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281.
Mar Chiquita Coastal Lagoon is located on the Atlantic coast of Argentina, and it has been declared a Biosphere Reserve under the UNESCO Man and Biosphere Programme (MAB). This coastal lagoon constitutes an estuarine environment with a very particular behaviour and it is ecologically important due to its biological diversity. The aim of the present study was to evaluate the distribution and geochemical behaviour of several heavy metals in this coastal system, focusing on their distribution in both the dissolved phase (<0.45 μm) and the suspended particulate matter. Therefore, the general hydrochemical parameters (salinity, temperature, turbidity, pH and dissolved oxygen) and concentration of total particulate and dissolved metals (Cd, Cu, Ni, Zn, Fe, Pb, Cr and Mn) were measured along 2 years (2004–2006) at two different sites. As regards their distribution, hydrological parameters did not present any evidence of deviation with respect to historical values. Suspended particulate matter showed no seasonal variation or any relationship with the tide, thus indicating that in this shallow coastal lagoon neither tides nor freshwater sources regulate the particulate matter input. Heavy metals behaviour, both in dissolved and particulate phases did not reveal any relationship with tide or seasons. Mar Chiquita Coastal Lagoon showed a large input of dissolved and particulate metals, which is probably due to intensive agriculture within the drainage basin of this system.  相似文献   
282.
The 2008 Chaitén volcanic eruption generated significant changes in the channel morphology and large wood (LW) abundance along the fluvial corridor of the Blanco River, southern Chile. Comparisons of remote sensing images from the pre‐eruption (year 2005) and post‐eruption (years 2009 and 2012) conditions showed that in a 10.2 km long study segment the Blanco River widened 3.5 times from 2005 to 2009, and that the maximum enlargement was nine times the original width. Changes in channel width were lower between the years 2012 and 2009. The sinuosity and braiding indexes also changed between 2005 and 2009. After the eruption the channel sinuosity was higher and specific river reaches developed a braided pattern, but by 2012 the channel was recovering pre‐eruption characteristics. Huge quantities of LW were introduced to the study segment; individual LW per km of channel length were 1.6 and 74.3 in 2005 and 2009, respectively, and more than 30 log jams km?1 were observed in the year 2009. Between 2009 and 2012 the quantity of LW was very similar. Statistically significant relationships were found between the number of log jams and channel sinuosity and between the number of pieces of large wood with sinuosity and channel width. Wood was highly dynamic between 2009 and 2012: 78% of individual pieces and 48% of log jams identified in the 2009 image had moved by 2012. Finally the supervised classification of imagery associated with ArcMap tools was tested to identify large wood.  相似文献   
283.
The purpose of this research is to analyze the seismostratigraphic and paleoenvironmental features of an ancient fluvial deposit characterized by the presence of paleochannels and sedimentary structures in Bahía Blanca estuary, Argentina. To this end, high-resolution seismic methods were used. Paleochannels exhibiting v-shaped cuts were found at different topographic positions at the base of this deposit. It was observed that channel silting is indicative of the relative change of river base level and the consequent migration of fluvial tributaries. This alluvial deposit is composed of low compacted fine sand and its middle–upper facies is characterized by the presence of horizontal and discontinuous wavy reflectors. The upper boundary of this deposit is an erosive discontinuity resulting from Holocene sea-level rise during which the mouth of old fluvial courses underwent changes. The deposit was subsequently buried by sandy and clayey silt sediments. The paleodrainage at subbottom indicates that this deposit is associated with an ancient river mouth. Based on the seismostratigraphic and lithological characteristics and the paleochannel structures found in the study area, it can be concluded that the deposit analyzed is an alluvial sequence formed in the period from the Middle-Late Pleistocene to Holocene marine transgression.  相似文献   
284.
This study analyses the perceptions of Zoque indigenous men and women of changes in climate variability, indicated by rainfall and temperature records from the region. Peasant farmers perceive decreases in rainfall and increases in temperature as these factors are related to modifications in the corn planting season and the introduction of crops which were usually only found in hot regions. The climate changes in the zone are attributed to vegetation loss and the eruption of the Chichón volcano in 1982. The Zoque perception is structured according to cultural and individual experience, tied to agriculture and the annual weather calendar. The volcanic eruption offers a significant chronological reference point in order to explain different environmental transformations, such as climate, within Zoque territory. Perception is the mental picture of local climate variability changes and the responses in seasonal agriculture modifications, utilizing individual and cultural experiences which are vulnerable to economic and environmental change.  相似文献   
285.
Variability of fish assemblages across habitat structures can depend on spatial scales. A hierarchical sampling design was used to assess the spatial variability of temperate fish assemblages in different habitats and at multiple scales. Underwater visual censuses were carried out along the coasts of Elba Island (NW Mediterranean) on Posidonia oceanica beds, rocky algal reefs and sandy habitat at three spatial scales, namely tens of metres (individual replicates), hundreds of metres (sites) and tens of kilometres (locations). At the assemblage level, there was a clear relationship between fish and habitat type and the observed habitat‐related differences were largely dependent on species identity. Fish assemblages on P. oceanica beds and rocky reefs shared a high number of species, whereas overlap with sandy assemblages was negligible. Multivariate analyses revealed significant differences in fish assemblages among habitats, although there was also a significant habitat × site interaction. These differences relied mainly upon assemblage composition and species richness. Assemblages on rocky reefs and P. oceanica meadows usually harboured a higher number of species and individuals compared with sandy assemblages. Nevertheless, the patterns of habitat‐related differences in species richness and, especially, in the total number of fish, changed significantly from site to site. Eight species showed significant differences over habitats, but they were not consistent due to the interaction of habitat with site. Predictability of fish at both assemblage and population levels decreased with the scale of observation, and the spatial pattern of fish observed at the smallest scale was likely dependent on factors other than habitat type.  相似文献   
286.
Most fisheries management studies have concentrated on understanding resource dynamics and have paid less attention to understanding the dynamics of those who use the resources. This situation limits the knowledge about the fisheries system as a whole and specifically about the viability of management schemes. It is vital to understand how the actors within the fishing sector (fishing firm owners/managers, fishers, fisheries managers, and traders) may respond to changes in fishing resources trends, market dynamics, and fisheries policies before they are implemented. These issues are explored in this paper by applying a longitudinal analysis of the Yucatan Mexico's fishing industry. The analysis is presented within the framework of the theory of change and coping strategies. The study primarily involved interviews during 2008 with the main owners of companies in the fishing industry and with fisheries managers and other stakeholders. Time-series catch data on the main fishing resources are also reviewed to evaluate changes across three historical periods and describe how the actors have perceived and responded to those changes. Given conditions of uncertainty in resource availability, changes in market demand and changes in institutional arrangements, the viability of traditional business and resource management practices are discussed. The analysis presents different kind of triggers that have modified the conditions of the fishing sector and had had impacts on the socio-economic–ecological system in which fisheries are embedded. The need for adaptive strategies in the whole chain of the fisheries business and resource management is stressed, given the current changes and conditions of fisheries. The discussion states a series of actions that could improve the relationships between business practices and fisheries management.  相似文献   
287.
Coronal radio-sounding experiments were carried out using the S-band (2.3 GHz) and X-band (8.4 GHz) signals of the ESA Mars Express, Venus Express, and Rosetta spacecraft during five superior conjunctions occurring in 2004, 2006 (3×), and 2008/2009. Differential frequency and propagation delay (ranging) observations were recorded during these opportunities over the better part of a solar cycle, yielding information on the large-scale structure of the coronal electron-density distribution and its variations, including fluctuations on time scales from seconds to hours. These results concern primarily regions of slow solar wind because the radio propagation path is generally confined to the low heliolatitude regions by the conjunction. The mean frequency fluctuation and total electron content are determined as a function of heliocentric distance, and, with a few exceptions caused by streamers and CMEs, are found to be consistent with previous results from experiments on Ulysses. Dense coronal streamers and several coronal mass ejection (CME) events were identified in the radio-frequency data, some of which were observed in white light by the LASCO coronagraphs onboard SOHO. For those events with sufficient mutual coverage, good correlations are found between the electron-content fluctuations and structure imaged by the LASCO instrument.  相似文献   
288.
Besides the enormous improvement of air quality in Germany due to the reduction of sulphur dioxide emissions in the last decades, high immissions of nitrogen oxides and fine particulate matter are frequently observed at traffic-rich urban sites. The changed chemical composition of air pollution requires a new investigation of its impact on historic buildings constructed of natural stone. In a pilot study a multi-disciplinary approach was chosen to obtain information on the actual pollution situation of historic buildings and monuments at traffic hotspots in Germany. The study concentrated on the two German cities of Munich and Mainz of different size, traffic volume and stone inventory. Dose–response functions were calculated to demonstrate the change of impact of different pollutants over the last three decades, and for comparison of traffic hotspots and housing areas of both cities. Numeric modelling on a city-scale was used to identify the historic buildings and monuments affected by elevated traffic immissions. Because a relevant part of these pollutants is dominated by short-range transport, the differences of wind speed and deposition rates were calculated using a street-scale 3D flow and dispersion model regarding traffic volume, wind regime and adjacent buildings. Finally, particulate matter was sampled at different positions of two buildings heavily exposed to traffic emissions. Individual particles were investigated by environmental scanning electron microscopy. After classification of the particles into different chemical groups, the fraction of traffic-induced particulate matter was quantified. Summarizing the results, it must be stated that soiling by traffic-related particulate matter, deposition of nitrates deriving from exhaust emission and other diffusely emitted components bear a severe damage potential for natural building stone at least locally at traffic-rich urban sites.  相似文献   
289.
The thiol peptide phytochelatins (PC2; the polymer with n = 2) are efficient metal-chelating compounds produced by phytoplankton and higher plants. Both PC2 and their precursor glutathione (GSH) are related to detoxification mechanisms. GSH and PC2 were quantified using liquid chromatography with fluorescent detection and observed in the particulate phase along a salinity gradient of the Tamar Estuary (SW UK), a heavily metal impacted site, at concentrations up to 274 and 16.5 μmol (g chl a)−1, respectively. The peptides predominated within low (0–5) and mid-salinities (5–20). Down-estuary, at sites farther from metal sources and salinities higher than 20, PC2 showed a sharp decrease or were not detected. High PC2/GSH ratios indicated areas with augmented concentrations of bioavailable metals at the tidal limit, near Cu mines and the mid-estuary where resuspension of sediments occurs. By following typical partitioning patterns previously reported for dissolved Cu and Zn, the production of thiol peptides, notably PC2, reflected a rapid interaction between the particulate and dissolved phases.  相似文献   
290.
The toxicity and potential bioavailability of heavy metals were studied in sewage sludge-amended ferralsols and chernosols, using bioassays with earthworms (Eisenia andrei). Acute toxicity tests and avoidance assays were performed according to standard protocols. Potentially bioavailable concentrations of heavy metals were estimated by quantifying their concentrations in tissues of survival earthworms. The results revealed that soil properties played an important role in the toxicity and bioavailability of heavy metals. In this respect, higher levels of toxicity were detected for the ferralsol. The abundance of 2:1 clay minerals, high fertility and more basic values of pH seem to be very important in the reduction of toxicity levels for earthworms. Organisms exposed to the chernosols were able to uptake higher amount of metals. In that case, higher contents of nutrients in chernosols may have influenced such bioavailability processes. Avoidance responses were the most sensible indicator of toxicity. In the near future, such data can subsidize the establishment of toxic reference concentrations able to reflect the characteristics of important tropical pedological occurrences, supporting the definition of sustainable indicators for using sewage sludge in the tropical agriculture.  相似文献   
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