Trace elements and polycyclic aromatic hydrocarbons (PAHs) concentrations in deep Gulf of Mexico sediments     

Terry L. Wade  Yousra Soliman  Stephen T. Sweet  Gary A. Wolff  Bobby J. Presley 《Deep Sea Research Part II: Topical Studies in Oceanography》2008,55(24-26):2585

The concentrations of polycyclic aromatic hydrocarbons (PAHs) and trace elements were determined for surface (top 2 cm) sediment samples collected during the deep Gulf of Mexico benthos (DGoMB) study .These elements and compounds are known to be toxic to organisms at high concentrations and may affect biological communities. There is no indication of major anthropogenic input of the elements Be, Co, Cr, Fe, Si, Tl, V, K, Mg, Ca, Sr and Zn, based on normalization to Al. The concentrations of these metals in the sediment are a function of the relative amounts of trace-metal-rich Mississippi River-derived silicate material and trace-metal-poor plankton-derived carbonate. This is not true for the elements Ba, Ni, Pb, Cd, As, Cu and Mn, whose concentrations show considerable scatter when normalized to Al and a general enrichment. On a normalized basis, Mn is enriched 5–10 fold, Cu and Ni 2–3 fold and Pb 2 fold over Mississippi River-derived material. These enrichments are likely the result of remobilization of metals from depths in the sediment column where reducing conditions exist. The Ba concentrations at selected sites are higher than those of average clay-rich sediments, but are typical of sediments from near oil well platforms in the northern Gulf of Mexico. In the case of Ba, it seems likely that the enrichments, as high as a factor of 10, are due to disposal of oil well drilling mud. The Ba-enriched samples are from the three shallowest water sites in the Mississippi Trough (sites MT1, 2 and 3) and from site C1 and WC5. All are in an area of intense petroleum exploration and development. PAH concentrations are also elevated at MT1, MT3 and C1. The total PAH concentration ranged from not detected (ND) to 1033 ng/g with a mean of 140 ng/g. Even at the sites most enriched in PAHs and trace elements, the concentrations are not at the levels expected to adversely affect the biota. However, these predicted non-effects are based on research using mostly near-shore estuarine species, not on the indigenous species at the sampling sites.  相似文献   

Leaching characteristics of a high-calcium fly ash as a function of pH: a potential source of selenium toxicity     

David A. Grisafe  Ernest E. Angino  Stephen M. Smith 《Applied Geochemistry》1988,3(6)

Using a modified extraction procedure, the effect of pH on the leaching of selected elements from Ca-rich (Type C) power plant fly ash was studied. Continuous additions of acetic acid were used to maintain pH values of fly ash slurries at 4.0, 6.0 and 8.0 for 24 h and an additional set was leached at its natural pH (average 11.8) value. Analyses for Se, As, Ca, Cd, Cr, Fe, Na and Pb showed that the highest concentrations occur in the leachate at pH 4.0 and decline with increasing pH. Concentrations of Cr and Fe increased slightly between neutral and high pH. Arsenic, Cd, Cr, Pb and Se concentrations exceeded the Environmental Protection Agency's toxicity criteria at pH 4.0. Selenium was above its toxicity level at pH values near 7 but the other elements were below their respective toxicity levels near neutral pH. Because recent studies show adverse effects of Se on aquatic life at far lower concentrations than the current Environmental Protection Agency's standard, high-Ca, power plant fly ashes represent a potentially hazardous pollutant to surface and subsurface waters.  相似文献   

Petrophysical properties of bioclastic platform carbonates: implications for porosity controls during burial     

Delphine Croizé  Stephen N. Ehrenberg  Knut Bjørlykke  François Renard  Jens Jahren 《Marine and Petroleum Geology》2010

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Open-system chemical behavior in deep Wilcox Group mudstones,Texas Gulf Coast,USA     

Ruarri J. Day-Stirrat  Kitty L. Milliken  Shirley P. Dutton  Robert G. Loucks  Stephen Hillier  Andrew C. Aplin  Anja M. Schleicher 《Marine and Petroleum Geology》2010

Wilcox Group mudstones have been mechanically and geochemically transformed over a temperature range of 20–200 °C. Our research controlled for provenance and age by sampling from five wells, parallel to the paleodepositional axis, all within the Houston delta system. Across the sampled depths, mudstone porosity has been reduced from ∼25 to <10% and bulk mineralogical change as documented by quantitative X-ray diffraction includes decreases in quartz, K-feldspar and kaolinite content whereas illite + illite − smectite, chlorite, and plagioclase increase. These mineral transformations transfer elements at a scale of less than 1 mm from one mineralogical form to another, however, X-ray fluorescence data suggest that among major elements only Al₂O₃ and TiO₂ are fully conserved within the system (trace-element ZrO₂ is also conserved). K₂O has been added to and SiO₂ released from the Wilcox Group mudstones. Cathodoluminescence and secondary electron imaging did not find this SiO₂ locally precipitated. We, therefore, document an open-system geochemical behavior.  相似文献   

Guiding ecological principles for marine spatial planning     

Melissa M. Foley  Benjamin S. Halpern  Fiorenza Micheli  Matthew H. Armsby  Margaret R. Caldwell  Caitlin M. Crain  Erin Prahler  Nicole Rohr  Deborah Sivas  Michael W. Beck  Mark H. Carr  Larry B. Crowder  J. Emmett Duffy  Sally D. Hacker  Karen L. McLeod  Stephen R. Palumbi  Charles H. Peterson  Helen M. Regan  Mary H. Ruckelshaus  Paul A. Sandifer  Robert S. Steneck 《Marine Policy》2010

The declining health of marine ecosystems around the world is evidence that current piecemeal governance is inadequate to successfully support healthy coastal and ocean ecosystems and sustain human uses of the ocean. One proposed solution to this problem is ecosystem-based marine spatial planning (MSP), which is a process that informs the spatial distribution of activities in the ocean so that existing and emerging uses can be maintained, use conflicts reduced, and ecosystem health and services protected and sustained for future generations. Because a key goal of ecosystem-based MSP is to maintain the delivery of ecosystem services that humans want and need, it must be based on ecological principles that articulate the scientifically recognized attributes of healthy, functioning ecosystems. These principles should be incorporated into a decision-making framework with clearly defined targets for these ecological attributes. This paper identifies ecological principles for MSP based on a synthesis of previously suggested and/or operationalized principles, along with recommendations generated by a group of twenty ecologists and marine scientists with diverse backgrounds and perspectives on MSP. The proposed four main ecological principles to guide MSP—maintaining or restoring: native species diversity, habitat diversity and heterogeneity, key species, and connectivity—and two additional guidelines, the need to account for context and uncertainty, must be explicitly taken into account in the planning process. When applied in concert with social, economic, and governance principles, these ecological principles can inform the designation and siting of ocean uses and the management of activities in the ocean to maintain or restore healthy ecosystems, allow delivery of marine ecosystem services, and ensure sustainable economic and social benefits.  相似文献   

A diverse Pleistocene marsupial trackway assemblage from the Victorian Volcanic Plains,Australia     

Stephen P. Carey  Aaron B. Camens  Matthew L. Cupper  Rainer Grün  John C. Hellstrom  Stafford W. McKnight  Iain Mclennan  David A. Pickering  Peter Trusler  Maxime Aubert 《Quaternary Science Reviews》2011,30(5-6):591-610

A diverse assemblage of late Pleistocene marsupial trackways on a lake bed in south-western Victoria provides the first information relating to the gaits and morphology of several megafaunal species, and represents the most speciose and best preserved megafaunal footprint site in Australia. The 60–110 ka volcaniclastic lacustrine sedimentary rocks preserve trackways of the diprotodontid Diprotodon optatum, a macropodid (probably Protemnodon sp.) and a large vombatid (perhaps Ramsayia magna or ‘Phascolomys’ medius) and possible prints of the marsupial lion, Thylacoleo carnifex. The footprints were imprinted within a short time period, demonstrating the association of the taxa present, rather than the time-averaged accumulations usually observed in skeletal fossil deposits. Individual manus and pes prints are distinguishable in some trackways, and in many cases some digital pad morphology is also present. Several parameters traditionally used to differentiate ichnotaxa, including trackway gauge and the degree of print in-turning relative to the midline, are shown to be subject to significant intraspecific variation in marsupials. Sexual dimorphism in the trackway proportions of Diprotodon, and its potential for occurrence in all large bodied, quadrupedal marsupials, is identified here for the first time.  相似文献   

Individual responsibility for the oceans? An evaluation of marine citizenship by UK marine practitioners     

Emma McKinley  Stephen Fletcher 《Ocean & Coastal Management》2010,53(7):379-384

In recent times, the governance of the marine environment has evolved from being primarily top down and state directed to being more participatory and community based. This paper proposes that an extension of this trend would be the inculcation of a societal sense of marine citizenship to deliver the sustainable management and protection of the marine environment through enhanced individual involvement in policy development and implementation. The potential role of marine citizenship in UK marine governance was examined by surveying UK marine practitioner’s views on both the current and future role of marine citizenship. Observations from this study identified three key factors for discussion including conflicting opinions over the implementation of marine citizenship into policy; that marine-focused education and a sense of personal attachment are integral to the development of marine citizenship; and that as yet, the potential implications of an enhanced sense of marine citizenship are uncertain. This research highlights the recognition amongst marine practitioners that higher levels of citizen involvement in the management of the marine environment would greatly benefit the marine environment, with additional benefits possible through an increased sense of marine citizenship.  相似文献   

The Miocene of Carriacou,the Grenadines,Lesser Antilles     

Stephen K. Donovan  Trevor A. Jackson 《Geology Today》2013,29(4):150-158

Carriacou is one of the small islands in the Grenadine chain in the southern Lesser Antilles. It preserves two Miocene successions, that on the south coast shallowing upwards and separated by a probable fault from the extensively exposed turbidite sequence, called the Grand Bay Formation, on the east coast. These formations show a range of features beautifully exposed in coastal sections, including unconformities, turbidites and a starfish bed.  相似文献   

A numerical model of the internal tide in knight inlet,British Columbia     

Michael W. Stacey  Stephen Pond 《大气与海洋》2013,51(3):383-418

Abstract

A two‐dimensional, hydrostatic numerical model of the tides in Knight Inlet is compared with observations of velocity and density obtained from three cyclesonde moorings. The observations from a fourth cyclesonde mooring were used to provide boundary data at the open end of the model. The time period in the fjord that the model simulates was a period of high, freshwater runoff, so that the fjord had a distinct, surface layer. The use of high, vertical resolution was avoided by attaching a homogeneous, fresh, surface layer to the top of the model. The density equation was linearized about a mean, fixed density field, and the mixing of density was not allowed.

The model reproduces the semidiurnal (M₂, S₂ and N₂) and diurnal (K₁ and O₁) velocity and density signals in the inlet. The shallow‐water constituents (M₄ and MK₃) are reproduced even though the density equation has been linearized. The fortnightly constituent (MSf) is poorly simulated. When the advection terms in the momentum equation are set to zero, the basic features of the semidiurnal and diurnal constituents are still reproduced, but the shallow‐water constituents are poorly simulated.

The energy flux along the inlet of the M₂ internal tide is insensitive to the advective terms in the momentum equation. The total rate of dissipation of M₂ energy is similar to the energy flux in the M₂ internal tide near the sill, which implies that, according to the model, most of the energy removed from the barotropic tide is fed into the internal tide. The majority of the energy in the M₂ internal tide is dissipated close to the sill of the inlet, but enough of the energy makes its way to the head of the inlet to reflect and set up a recognizable standing wave pattern.  相似文献   

Late Pleistocene glaciation of the Mt Giluwe volcano,Papua New Guinea     

Timothy T. Barrows  Geoffrey S. Hope  Michael L. Prentice  L. Keith Fifield  Stephen G. Tims 《Quaternary Science Reviews》2011,30(19-20):2676-2689

The Mt Giluwe shield volcano was the largest area glaciated in Papua New Guinea during the Pleistocene. Despite minimal cooling of the sea surface during the last glacial maximum, glaciers reached elevations as low as 3200 m. To investigate changes in the extent of ice through time we have re-mapped evidence for glaciation on the southwest flank of Mt Giluwe. We find that an ice cap has formed on the flanks of the mountain on at least three, and probably four, separate occasions. To constrain the ages of these glaciations we present 39 new cosmogenic ³⁶Cl exposure ages complemented by new radiocarbon dates. Direct dating of the moraines identifies that the maximum extent of glaciation on the mountain was not during the last glacial maximum as previously thought. In conjunction with existing potassium/argon and radiocarbon dating, we recognise four distinct glacial periods between 293–306 ka (Gogon Glaciation), 136–158 ka (Mengane Glaciation), centred at 62 ka (Komia Glaciation) and from >20.3–11.5 ka (Tongo Glaciation). The temperature difference relative to the present during the Tongo Glaciation is likely to be of the order of at least 5 °C which is a minimum difference for the previous glaciations. During the Tongo Glaciation, ice was briefly at its maximum for less than 1000 years, but stayed near maximum levels for nearly 4000 years, until about 15.4 ka. Over the next 4000 years there was more rapid retreat with ice free conditions by the early Holocene.  相似文献