Drying effects on sorption capacity of coastal sediment: The importance of architecture and polarity of organic matter     

Zhanfei Liu  Cindy Lee 《Geochimica et cosmochimica acta》2006,70(13):3313-3324

Investigations on how desiccation changes sorption of organic compounds by salt marsh sediments provide insight into the physical and chemical properties of these wide-spread coastal sediments. We measured sorption of compounds with different polarities (lysine, tyrosine, naphthalene and aniline) onto natural sediments and sediments that were dried and rewetted. Sorption of lysine by marsh sediment decreased significantly when the sediment was dried using a freeze-drier, oven, or desiccator, and sorption capacity was not restored when sediments were rewetted. In contrast to lysine, the sorption capacity of more hydrophobic compounds (tyrosine, aniline and naphthalene) increased significantly after salt marsh sediment was dried. These results suggest that drying greatly increased sediment hydrophobicity. Consistently, water drop penetration time, an index of hydrophobicity, was significantly lower for combusted sediments than for those that were simply dried. Sediments treated with EDTA, or boiled in seawater, exhibited a similar or even greater reduction in lysine sorption capacity compared with sediments that were dried. Water retention capacity of salt marsh sediment decreased 50% after sediment was dried. The effects of pH and salinity on lysine sorption in wet and dry sediments suggest that carboxyl groups play a major role in lysine sorption through cation ion exchange, and drying may reduce access to carboxyl groups. We hypothesize that the three-dimensional (3D) structure of organic matter, originating mainly from Spartina alterniflora, is an important factor controlling sorption capacity in salt marsh sediment. The drying process makes sedimentary organic matter change conformation, shrink in volume, and expose hydrophobic groups, thus becoming more hydrophobic. In environments with wet and dry cycles, the distribution of hydrophobic or hydrophilic compounds between solution and particulate phases could thus be influenced by the 3D structure and polarity of organic matter.  相似文献   

Some breakage characteristics of ultra-fine wet grinding with a centrifugal mill     

Heechan Cho  Hoon LeeYeongwoo Lee 《International Journal of Mineral Processing》2006

A centrifugal mill is a high-power intensity media mill that can be used for ultra-fine grinding, employing centrifugal forces generated by gyration of the axis of the mill tube in a circle. The mill charge motion is quite different depending on the ratio of the gyration diameter to the mill diameter (G / D ratio), varying from a motion similar to that of a conventional tumbling media mill to that of a vibration mill. In this study, a centrifugal mill was constructed with an arrangement where the gyration diameter could be readily adjusted. The batch grinding characteristics of three different minerals (limestone, talc and illite) in water with dispersing agent were investigated at various G / D ratios. It was found that the optimum G / D ratio in terms of the specific energy consumption to give a desired fineness of product was different for the three minerals. This was due to their different reactions to the breakage mechanisms provided by the mill charge motion at varying G / D ratios. The size distributions became progressively narrower at increased grinding times, and particles finer than about 0.1 μm were not detected even for prolonged grinding times. Measurement of specific surface areas indicated that this was not due to an artifact of the size measurements by laser diffractometry. This implies that there is a limitation in which particles finer than 0.1 μm are not produced under the conditions tested in this type of mill, but further investigation is needed for experimental verification of this limit of comminution.  相似文献   

Study on the kinetics of iron oxide leaching by oxalic acid   总被引：2，自引：0，他引：2  

Suong Oh Lee  Tam Tran  Yi Yong Park  Seong Jun Kim  Myong Jun Kim   《International Journal of Mineral Processing》2006,80(2-4):144-152

The presence of iron oxides in clay or silica raw materials is detrimental to the manufacturing of high quality ceramics. Although iron has been traditionally removed by physical mineral processing, acid washing has been tested as it is more effective, especially for extremely low iron (of less than 0.1% w/w). However, inorganic acids such as sulphuric or hydrochloric acids easily contaminate the clay products with SO₄²⁻ and Cl⁻, and therefore should be avoided as much as possible. On the other hand, if oxalic acid is used, any acid left behind will be destroyed during the firing of the ceramic products. The characteristics of dissolution of iron oxides were therefore investigated in this study.The dissolution of iron oxides in oxalic acid was found to be very slow at temperatures within the range 25–60 °C, but its rate increases rapidly above 90 °C. The dissolution rate also increases with increasing oxalate concentration at the constant pH values set within the optimum range of pH2.5–3.0. At this optimum pH, the dissolution of fine pure hematite (Fe₂O₃) (105–140 μm) follows a diffusion-controlled shrinking core model. The rate expression expressed as 1 − (2 / 3)x − (1 − x)^2 / 3 where x is a fraction of iron dissolution was found to be proportional to [oxalate]^1.5.The addition of magnetite to the leach liquor at 10% w/w hematite was found to enhance the dissolution rate dramatically. Such addition of magnetite allows coarser hematite in the range 0.5–1.4 mm to be leached at a reasonable rate.  相似文献   

Structural similarity and variety at the tips in a wide range of strike–slip faults: a review     

Young‐Seog Kim  David J. Sanderson 《地学学报》2006,18(5):330-344

Strike–slip faults are often accompanied by a variety of structures, particularly at their tips. The zones of additional fracturing are classified as tip‐damage zones. These zones can be subdivided into several different damage patterns based on the nature and orientation of faults and fractures developed. Damage zones at the ends of small strike–slip faults (mode II tips) develop wing cracks, horsetail splays, antithetic faults, synthetic branch faults and solution surfaces. Similar tip‐damage patterns are also commonly observed at larger (regional) scales, but with a dominance of faulting over tensile cracks and solution surfaces. Wing cracks and horsetail splays developed at small‐scale faults are replaced by normal faults in large‐scale faults. Antithetic faults and synthetic branch faults are observed at small and large scales. Thrust faults are developed at large scales, in a similar pattern to solution surfaces at a small scale. All these structures may show slightly different angular relationships to the master fault at small and large scale, but develop in response similar stress distribution and mechanics around the fault. Thus, mode II tip‐damage zones show similar patterns over a wide range of fault scales.  相似文献   

Deformation-induced garnet zoning   总被引：1，自引：0，他引：1  

Hyeong Soo Kim   《Gondwana Research》2006,10(3-4):379-388

Compositional zoning patterns in garnet porphyroblasts from kyanite-bearing samples of the Devonian Littleton Formation, north-central Massachusetts, reveal complex patterns of growth that are related to multiple deformation and metamorphic events. Garnet porphyroblasts exhibit asymmetrical and irregular zoning patterns in X_Mn, X_Ca and Fe/(Fe + Mg). Zoning reversals in Mn and Fe/(Fe + Mg) and patch distribution in Ca appear to occur around the boundaries of the textural zones. Also, the compositions of the garnet at the textural boundaries are variable for all traverses. These observations suggest that the garnet zoning was not only modified from diffusion processes, but was also influenced by pre-existing microfabrics through the effects of preferential dissolution and resorption in partial disequilibrium. Relationships between chemical and textural truncations indicate that the zoning patterns of garnet were strongly modified from preferential dissolution and precipitation during the development of successive foliations that occurred in zones of high strain/stress (cleavage seams) and zones of low strain/stress, respectively.  相似文献   

Microvariability of line profiles in the spectrum of the star ι Her     

A. F. Kholtygin  G. A. Galazutdinov  T. E. Burlakova  G. G. Valyavin  S. N. Fabrika  B. -C. Lee 《Astronomy Reports》2006,50(3):220-231

We present the results of a search for and analysis of line-profile variations in the spectrum of the star ι Her. The observations were acquired with the 1.8 m telescope of the Bohyunsan Optical Astronomy Observatory (Republic of Korea) in May–June 2004. We obtained 69 spectra of the star with signal-to-noise ratios ≈300 and a time resolution of 5–7 min. Profile variability was revealed for six lines of HI, HeI, and SiIII, in the central parts of the lines. The variability amplitude is ≈(1–2)% in units of the intensity of the adjacent continuum. Evidence was found for cyclic variations of the lines, with periods from ≈7^h to ≈2.9^d. We conclude that ι Her belongs to the group of slowly pulsating stars.  相似文献   

Real eukaryotes and precipitates first found in the Middle Riphean stratotype, southern Urals   总被引：1，自引：0，他引：1  

V. N. Sergeev  Lee Seong-Joo 《Stratigraphy and Geological Correlation》2006,14(1):1-18

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The 1786 earthquake-triggered landslide dam and subsequent dam-break flood on the Dadu River, southwestern China — Reply     

F.C. Dai  C.F. Lee  J.H. Deng  L.G. Tham 《Geomorphology》2006,73(3-4):277-278

A short reply to discussion by Chanson.  相似文献   

Food Deserts in the Prairies? Supermarket Accessibility and Neighborhood Need in Edmonton,Canada*     

Karen E. Smoyer‐Tomic  John C. Spence  Carl Amrhein 《The Professional geographer》2006,58(3):307-326

The U.S. and U.K. literatures have discussed “food deserts,” reflecting populated, typically urban, low‐income areas with limited access to full‐service supermarkets. Less is known about supermarket accessibility within Canadian cities. This article uses the minimum distance and coverage methods to determine supermarket accessibility within the city of Edmonton, Canada, with a focus on high‐need and inner‐city neighborhoods. The results show that for 1999 both of these areas generally had higher accessibility than the remainder of the city, but six high‐need neighborhoods had poor supermarket accessibility. We conclude by examining potential reasons for differences in supermarket accessibility between Canadian, U.S., and U.K. cities.  相似文献   

Assembly of Proterozoic Australia: implications of a revised pole for the ∼1070 Ma Alcurra Dyke Swarm, central Australia     

Phillip W. Schmidt  George E. Williams  Alfredo Camacho  James K. W. Lee 《Geophysical Journal International》2006,167(2):626-634

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