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81.
The anisotropy of magnetic susceptibility (AMS) and rock magnetic properties were measured on specimens from a basalt plate that was cut from a vertical section of a basalt column from Hrepphólar, Iceland. Macroscopic structures are clearly distinguishable in the plate, including banding inferred to represent viscous fingering parallel to the vertical axis of the column. Rock magnetic experiments indicate that the dominant ferromagnetic (sensu lato) mineral is titanomagnetite, Fe 3?x Ti x O4, with a Ti-composition of x?=?~0.6. Magnetic properties are related to the position within the plate and reveal a dominant volume fraction of single domain titanomagnetite in the center of the basalt column, with multidomain titanomagnetite away from the center. The AMS determined by low-field measurements shows an inconclusive relationship with the visual structures, which arises from variation of the grain size (i.e., single domain versus multidomain) across the column. In contrast, the AMS measured with a high-field torsion magnetometer avoids the complication of magnetic domain state, as is demonstrated in this contribution, and additionally allows for the separation of ferrimagnetic from paramagnetic sub-fabrics. Both sub-fabrics display a clear relationship with the macroscopic structures and support the hypothesis that vertical flow of melt took place during development of the Hrepphólar columnar basalt. Maximum susceptibility axes of the ferrimagnetic sub-fabric are grouped near the vertical axis of the column. The paramagnetic sub-fabric varies systematically across the column in coincidence with internal structure. The shape of the magnetic susceptibility ellipsoid varies across the basalt column, showing an increasingly prolate fabric toward its center.  相似文献   
82.
83.
Tufa sediments are freshwater carbonates that precipitate in karst regions after degassing of carbon dioxide from groundwater in contact with the atmosphere. When laminated, these carbonates can provide high‐resolution records for the study of climate, hydrological and environmental conditions at the time of their precipitation. The formation of these carbonates directly depends on the hydrological regime, and in karst regions discontinuous discharges are often recorded. This study investigates the record of recent laminated tufa sediments precipitated downstream overflow springs in Trabaque Canyon (central Spain). The hydrological dynamics of the karst system were monitored for over three years and a stable isotope record was obtained from laminated tufa carbonates precipitated from an overflow spring. Additionally, a hydrological model of overflow springs was generated and a tufa δ18O record under constrained parameters was simulated. Temperature is the dominant control of the variation in tufa δ13C and δ18O values within each lamina, although when comparing different laminae, δ13CDIC and δ18O of river water are also major controls. The positive correlation between tufa δ13C values and water temperature is caused by the fractionation occurred by carbon dioxide degassing due to the thermal dependence of carbon dioxide solubility. Additionally, the system recorded a temperature‐independent degassing process caused by the large gradient between groundwater and atmospheric carbon dioxide that is limited to the proximity of the spring. This study cautions on the risk of assuming continuous deposition when studying laminated tufa sediments and highlights the potential of their stable isotope records to provide hydrological information of their aquifers during the past.  相似文献   
84.
Abstract— We present a purely physical model for the calculation of depth‐ and size‐dependent production rates of cosmogenic nuclides by galactic cosmic‐ray (GCR) particles. besides the spectra of primary and secondary particles and the excitation functions of the underlying nuclear reactions, the model is based on only one free parameter—the integral number of gcr particles in the meteoroid orbits. We derived this value from analysis of radionuclide data in Knyahinya. We also show that the mean GCR proton spectrum in the meteoroid orbits has been constant over about the last 10 Ma. For the major target elements in stony meteoroids, we present depth‐ and size‐dependent production rates for 10Be, 14C, 26Al, 36Cl, and 53Mn as well as for the rare gas isotopes 3He, 20Ne, 21Ne, 22Ne, 36Ar, and 38Ar. The new data differ from semi‐empirical estimates by up to a factor of 4 but agree within ~20% with results obtained by earlier parametric or physical approaches. The depth and size dependence of the shielding parameter 22Ne/21Ne and the correlations 26Al vs. 10Be, 26Al vs. 53Mn, 10Be/21Ne vs. 22Ne/21Ne, and 36Ar vs. 36Cl for deciphering preatmospheric sizes, shielding depths, terrestrial residence times, and exposure histories are also discussed.  相似文献   
85.
The Campi Flegrei (Campanian Region, Italy) experienced two cataclysmic caldera-forming eruptions which produced the Campanian Ignimbrite (39 ka, CI) and the Neapolitan Yellow Tuff (15 ka, NYT). We studied the minor eruptions before both these large events to understand magma chamber evolution leading towards such catastrophic eruptions. Major, trace element, and Sr and Nd isotope compositions of pre-Campanian Ignimbrite and pre-Neapolitan Yellow Tuff products define distinct geochemical groups, which are here interpreted as distinct magma batches. These batches do not show any transitional trend towards the CI and NYT eruptions. The CI and NYT systems are decoupled geochemically and isotopically. At least one of the pre-CI and one of the pre-NYT erupted magma batches qualifies as mixing endmembers for the large CI and NYT eruptions, and thus, must have been stored in reservoirs for some time to remain available for the CI and NYT eruptions. The least evolved, isotopically distinct magma compositions that are typical of the last phases of the NYT and CI eruptions did not occur before caldera-forming events. Based on the new data, we propose the following scenario: Multiple magma chambers with distinct compositions existed below the Campi Flegrei before the CI and NYT eruptions and remained generally separated for some time unless new magma was recharged. In each case, one of the residing magma reservoirs was recharged by a new large-volume magma input of intermediate composition from a deeper differentiating magma reservoir. This may have triggered the coalescence of the previously separated reservoirs into one large chamber which fed the cataclysmic caldera-forming eruption. Large magma chambers in the Campi Flegrei may therefore be ephemeral features, interrupted by periods of evolution in individual, separated magma reservoirs.  相似文献   
86.
Population growth, urban sprawl and a high degree of car dependency as well as slowly rising petrol prices contribute towards increasing challenges for everyday urban mobility in Muscat, Oman. Until now, only a few empirical studies have dealt with urban mobility in Oman. Therefore, this article draws mainly on our own empirical findings to answer the following questions: What do daily and weekly mobility patterns look like in Muscat? How do these practices differ depending on the social position of the household, i.e. their nationality, income and education? Which interdependent effects can be discerned between everyday mobility practices and the fragmented and segregated urban structures? Since our research questions focus on the interrelations between urban structures and individual mobility, we chose a mixed‐methods approach including methods derived both from social and spatial research. This article in particular draws on our quantitative survey covering 850 households and extensive mappings of three selected case study areas and secondary data analysis.  相似文献   
87.
Olivine, clinopyroxene and orthopyroxene in variably metasomatised peridotite xenoliths from three lithospheric mantle sections beneath the East African Rift in Tanzania (Lashaine, Olmani, Labait) show systematic differences in their average Li concentrations (2.4 ppm, 2.0 ppm and 1.5 ppm, respectively) and intermineral isotopic fractionations, with olivine being heaviest (δ7Li = + 2.3 to + 13.9‰, average + 5.0‰), followed by orthopyroxene (? 4.1 to + 6.5‰, average + 0.8‰) and clinopyroxene (? 6.7 to + 4.1‰, average ? 1.6‰). These features are ascribed to the effects of kinetic Li isotope fractionation combined with different Li diffusivities in mantle minerals.Two main mechanisms likely generate diffusion-driven kinetic Li isotope fractionation in mantle xenoliths (1) Li diffusion from grain boundary melt into minerals during recent metasomatism or entrainment in the host magma and (2) subsolidus intermineral Li-redistribution. The latter can produce both isotopically light (Li-addition) and heavy (Li-loss) minerals and may occur in response to changes in pressure and/or temperature.Modelling shows that non-mantle-like δ7Li in clinopyroxene (< + 2‰), combined with apparent equilibrium olivine-clinopyroxene elemental partitioning in most peridotite xenoliths from all three Tanzanian localities probably reflects incipient Li addition during interaction with the host magma. Low δ7Li (< ? 3‰), combined with high Li concentrations (> 3 ppm) in some clinopyroxene may require very recent (minutes) Li ingress from a Li-rich melt (100s of ppm) having mantle-like δ7Li. This might happen during late fragmentation of some mantle xenoliths caused by a volatile- (and Li-) rich component exsolved from the host basalt. In contrast, high Li concentrations (> 2 ppm) and δ7Li (> 4‰) in olivine from many Labait and Olmani samples are attributed to an older, pre-entrainment enrichment event during which isotopic equilibrium was attained and whose signature was not corrupted during xenolith entrainment. Low Li concentrations and mantle-like isotopic composition of olivine from most Lashaine xenoliths indicate limited metasomatic Li addition.Thus, Li concentrations and isotope compositions of mantle peridotites worldwide may reflect two processes, with olivine mainly preserving a signature of depletion in refractory samples (low Li contents and δ7Li) or of older (precursory) melt addition in metasomatised samples (high Li contents and δ7Li), while non mantle-like, low δ7Li in almost all clinopyroxene can be due to Li ingress during transport in the host magma and/or slow cooling, if the samples were erupted in lavas. In Tanzania, the peridotites experienced rift-related heating prior to entrainment and were quenched upon eruption, so Li ingress is the most likely process responsible for the isotopically light clinopyroxene here.  相似文献   
88.
Snow is an important environmental factor in alpine ecosystems, which influences plant phenology, growth and species composition in various ways. With current climate warming, the snow-to-rain ratio is decreasing, and the timing of snowmelt advancing. In a 2-year field experiment above treeline in the Swiss Alps, we investigated how a substantial decrease in snow depth and an earlier snowmelt affect plant phenology, growth, and reproduction of the four most abundant dwarf-shrub species in an alpine tundra community. By advancing the timing when plants started their growing season and thus lost their winter frost hardiness, earlier snowmelt also changed the number of low-temperature events they experienced while frost sensitive. This seemed to outweigh the positive effects of a longer growing season and hence, aboveground growth was reduced after advanced snowmelt in three of the four species studied. Only Loiseleuria procumbens, a specialist of wind exposed sites with little snow, benefited from an advanced snowmelt. We conclude that changes in the snow cover can have a wide range of species-specific effects on alpine tundra plants. Thus, changes in winter climate and snow cover characteristics should be taken into account when predicting climate change effects on alpine ecosystems.  相似文献   
89.
The South Iceland Seismic Zone (SISZ) was loaded to failure in June 2000, resulting in two M6.6 earthquakes. The SISZ is an E–W‐trending zone with an overall sinistral movement. Numerical models indicate that, when the SISZ is loaded to failure, there are stress concentrations at its ends: tensile in the north‐east and south‐west quadrants, and compressive in the north‐west and south‐east quadrants. These model predictions fit well with observations. Geodetic measurements indicate considerable compression, uplift and associated intense seismicity in recent years in the volcanoes of Hengill and Eyjafjallajokull, located in the quadrants of compression, whereas there have been unusually frequent eruptions in the past decades in the Hekla Volcano, located in one of the quadrants of extension. The models predict that following the large June 2000 earthquakes, stress relaxation within the SISZ should lead to stopping of the intense seismicity and deformation in the volcanoes of Hengill and Eyjafjallajokull, again in agreement with observations. However, when similar episodes of deformation and seismicity start again, particularly in the Hengill Volcano, a large earthquake would be expected within several years in the SISZ. The numerical models, and the deformation and seismic data, indicate that monitoring of ‘soft’ inclusions such as volcanoes (many with magma chambers) in the vicinity of a seismic zone may serve as precursors to large earthquakes.  相似文献   
90.
Because of large economic and environmental asymmetries among world regions and the incentive to free ride, an international climate regime with broad participation is hard to reach. Most of the proposed regimes are based on an allocation of emissions rights that is perceived as fair. Yet, there are also arguments to focus more on the actual welfare implications of different regimes and to focus on a ‘fair’ distribution of resulting costs. In this article, the computable general equilibrium model DART is used to analyse the driving forces of welfare implications in different scenarios in line with the 2?°C target. These include two regimes that are often presumed to be ‘fair’, namely a harmonized international carbon tax and a cap and trade system based on the convergence of per capita emissions rights, and also an ‘equal loss’ scenario where welfare losses relative to a business-as-usual scenario are equal for all major world regions. The main finding is that indirect energy market effects are a major driver of welfare effects and that the ‘equal loss’ scenario would thus require large transfer payments to energy exporters to compensate for welfare losses from lower world energy demand and prices.

Policy relevance

A successful future climate regime requires ‘fair’ burden sharing. Many proposed regimes start from ethical considerations to derive an allocation of emissions reduction requirements or emissions allowances within an international emissions trading scheme. Yet, countries also consider the expected economic costs of a regime that are also driven by other factors besides allowance allocation. Indeed, in simplified lab experiments, successful groups are characterized by sharing costs proportional to wealth. This article shows that the major drivers of welfare effects are reduced demand for fossil energy and reduced fossil fuel prices, which implies that (1) what is often presumed to be a fair allocation of emissions allowances within an international emissions trading scheme leads to a very uneven distribution of economic costs and (2) aiming for equal relative losses for all regions requires large compensation to fossil fuel exporters, as argued, for example, by the Organization of Petroleum Exporting Countries (OPEC).  相似文献   
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