Sardignaite, a new mineral, the second known bismuth molybdate: description and crystal structure     

Paolo Orlandi  Marco Pasero  Simona Bigi 《Mineralogy and Petrology》2010,100(1-2):17-22

The new mineral sardignaite, a bismuth molybdate with formula BiMo₂O₇(OH)·2H₂O, occurs in quartz veins within a granitic rock at Su Senargiu, near Sarroch, Sardegna, Italy. The name is after the locality. Sardignaite occurs a thin prismatic crystals up to 1 mm in length, with pale yellow color and a white streak. It is transparent with adamantine lustre, non fluorescent, and brittle with a conchoidal fracture. It is associated with bismuthinite, bismoclite, molybdenite, ferrimolybdite, koechlinite, wulfenite, and the new mineral IMA 2009–022. Mohs hardness is ca. 3. D _calc is 4.82 g/cm³. The mineral is monoclinic, space group P2₁/m, with a 5.7797(7), b 11.567(1), c 6.3344(8) Å, β 113.360(9)°, V 388.8(1) ų. The strongest lines in the powder X-ray diffraction pattern are d(I)(hkl): 3.206(100)(031), 5.03(80)(?101), 1.992(45)(221), 3.120(32)(130). The crystal structure of sardignaite was solved to R(F) 0.056 using single-crystal X-ray diffraction data, and is characterized by edge-sharing dimers of [MoO₅(H₂O)] octahedra, linked to each other through corner-sharing to give rise to corrugated columns running along b. Such columns are held together by Bi³⁺ cations, eight-fold coordinated by 7 O + 1 (OH). Both the mineral and its name were approved by the IMA-CNMNC.  相似文献   

Intermediate Alkali-Alumino-silicate Aqueous Solutions Released by Deeply Subducted Continental Crust: Fluid Evolution in UHP OH-rich Topaz-Kyanite Quartzites from Donghai (Sulu, China)   总被引：3，自引：0，他引：3  

Frezzotti  Maria Luce; Ferrando  Simona; Dallai  Luigi; Compagnoni  Roberto 《Journal of Petrology》2007,48(6):1219-1241

Minerals, fluid inclusions and stable isotopes have been studiedin ultrahigh-pressure (UHP) OH-rich topaz–kyanite quartzitesfrom Hushan (west of Dongai), in southern Sulu (China). Thequartzites underwent a metamorphic evolution characterized bya peak stage (3·5 GPa and 730–820°C) with theanhydrous assemblage coesite + kyanite I, followed by an earlynear-isothermal decompression stage (2·9 GPa and 705–780°C)with growth of kyanite II, muscovite, and OH-rich topaz, andby decompression-cooling stages, represented by paragonite (1·9GPa and 700–780°C) and pyrophyllite (0·3 GPaand 400°C) on kyanite (I and II) and OH-rich topaz, respectively.These rocks may exhibit unusually low ¹⁸O and D values acquiredbefore undergoing UHP metamorphism. Five distinct fluid generationsare recognized. Type I: concentrated peak solutions rich inSi, Al, and alkalis, present within multiphase inclusions inkyanite I. Type II: CaCl₂-rich brines present during the growthof early retrograde OH-rich topaz. Type III, IV, and V: lateaqueous fluids of variable salinity, and rare CO₂ present duringamphibolite- and late greenschist-facies conditions. A numberof conclusions may be drawn from these relationships that havean effect on fluid evolution in deeply subducted continentalrocks. (1) At a pressure of about 3·5 GPa alkali–alumino-silicateaqueous solutions, with compositions intermediate between H₂Ofluid and melt (H₂O > 25 and 50 wt %) evolved from quartzites,probably generated by dehydration reactions. (2) During earlydecompression stages, at the transition from UHP to high-pressure(2·9 GPa) conditions, brines of external origin withhigher water contents (82 wt % H₂O) initiated the growth ofOH-rich topaz and muscovite. (3) The subsequent decompression,at P <2 GPa, was defined by a limited circulation of NaClaqueous fluids, and CO₂ infiltration. Overall, fluid inclusionsand stable isotopes highlight a metamorphic fluid–rockinteraction characterized by internally derived intermediateaqueous solutions at UHP, followed by infiltration of Cl-richbrines with higher water activities. KEY WORDS: ultrahigh-pressure metamorphism; OH-rich topaz; fluid inclusions; stable isotopes; supercritical liquids  相似文献   

A temperature dependent X-ray Absorption Fine Structure study of dynamic X-site disorder in almandine: a comparison to diffraction data     

Simona Quartieri  G. Antonioli  G. Artioli  C. A. Geiger  P. P. Lottici 《Physics and Chemistry of Minerals》1997,24(3):200-205

X-ray Absorption Fine-Structure (XAFS) measurements in the temperature range 20-473K at the Fe K-edge of synthetic almandine (Fe₃Al₂Si₃O₁₂) allow us to determine the temperature dependence of the XAFS Debye-Waller (DW) factors for each of the two crystallographically independent Fe?O bond distances (Fe(1)?O and Fe(2)?O). The vibrational anisotropy of Fe²⁺ in the dodecahedral X-site has been documented. The XAFS DW factor of the longer Fe(2)?O bond is larger and has a greater T-dependence than the shorter Fe(1)?O bond, which remains constant over the measured T range. The XAFS DW factors are compared with the uncorrelated part of the DW factors derived from a single-crystal X-ray diffraction (XRD) study on almandine and are interpreted on the basis of the Einstein model. A comparison with diffraction data shows that the shorter Fe(1)–O bond is significantly affected by correlation in the atomic displacements.  相似文献   

Impact of extreme CO2 levels on tropical climate: a CGCM study     

Annalisa Cherchi  Simona Masina  Antonio Navarra 《Climate Dynamics》2008,31(7-8):743-758

A coupled general circulation model has been used to perform a set of experiments with high CO₂ concentration (2, 4, 16 times the present day mean value). The experiments have been analyzed to study the response of the climate system to strong radiative forcing in terms of the processes involved in the adjustment at the ocean–atmosphere interface. The analysis of the experiments revealed a non-linear response of the mean state of the atmosphere and ocean to the increase in the carbon dioxide concentration. In the 16 × CO₂ experiment the equilibrium at the ocean–atmosphere interface is characterized by an atmosphere with a shut off of the convective precipitation in the tropical Pacific sector, associated with air warmer than the ocean below. A cloud feedback mechanism is found to be involved in the increased stability of the troposphere. In this more stable condition the mean total precipitation is mainly due to large-scale moisture flux even in the tropics. In the equatorial Pacific Ocean the zonal temperature gradient of both surface and sub-surface waters is significantly smaller in the 16 × CO₂ experiment than in the control experiment. The thermocline slope and the zonal wind stress decrease as well. When the CO₂ concentration increases by about two and four times with respect to the control experiment there is an intensification of El Niño. On the other hand, in the experiment with 16 times the present-day value of CO₂, the Tropical Pacific variability weakens, suggesting the possibility of the establishment of permanent warm conditions that look like the peak of El Niño.  相似文献   

Crash-testing the cauldron code for joint lensing and dynamics analysis of early-type galaxies     

Matteo Barnabè  Carlo Nipoti  Léon V. E. Koopmans  Simona Vegetti  Luca Ciotti 《Monthly notices of the Royal Astronomical Society》2009,393(4):1114-1126

We apply the joint lensing and dynamics code for the analysis of early-type galaxies, 'Combined Algorithm for Unified Lensing and Dynamics ReconstructiON ( cauldron )', to a rotating N -body stellar system with dark matter halo which significantly violates the two major assumptions of the method, i.e. axial symmetry supported by a two-integral distribution function. The goal is to study how cauldron performs in an extreme case, and to determine which galaxy properties can still be robustly recovered. Three data sets, corresponding to orthogonal lines of sight, are generated from the N -body system and analysed with the identical procedure followed in the study of real lens galaxies, adopting an axisymmetric power-law total density distribution. We find that several global properties of the N -body system are recovered with remarkable accuracy, despite the fact that the adopted power-law model is too simple to account for the lack of symmetry of the true density distribution. In particular, the logarithmic slope of the total density distribution is robustly recovered to within less than 10 per cent (with the exception of the ill-constrained very inner regions), the inferred angle-averaged radial profile of the total mass closely follows the true distribution, and the dark matter fraction of the system (inside the effective radius) is correctly determined within ∼10 per cent of the total mass. Unless the line-of-sight direction is almost parallel to the total angular momentum vector of the system, reliably recovered quantities also include the angular momentum, the   V /σ  ratio and the anisotropy parameter δ. We conclude that the cauldron code can be safely and effectively applied to real early-type lens galaxies, also providing reliable information for the systems that depart significantly from the method's assumptions.  相似文献   

A cathodoluminescence and petrographical study of marbles from the Pohorje area in Slovenia     

Simona Jarc  Nina Zupancic 《Chemie der Erde / Geochemistry》2009,69(1):75-80

Marbles from the Pohorje area in Slovenia are investigated by mineralogical-petrographical analyses of thin sections as well as by cathodoluminescence in order to detect their local variability in texture and mineral assemblages. The CL colours observed in a cold cathode device are related to the manganese contents. An attempt is made to relate the textures seen under CL to mineral reactions during the process of metamorphism. The predominantly calcite marbles from Pohorje exhibit orange luminescence with some dolomite lenses with red luminescence. The typical mineral assemblages are calcite+tremolite+phlogopite or calcite+dolomite+tremolite+phlogopite. Therefore, the estimated temperature from the stability of mineral assemblage is assumed at approximately 500 °C.  相似文献   

Another Year of Record Heat for the Oceans     

Lijing CHENG  John ABRAHAM  Kevin E.TRENBERTH  John FASULLO  Tim BOYER  Michael E.MANN  Jiang ZHU  Fan WANG  Ricardo LOCARNINI  Yuanlong LI  Bin ZHANG  Fujiang YU  Liying WAN  Xingrong CHEN  Licheng Feng  Xiangzhou SONG  Yulong LIU  Franco RESEGHETTI  Simona SIMONCELLI  Viktor GOURETSKI  Gengxin CHEN  Alexey MISHONOV  Jim REAGAN  Guancheng LI 《大气科学进展》2023,40(6):963-974

Changes in ocean heat content(OHC), salinity, and stratification provide critical indicators for changes in Earth’s energy and water cycles. These cycles have been profoundly altered due to the emission of greenhouse gasses and other anthropogenic substances by human activities, driving pervasive changes in Earth’s climate system. In 2022, the world’s oceans, as given by OHC, were again the hottest in the historical record and exceeded the previous 2021 record maximum.According to IAP/CAS data, ...  相似文献   

Carbonate slope re-sedimentation in a tectonically-active setting (Western Sicily Cretaceous Escarpment,Italy)     

Vincenzo Randazzo  Johan Le Goff  Pietro Di Stefano  John Reijmer  Simona Todaro  Maria Simona Cacciatore 《Sedimentology》2020,67(5):2360-2391

Tectonic processes are widely considered as a mechanism causing carbonate platform margin instabilities leading to the emplacement of mass transport deposits and calciturbidites. However, only few examples establishing a clear link between tectonics and re-sedimentation processes are known from the literature. The two-dimensional and three-dimensional wire-cut walls of hundreds of quarries extracting ornamental limestones (for example, Perlato di Sicilia) from the Western Sicily Cretaceous Escarpment in Italy expose a series of mass transport deposits. The depositional architecture, spatial facies distribution and sedimentary features of these deposits were studied in detail. Thin section analysis was used to define the microfacies characteristics and to determine the age of the re-sedimented limestones. Eleven facies types grouped into four facies associations were recognized that defined specific depositional processes and environments. The stratigraphic architecture of the slope was reconstructed using four composite facies successions based on the detailed analysis and correlation of the field sections. The palaeoslope orientation was reconstructed based on the analysis of synsedimentary faults, slump scars and pinch-out geometries. The Western Sicily Cretaceous Escarpment was strongly influenced by synsedimentary transtensional tectonics in combination with magmatic processes, as suggested by the presence of tuffites and pillow lava intercalations within the re-sedimented carbonate series. These volcanics point to a major role of crustal shear as a trigger for mass transport deposit emplacement. The facies distribution along the Western Sicily Cretaceous Escarpment delivers new insights into the deformation processes accompanying the crustal extension of the Cretaceous western Tethys realm.  相似文献   

Removal of uranium(VI) from the aqueous phase by iron(II) minerals in presence of bicarbonate     

Simona Regenspurg  Dieter Schild  Thorsten Schfer  Florian Huber  Maria E. Malmstrm 《Applied Geochemistry》2009,24(9):1617-1625

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Performance and Characteristics of Aerobic Granular Sludge Degrading 2,4,6‐Trichlorophenol at Different Volumetric Organic Loading Rates          下载免费PDF全文

Stefano Milia  Roberta Porcu  Simona Rossetti  Alessandra Carucci 《洁净——土壤、空气、水》2016,44(6):615-623

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