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1.
We present a computer model calculation for the racemization of a possible excess of amino acids in the icy fraction of comet nuclei bring about by ionizing radiation released during the decay of26Al,40K,235U,238U and232Th. The model takes into account a total of 110 chemical reactions, of which 91 are needed to explain the radiation chemical processing of the major constituents of comet nuclei (Navarro-Gonzálezet al., 1992) and 19 are necessary to simulate the radiolysis of glycine/alanine mixtures in aqueous solutions (Navarro-Gonzálezet al., 1994 and 1996). It is predicted that an enantiomeric excess of alanine would not be destroyed by radioracemization during the decay of embedded radionuclides. Nevertheless, this enantiomeric excess could be attenuated by the formation of racemic amino acids in the interior of comet nuclei as a result of the radiation-induced polymerization of HCN.  相似文献   
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The buried Chicxulub impact structure is marked by a dramatic ring of sinkholes (called cenotes if containing water), and adjacent less prominent partial rings, which have been shown to coincide with maxima in horizontal gravity gradients and a topographic depression. These observations, along with the discreteness and spacing of the features, suggest a formation mechanism involving faulting in the outer slump zone of the crater, which would thus have a diameter of approximately 180 km.
An opposing view, based primarily on the interpretation of gravity data, is that (he crater is much larger than the cenote ring implies. Given the association of the known cenote ring with faults, we here examine northern Yucatan for similar rings in gravity, surface features and elevation, which we might expect to be associated with outer concentric faults in the case of a larger, possibly multiring, structure.
No such outer rings have been found, although definite patterns are seen in the distribution of karst features outside the crater rim. We explain these patterns as resulting mainly from deformation related to the block fault zone that parallels tbe shelf edge of eastern Yucatan.  相似文献   
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Major volcanogenic structures within the Marifil Formation allowed to determine the location of a claderas field that spreads along 400 kilometers. This field has at least three large calderas with diameters near to 100 kilometers, recognizable by regional distribution of associated dikes and rhyolite lava flows present at the caldera border that separates a monotonous ignimbritic plateau from a depressed (150 meters) inner volcanic collapsed caldera. The Marifil ignimbritic plateau cover more than 50,000 square kilometers with thicknesses that reach 800 meters. Associated with these plateau ignimbrites there is an important fluorite mineralization.  相似文献   
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The Tibetan plateau is host to numerous ~N‐S striking graben that have accommodated E‐W directed extension. The development of these structures has been interpreted to reflect a variety of different geological processes including plateau collapse, oroclinal bending or mid‐to‐lower crustal flow. New 40Ar/39Ar thermochronology and quartz c‐axis data from the Thakkhola graben of west‐central Nepal show that E‐W extension was ongoing at least locally by the early Miocene (ca. 17 Ma). Our new, and previously published chronologic information on the initiation of graben across the orogen shows that they typically developed immediately after cessation of the South Tibetan detachment system, a structural network that facilitated differential southward movement of the upper and middle crust. We interpret this fundamental switch in orogen kinematics to reflect recoupling of the middle and upper Himalayan crust such that the subsequent widespread flow of the mid‐to‐lower crust out of the system to the east forced brittle accommodation in the upper crust.  相似文献   
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International Journal of Earth Sciences - The Juchatengo complex (JC) suite is located between the Proterozoic Oaxacan complex to the north and the Xolapa complex to the south, and was amalgamated...  相似文献   
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In Mexico, many environmental problems are generated by large mining activities taking place in several mining districts. These mining activities produce great quantities of residues; large majorities of these have high sulfur content, which could generate acid drainage due to their interaction with the oxygen in the environment. The study area was located in the Mining District of Guanajuato, Mexico with abandoned tailings generated mainly by the gold and silver production. Two areas, called as Monte de San Nicolás (SN) and Peregrina (P) were selected for this study. The results study shows that there was no risk of production of acid drainage, since these tailings contained high amount of carbonates, which neutralized the generation of acidity and consequently decreased the possibility of leaching of some elements. However, not all elements leach in acid pH, as arsenic bound to oxyhydroxides, which is in a basic environment and its increased release by increasing the pH.  相似文献   
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Ionospheric delays compensation is a mandatory step for precise absolute and relative positioning of Low Earth Orbit Satellites (LEO) by GPS measurements. The most frequently used ionosphere model for real-time GPS-based navigation in LEO is an isotropic model proposed by Lear, which uses the Vertical Total Electron Content (VTEC) above the receiver and a mapping function for TEC evaluation along a given ray path. Based on significant assessed results available for ground-based GPS receivers, we propose the use of a different model relying on the thin shell assumption and a bilinear horizontal variation of the VTEC as a function of latitude and longitude in the shell. It is expected that this model is capable of better describing horizontal gradients in the ionosphere, thus improving ionospheric delay estimation, especially in intense ionospheric conditions. This model is referred to as Linear Thin Shell (LTS). LTS performance in estimating undifferenced and double-differenced ionospheric delays is checked by comparing measured and predicted delays computed using flight data from the GRACE mission. Results show that the LTS always outperforms the isotropic model, especially in case of high solar activity. Moreover, the LTS model provides a higher performance uniformity over a wide range of ionospheric delays, thus ensuring good performance in different conditions. The results obtained demonstrate that the LTS model improves the ionosphere delays estimation accuracy by 20 and 40% for undifferenced and double-differenced delays, respectively. This suggests the LTS model can effectively contribute to improving precision in LEO positioning applications.  相似文献   
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This study investigates the stratigraphical sequence of Cocina Cave (Spain) employing and testing for the first time the capability of rare earth elements as markers of human activities in caves. Located in Dos Aguas (Valencian Community, Spain), Cocina Cave is characterized by the presence of several Holocene archaeological deposits from the final Mesolithic to the present day and is a pivotal site for understanding the socio-ecological dynamics of the last hunter-gatherer inhabitants of the Iberian Peninsula and the transition to pastoral and agricultural economies in the Western Mediterranean. However, the identification of strata from particular time-periods in the cave is often difficult due to the homogeneity of layers, the poor archaeological record in some strata and the presence of severe disturbance phenomena. The methodological approach of this study consisted of cross-referencing rare earth elements and other chemical markers with the archaeological stratigraphical interpretation, in an attempt to not only support the identification of the anthropic contribution to the formation of Cocina Cave strata, but also to characterize and confirm different natural and occupational episodes, particularly those associated with hunter-gatherer, early agriculturalist, and shepherd activities. Sediments were collected from different excavation areas and analysed for major elements, trace elements, rare earth elements (REE), soil organic matter (SOM) amounts and pH. Multivariate statistics were employed to group samples according to their elemental profile, and these were then compared to the archaeological temporal interpretation. The obtained results showed that REE amount and fractionation geochemical processes were regulated by carbonates, phosphates and pH. The use of REE as markers was particularly useful as their concentrations and their calculated ratios and anomaly distributions were demonstrated to be highly consistent with the archaeological stratigraphical interpretation.  相似文献   
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