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11.
A solid phase extraction method based on the immobilisation of Penicillium chrysogenum on silica was developed for preconcentration and flame atomic absorption spectrometric determination of Pb(II). The immobilised sorbent was packed in a column to optimise the conditions for its quantitative sorption and desorption. Various parameters such as pH, type of eluent, sample and eluent flow rate and influence of others ions were systematically studied. Pb(II) was quantitatively sorbed at pH 4.0 at a flow rate of 2.0 mL min?1 and eluted with 10.0 mL of 1.0 M HCl at 0.2 mL min?1 flow rate. The devised procedure applied for Pb determination in tap water, an industrial effluent and sludge sample, black tea, spinach leaves and green beans (canned food) was reproducible, with a relative standard deviation of 0.8%. The method was validated by a BCR 701 standard lake sediment sample. The limit of detection and limit of quantification for Pb(II) were 7.16 and 23.88 μg L?1, respectively, with an enrichment factor of 100.  相似文献   
12.
13.
Sediment sequences spanning the last 800 years from two small lakes in the south Swedish uplands were explored for assessment of effects of changing human population, local land-use practices and airborne pollution on lake-ecosystem functioning and resilience. Variations in nutrient cycling and deposition of lithogenic elements were studied, using a multi-proxy stratigraphic approach. Carbon and nitrogen elemental and isotopic analyses were applied in combination with records of hydrocarbons (n-alkanes) to investigate the sources and depositional conditions of sediment organic matter. Changes in fluvial and airborne delivery of inorganic matter were based on X-ray fluorescence measurements. The results reveal that population growth and related increases in land-use pressure had a major impact on catchment erosion and input of terrestrial organic matter to the lakes from the 1500s to the end of the 1800s. Evidence also exists of a brief period of catchment disturbance at ca. 1200–1300, followed by recovery, likely connected to the Black Death pandemic. At ca. 1900 synchronous shifts in most of the proxy records suggest a marked change in external forcing common to the two lakes related to a major decrease in population density and the introduction of modern forestry following the industrial revolution. Interestingly, the two sediment records exhibit generally coherent trends in C/N ratio, organic C content and δ13C, both before and after 1900, indicating broadly similar sensitivities of the lake ecosystems to human impact. In contrast, deviating trends in total N content, δ15N and lithogenic element concentrations (K, Ti, Rb and Zr) reflect site-specific responses to local disturbances during the last century due to different nutrient conditions and catchment properties. Our companion sediment records highlight the importance of understanding long-term human impact on watersheds and demonstrate how regional versus local forcing of lake ecosystems, as well as site-specific responses related to catchment characteristics can be reconstructed.  相似文献   
14.
Rapid urbanization and increased tourism around Nainital Lake in the Kumaun Himalayan region in north India has raised concerns about sediment and water pollution. Lead-210 dated sediment cores from the lake represent ~95 years of accumulation and yield a mean sedimentation rate of ~4.7 mm year−1. Total organic carbon (TOC), percent N and S and their atomic C/N and C/S ratios, stable isotopes (δ13C, δ15N, and δ34S), and specific biomarkers (n-alkanes and pigments) were measured in the core. Organic matter is primarily derived from in-lake algal production and TOC flux varies from 1.0 to 3.5 g m−2 year−1. Sediments are anoxic (Eh −328 to −187 mV) and have low (0.10–0.30 g m−2 year−1) N, but high (0.37–1.0 g m−2 year−1) S flux. Shifts in δ13C, δ15N, and δ34S suggest in-lake microbial processes dominated by denitrification and sulfate reduction. The sediments are dominated by short-chain hydrocarbons with low Carbon Preference Index values. The pigments indicate a gradual shift to cyanobacterial domination of the phytoplankton community in recent years. Despite an increase in external input of nutrients, the trophic state of the lake has remained largely unchanged, and the perceived human-induced impacts are limited.  相似文献   
15.
Urban land-use zoning analysis has been carried out to evaluate the suitability of land for urbanisation i.e. a process of assessing the fitness of different land characteristics (soils, physiography, slope, land use etc.) for urban development in Calcutta Metropolitan Development Authority (CMDA) area (1350 sq. km). Remote sensing data in conjunction with Survey of India maps and ancillary data have been employed for the analysis. A GIS-based methodology has been developed for the integration of different physical parameters and generation of urban land development units. In all 82 Urban Land Development Units (ULDUs) were delineated and evaluated with respect to physical constraints and the degree to which each class could limit the development for urban purpose. These ULDUs are categorised into five suitability classes for urban use. The relationships between ULDU classes, suitabilities and urban land development considerations in a generalised form have also been assessed. It has been observed that the physical constraints have become progressively greater from class-I to class-V meaning thereby that the cost for the developing the area for urban purpose increases from class-I and becomes uneconomic for class-V. The suitability map prepared using this methodology would also serve as a sub-set for the preparation of a Master plan of the city.  相似文献   
16.
Organic geochemical proxies have been studied in a 45-cm-long core retrieved from Lake Naukuchiyatal in Kumaun Himalayas, India. Increase in TOC, N, hydrocarbons and pigments concentration from bottom to surface sediments of the core indicates increase in the lake productivity. Stable isotopes (δ13C and δ 15 N), biomarkers (TAR, CPI and n-ΣC15,17,19) and C/N atomic (between 9 and 12) suggest dominance of algal derived organic matter in these sediments. Decrease in organic δ13C values (between ?27 and ?31‰) in surface sediments indicate influence of sewage and land runoff in shifting organic δ13C values, whereas low (between ?0.23 and 2.2‰) δ15N values together with high pigment concentrations (zeaxanthin and echinenone) represent dominance of cyanobacteria in the lake.  相似文献   
17.
ABSTRACT

Vertical anchor plates are often provided to increase the performance of various geotechnical engineering structures such as sheet pile walls, bulkheads, bridge abutments and offshore structures. Hence, the safe design of such structures needs a better understanding of the 3D behaviour of the anchor plate. This paper presents and discusses the results obtained from a series of 3D finite-difference analyses of vertical square anchor plate embedded in cohesionless soil. The 3D model is found to closely predict experimental pullout load–displacement relationship. The failure mechanism observed in the numerical model is found to be very similar to the failure reported in experimental studies. For a given embedment depth, the stiffness of the breakout factor–displacement response substantially reduces with increase in anchor plate size. However, the ultimate reduction in anchor capacity is found to approximately 8% with an increase in anchor size from 0.1 to 1 m. Numerical analysis reveals that at deeper embedment depth, the friction angle of sand is the critical parameter in enhancing the performance of anchor plate. The obtained 3D model results are then compared with the published results and are found to be reasonably in good agreement with each other.  相似文献   
18.
This article highlights the results of an action research to upgrade mountain farmers of bay leaf (Cinnamomum tamala Nees and Eberm) in Udayapur district of Nepal. Farmers received low prices, lacked market information, capacities, and institutional mechanisms, and were exploited by traders. To address these constraints, three independent but interlinked pro-poor value chain (VC) upgrading strategies comprising VC coordination upgrading and horizontal and vertical contractualization were implemented. Information was collected from focus-group discussions with collectors, traders, and facilitators, and a questionnaire was used to collect pre- and postintervention data (n = 120). VC upgrading strategies improved harvesting practices, increased farmers’ bargaining power, and led to a threefold increase in price, which increased household incomes. Results demonstrated improved terms of participation of farmers and a general increase in market price of bay leaf in Udayapur. The study approach can be up scaled to reduce poverty from high value products.  相似文献   
19.
The Himalayas has experienced varying rates of earthquake occurrence in the past in its seismo-tectonically distinguished segments which may be attributed to different physical processes of accumulation of stress and its release, and due diligence is required for its inclusion for working out the seismic hazard. The present paper intends to revisit the various earthquake occurrence models applied to Himalayas and examines it in the light of recent damaging earthquakes in Himalayan belt. Due to discordant seismicity of Himalayas, three types of regions have been considered to estimate larger return period events. The regions selected are (1) the North-West Himalayan Fold and Thrust Belt which is seismically very active, (2) the Garhwal Himalaya which has never experienced large earthquake although sufficient stress exists and (3) the Nepal region which is very seismically active region due to unlocked rupture and frequently experienced large earthquake events. The seismicity parameters have been revisited using two earthquake recurrence models namely constant seismicity and constant moment release. For constant moment release model, the strain rates have been derived from global strain rate model and are converted into seismic moment of earthquake events considering the geometry of the finite source and the rates being consumed fully by the contemporary seismicity. Probability of earthquake occurrence with time has been estimated for each region using both models and compared assuming Poissonian distribution. The results show that seismicity for North-West region is observed to be relatively less when estimated using constant seismicity model which implies that either the occupied accumulated stress is not being unconfined in the form of earthquakes or the compiled earthquake catalogue is insufficient. Similar trend has been observed for seismic gap area but with lesser difference reported from both methods. However, for the Nepal region, the estimated seismicity by the two methods has been found to be relatively less when estimated using constant moment release model which implies that in the Nepal region, accumulated strain is releasing in the form of large earthquake occurrence event. The partial release in second event of May 2015 of similar size shows that the physical process is trying to release the energy with large earthquake event. If it would have been in other regions like that of seismic gap region, the fault may not have released the energy and may be inviting even bigger event in future. It is, therefore, necessary to look into the seismicity from strain rates also for its due interpretation in terms of predicting the seismic hazard in various segments of Himalayas.  相似文献   
20.
We examine daily records of sunspot group areas (measured in millionths of a solar hemisphere or μHem) for the last 130 years to determine the rate of decay of sunspot group areas. We exclude observations of groups when they are more than 60° in longitude from the central meridian and only include data when at least three days of observations are available following the date of maximum area for a group’s disk passage. This leaves data for over 18 000 measurements of sunspot group decay. We find that the decay rate increases linearly from 28 μHem day−1 to about 140 μHem day−1 for groups with areas increasing from 35 μHem to 1000 μHem. The decay rate tends to level off for groups with areas larger than 1000 μHem. This behavior is very similar to the increase in the number of sunspots per group as the area of the group increases. Calculating the decay rate per individual sunspot gives a decay rate of about 3.65 μHem day−1 with little dependence upon the area of the group. This suggests that sunspots decay by a Fickian diffusion process with a diffusion coefficient of about 10 km2 s−1. Although the 18 000 decay rate measurements are lognormally distributed, this can be attributed to the lognormal distribution of sunspot group areas and the linear relationship between area and decay rate for the vast majority of groups. We find weak evidence for variations in decay rates from one solar cycle to another and for different phases of each sunspot cycle. However, the strongest evidence for variations is with latitude and the variations with cycle and phase of each cycle can be attributed to this variation. High latitude spots tend to decay faster than low latitude spots.  相似文献   
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