Oil-generation kinetics for organic facies with Type-II and -IIS kerogen in the Menilite Shales of the Polish Carpathians     

M.D. Lewan  M.J. Kotarba  D. Wi?c?aw 《Geochimica et cosmochimica acta》2006,70(13):3351-3368

The Menilite Shales (Oligocene) of the Polish Carpathians are the source of low-sulfur oils in the thrust belt and some high-sulfur oils in the Carpathian Foredeep. These oil occurrences indicate that the high-sulfur oils in the Foredeep were generated and expelled before major thrusting and the low-sulfur oils in the thrust belt were generated and expelled during or after major thrusting. Two distinct organic facies have been observed in the Menilite Shales. One organic facies has a high clastic sediment input and contains Type-II kerogen. The other organic facies has a lower clastic sediment input and contains Type-IIS kerogen. Representative samples of both organic facies were used to determine kinetic parameters for immiscible oil generation by isothermal hydrous pyrolysis and S₂ generation by non-isothermal open-system pyrolysis. The derived kinetic parameters showed that timing of S₂ generation was not as different between the Type-IIS and -II kerogen based on open-system pyrolysis as compared with immiscible oil generation based on hydrous pyrolysis. Applying these kinetic parameters to a burial history in the Skole unit showed that some expelled oil would have been generated from the organic facies with Type-IIS kerogen before major thrusting with the hydrous-pyrolysis kinetic parameters but not with the open-system pyrolysis kinetic parameters. The inability of open-system pyrolysis to determine earlier petroleum generation from Type-IIS kerogen is attributed to the large polar-rich bitumen component in S₂ generation, rapid loss of sulfur free-radical initiators in the open system, and diminished radical selectivity and rate constant differences at higher temperatures. Hydrous-pyrolysis kinetic parameters are determined in the presence of water at lower temperatures in a closed system, which allows differentiation of bitumen and oil generation, interaction of free-radical initiators, greater radical selectivity, and more distinguishable rate constants as would occur during natural maturation. Kinetic parameters derived from hydrous pyrolysis show good correlations with one another (compensation effect) and kerogen organic-sulfur contents. These correlations allow for indirect determination of hydrous-pyrolysis kinetic parameters on the basis of the organic-sulfur mole fraction of an immature Type-II or -IIS kerogen.  相似文献   

Study on the kinetics of iron oxide leaching by oxalic acid   总被引：2，自引：0，他引：2  

Suong Oh Lee  Tam Tran  Yi Yong Park  Seong Jun Kim  Myong Jun Kim   《International Journal of Mineral Processing》2006,80(2-4):144-152

The presence of iron oxides in clay or silica raw materials is detrimental to the manufacturing of high quality ceramics. Although iron has been traditionally removed by physical mineral processing, acid washing has been tested as it is more effective, especially for extremely low iron (of less than 0.1% w/w). However, inorganic acids such as sulphuric or hydrochloric acids easily contaminate the clay products with SO₄²⁻ and Cl⁻, and therefore should be avoided as much as possible. On the other hand, if oxalic acid is used, any acid left behind will be destroyed during the firing of the ceramic products. The characteristics of dissolution of iron oxides were therefore investigated in this study.The dissolution of iron oxides in oxalic acid was found to be very slow at temperatures within the range 25–60 °C, but its rate increases rapidly above 90 °C. The dissolution rate also increases with increasing oxalate concentration at the constant pH values set within the optimum range of pH2.5–3.0. At this optimum pH, the dissolution of fine pure hematite (Fe₂O₃) (105–140 μm) follows a diffusion-controlled shrinking core model. The rate expression expressed as 1 − (2 / 3)x − (1 − x)^2 / 3 where x is a fraction of iron dissolution was found to be proportional to [oxalate]^1.5.The addition of magnetite to the leach liquor at 10% w/w hematite was found to enhance the dissolution rate dramatically. Such addition of magnetite allows coarser hematite in the range 0.5–1.4 mm to be leached at a reasonable rate.  相似文献   

Effect of polypropylene fibre and lime admixture on engineering properties of clayey soil   总被引：2，自引：0，他引：2  

Yi Cai  Bin Shi  Charles W.W. Ng  Chao-sheng Tang 《Engineering Geology》2006,87(3-4):230-240

In order to reduce the brittleness of soil stabilized by lime only, a recent study of a newly proposed mixture of polypropylene fibre and lime for ground improvement is described and reported in the paper. To investigate and understand the influence of the mixture of polypropylene fibre and lime on the engineering properties of a clayey soil, nine groups of treated soil specimens were prepared and tested at three different percentages of fibre content (i.e. 0.05%, 0.15%, 0.25% by weight of the parent soil) and three different percentages of lime (i.e. 2%, 5%, 8% by weight of the parent soil). These treated specimens were subjected to unconfined compression, direct shear, swelling and shrinkage tests. Through scanning electron microscopy (SEM) analysis of the specimens after shearing, the improving mechanisms of polypropylene fibre and lime in the soil were discussed and the observed test results were explained. It was found that fibre content, lime content and curing duration had significant influence on the engineering properties of the fibre–lime treated soil. An increase in lime content resulted in an initial increase followed by a slight decrease in unconfined compressive strength, cohesion and angle of internal friction of the clayey soil. On the other hand, an increase in lime content led to a reduction of swelling and shrinkage potential. However, an increase in fibre content caused an increase in strength and shrinkage potential but brought on the reduction of swelling potential. An increase in curing duration improved the unconfined compressive strength and shear strength parameters of the stabilized soil significantly. Based on the SEM analysis, it was found that the presence of fibre contributed to physical interaction between fibre and soil whereas the use of lime produced chemical reaction between lime and soil and changed soil fabric significantly.  相似文献   

T -distributed Random Fields: A Parametric Model for Heavy-tailedWell-log Data1     

Jo R?islien  Henning Omre 《Mathematical Geology》2006,38(7):821-849

Histograms of observations from spatial phenomena are often found to be more heavy-tailed than Gaussian distributions, which makes the Gaussian random field model unsuited. A T-distributed random field model with heavy-tailed marginal probability density functions is defined. The model is a generalization of the familiar Student-T distribution, and it may be given a Bayesian interpretation. The increased variability appears cross-realizations, contrary to in-realizations, since all realizations are Gaussian-like with varying variance between realizations. The T-distributed random field model is analytically tractable and the conditional model is developed, which provides algorithms for conditional simulation and prediction, so-called T-kriging. The model compares favourably with most previously defined random field models. The Gaussian random field model appears as a special, limiting case of the T-distributed random field model. The model is particularly useful whenever multiple, sparsely sampled realizations of the random field are available, and is clearly favourable to the Gaussian model in this case. The properties of the T-distributed random field model is demonstrated on well log observations from the Gullfaks field in the North Sea. The predictions correspond to traditional kriging predictions, while the associated prediction variances are more representative, as they are layer specific and include uncertainty caused by using variance estimates.  相似文献   

萨拉乌苏河流域萨拉乌苏组沙丘砂沉积特征   总被引：7，自引：1，他引：7  

欧先交  李保生  靳鹤龄  吴正  温小浩  董光荣  曾兰华  欧阳椿陶  杨艺  刘宇飞 《地理学报》2006,61(9):965-975

萨拉乌苏河流域米浪沟湾剖面萨拉乌苏组含7层古流动沙丘砂、4层古固定-半固定沙丘砂.对这些沙丘砂的沉积构造观察以及粒度、扫描电镜和常量化学元素分析结果表明：（1）这些沙丘砂具有与现代沙丘砂相似的风成沉积构造特征;（2）粒度及其参数——Mz、σ、Sk和Kg,以及主要化学组分SiO2、Al2O3和TOFE也与现代沙丘砂相近;（3）Mz-σ、SiO2-Al2O3＋TOFE散点图和概率累积曲线显示这些沙丘砂与萨拉乌苏组中的河湖相、古土壤差别明显,而与现代沙丘砂一致;（4）石英砂颗粒具有良好的磨圆以及碟形坑、新月形坑、麻坑、上翻解理薄片、硅质沉淀和硅质裂纹等表面结构特征,反映其曾受持久的风力搬运作用.沉积构造、粒度、石英砂颗粒表面结构和化学元素等多个方面具备了与现代沙丘砂类似的风成特征,证明这些沙丘砂的成因是风成的.  相似文献   

Late Early Miocene lake deposits near Mauensee, central Switzerland: Fish fauna (otoliths, teeth), accompanying biota and palaeoecology     

Jürg Jost  Daniel K?lin  Tanja Schulz-Mirbach  Bettina Reichenbacher 《Eclogae Geologicae Helvetiae》2006,99(3):309-326

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柴达木盆地西部尕斯库勒油田E₃1油藏成藏条件与机制     

段毅  彭德华  张辉  吴保祥  郑朝阳  王传远 《沉积学报》2005,23(1):150-155

柴达木盆地西部原油为盐湖相未成熟-低成熟原油,属于典型的原油成因类型。尕斯库勒油田是柴达木盆地西部最大的油田。从油气生成运移、聚集成藏诸方面,较为系统地研究了该油田中E1₃ 油藏的形成条件,动态地探讨了油藏的形成机制,为该油藏的成因认识和进一步勘探开发提供了科学依据。  相似文献   

基于PGNAA技术在线分析系统的应用     

何伶俐  庹先国  穆克亮  曾旖  李向阳 《物探化探计算技术》2005,27(4):317-320

近年来,随着核探测与分析技术的日趋成熟,使复杂γ谱的获取、解析达到了在线测量的要求,从而使在线PGNAA(中子活化瞬发γ射线分析)技术获得了飞速的发展。它可对一些工业生产过程中的全物料进行在线测量,其分析精度、可靠性等皆能满足在线元素含量分析的需要,因而显示出巨大的发展潜力和广阔的市场前景。这里介绍了基于PGNAA技术的在线分析系统的基本原理、组成和发展,并概述了它在水泥、煤炭等行业的应用情况。  相似文献   

克鲁伦凹陷大磨拐河组沉积体系演化与赋铀性     

张志杰  于兴河  陈占坤  郭庆银  罗毅  张传恒 《铀矿地质》2005,21(1):23-29

克鲁伦凹陷下白垩统大磨拐河组是海拉尔盆地寻找可地浸砂岩型铀矿的目的层。大磨拐河组主要发育冲积扇、扇三角洲和湖相 3种沉积体系。根据沉积环境和沉积物特征 ,可将冲积扇划分为扇根、扇中和扇端 3种亚相 ;扇三角洲划分为上扇三角洲平原、下扇三角洲平原、扇三角洲前缘和前扇三角洲亚相。凹陷北缘发育两个扇体 ,扇三角洲体系和冲积扇体系之间在不同时期可相互转化。区内的陆源粗碎屑沉积岩为铀的富集创造了有利条件 ,扇三角洲和冲积扇的主河道和分流河道是最有利于铀聚集的部位。  相似文献   

昆明市山地灾害风险分区及防治对策   总被引：2，自引：0，他引：2  

张云霞  朱杰勇  刘益 《云南地质》2005,24(1):114-121

通过地质灾害调查，认为昆明市地质灾害以泥石流、滑坡、崩塌为主。分析地质灾害时空分布及形成条件，从致灾因子角度，给出昆明市地质灾害风险区划，提出地质灾害防治对策。  相似文献