase in CO2 emission was observed following Irene at our site where aerobic respiration was water‐limited. Over a 2‐year period, an oxbow depression exhibited higher WT, higher N2O and CH4 fluxes (hot moment), higher CO2 fluxes (seasonal), and lower NO3? concentrations (seasonal) than the rest of the riparian zone. However, neither Irene, nor Lee, nor the oxbow depression significantly impacted PO43?. Dissolved organic carbon, ORP, and DO data illustrate the time‐lag (>20 years) between the creation of an oxbow depression and the development of reducing conditions despite clear differences in riparian zone and oxbow WT dynamics.  相似文献   
329.
Abstract– In situ secondary ion mass spectrometry analyses of 32S, 33S, and 34S in iron‐nickel sulfide grains in two CI1 chondrites and six CM chondrites were performed. The results show a wider range of both enrichment and depletion in δ34S relative to troilite from the Canyon Diablo meteorite (CDT) than has been observed in previous studies. All data points lie within error of a single mass dependent fractionation line. Sulfides from CI1 chondrites show δ34SCDT from ?0.7 to 6.8‰, while sulfide grains in the CM1 chondrite are generally depleted in heavy sulfur relative to CDT (δ34S from ?2.9 to 1.8‰). CM2 chondrites contain sulfide grains that show enrichment and depletion in 34S (δ34SCDT from ?7.0 to 6.8‰). Sulfates forming from sulfide grains during aqueous alteration on the chondrite parent body are suggested to concentrate light sulfur, leaving the remaining sulfide grains enriched in the heavy isotopes of sulfur. The average degree of enrichment in 34S in CM chondrite sulfides is broadly consistent with previously suggested alteration sequences.  相似文献   
330.
Using a large (14 857), homogenously selected sample of cluster galaxies identified in the Sloan Digital Sky Survey Data Release 4, we investigate the impact of cluster membership and local density on the stellar mass–gas phase metallicity relation (MZR). We show that stellar metallicities are not suitable for this work, being relatively insensitive to subtle changes in the MZR. Accurate nebular abundances can be obtained for 1318 cluster galaxies in our sample and we show that these galaxies are drawn from clusters that are fully representative of the parent sample in terms of mass, size, velocity dispersion and richness. By comparing the MZR of the cluster galaxies with a sample of control galaxies matched in mass, redshift, fibre covering fraction and rest-frame   g − r   colour cluster galaxies are found to have, on average, higher metallicities by up to 0.04 dex. The magnitude of this offset does not depend strongly on galactic half-light radius or cluster properties such as velocity dispersion or cluster mass. The effect of local density on the MZR is investigated, using the presence of a near neighbour and both two- and three-dimensional density estimators. For all three metrics, it is found that the cluster galaxies in locally rich environments have higher median metallicities by up to ∼0.05 dex than those in locally poor environments (or without a near neighbour). Control (non-cluster) galaxies at locally high densities exhibit similar metal enhancements. Taken together, these results show that galaxies in clusters are, on average, slightly more metal rich than the field, but that this effect is driven by local overdensity and not simply cluster membership.  相似文献   
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