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1.
Distribution of arsenic and its mobility in shallow aquifer sediments from Ambikanagar, West Bengal, India 总被引：1，自引：0，他引：1
Sediments from a core retrieved during installation of a shallow drinking water well in Ambikanagar (West Bengal, India) were analyzed for various physical and chemical parameters. The geochemical analyses included: (1) a 4-step sequential extraction scheme to determine the distribution of As between different fractions, (2) As speciation (As3+ vs. As5+), and (3) C, N and S isotopes. The sediments have a low percentage of organic C and N (0.10-0.56% and 0.01-0.05%, respectively). Arsenic concentration is between 2 and 7 mg kg−1, and it is mainly associated with the residual fraction, less susceptible to chemical weathering. The proportion of As3+ in these sediments is high and ranges from 24% to 74%. Arsenic in the second fraction (reducible) correlates well with Mn, and in the residual fraction As correlates well with several transition elements. The stable isotope results indicate microbial oxidation of organic matter involving SO4 reduction. Oxidation of primary sulfide minerals and release of As from reduction of Fe-(oxy)hydroxides do not seem important mechanisms in As mobilization. Instead, the dominance of As3+ and presence of As5+ reducing microorganisms in this shallow aquifer imply As remobilization involving microbial processes that needs further investigations. 相似文献
2.
Petra Bragée Preetam Choudhary Joyanto Routh John F. Boyle Dan Hammarlund 《Journal of Paleolimnology》2013,50(4):545-560
Sediment sequences spanning the last 800 years from two small lakes in the south Swedish uplands were explored for assessment of effects of changing human population, local land-use practices and airborne pollution on lake-ecosystem functioning and resilience. Variations in nutrient cycling and deposition of lithogenic elements were studied, using a multi-proxy stratigraphic approach. Carbon and nitrogen elemental and isotopic analyses were applied in combination with records of hydrocarbons (n-alkanes) to investigate the sources and depositional conditions of sediment organic matter. Changes in fluvial and airborne delivery of inorganic matter were based on X-ray fluorescence measurements. The results reveal that population growth and related increases in land-use pressure had a major impact on catchment erosion and input of terrestrial organic matter to the lakes from the 1500s to the end of the 1800s. Evidence also exists of a brief period of catchment disturbance at ca. 1200–1300, followed by recovery, likely connected to the Black Death pandemic. At ca. 1900 synchronous shifts in most of the proxy records suggest a marked change in external forcing common to the two lakes related to a major decrease in population density and the introduction of modern forestry following the industrial revolution. Interestingly, the two sediment records exhibit generally coherent trends in C/N ratio, organic C content and δ13C, both before and after 1900, indicating broadly similar sensitivities of the lake ecosystems to human impact. In contrast, deviating trends in total N content, δ15N and lithogenic element concentrations (K, Ti, Rb and Zr) reflect site-specific responses to local disturbances during the last century due to different nutrient conditions and catchment properties. Our companion sediment records highlight the importance of understanding long-term human impact on watersheds and demonstrate how regional versus local forcing of lake ecosystems, as well as site-specific responses related to catchment characteristics can be reconstructed. 相似文献
3.
Torsional waves supported by magnetic flux tubes have long been thought to bear a high potential for supplying energy and momentum to the upper solar atmosphere, thereby contributing to its heating and to the driving of dynamic events like spicules. This hope rested on the belief that their propagation is not impeded by cutoff restrictions, unlike longitudinal and kink waves. We point out that this applies only to thin, isothermal tubes. When they widen in the chromosphere, and as a result of temperature gradients, cutoff restrictions arise. We compare them to recent observational reports of such waves and of vortex motions and find that their long period components are already affected by cutoff restrictions. An observational strategy is proposed that should permit the derivation of better information on vortex flows from off‐center observations with next generation telescopes (© 2010 WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim) 相似文献
4.
5.
Supriyo Kumar Das Joyanto Routh Alakendra N. Roychoudhury J. Val Klump 《Journal of Paleolimnology》2008,39(3):349-360
We used elemental carbon, nitrogen, phosphorus and hydrogen ratios (C/N, N/P and H/C) with total organic carbon (TOC) and
total phosphorus (TP) as well as stable carbon and nitrogen isotopes (δ13C and δ15N) to investigate the source and depositional conditions of organic matter in sediments from Zeekoevlei, the largest freshwater
lake in South Africa. Typical C/N (10–12), H/C ratios (≥1.7) and δ13Corganic values (−22 to −19‰) together with the increase in TOC concentration indicate elevated primary productivity in lower middle
(18–22 cm) and top (0–8 cm) sections of the sediment cores. Seepage of nutrients from a nearby waste water treatment plant,
rapid urbanization and heavily fertilized farming in the catchments are responsible for the increased productivity. Consistent
with this, measured δ15Norganic values (∼11‰) indicate increased raw sewage input towards the top-section of the core. Although cyanobacterial blooms are
evident from the low δ15N values (∼3‰) in mid-section of the core, they did not outnumber the phytoplankton population. Low N/P ratio (∼0) and high
TP (100–2,200 mg l−1) support cyanobacterial growth under N limited condition, and insignificant input of macrophytes towards the organic matter
pool. Dredging in 1983, caused sub-aerial exposure of the suspended and surface sediments, and affected organic matter preservation
in the upper mid-section (12–14 cm) of the core. 相似文献
6.
Biogeochemical records of paleoenvironmental changes in Nainital Lake,Kumaun Himalayas,India 总被引：1，自引：0，他引：1
Preetam Choudhary Joyanto Routh Govind J. Chakrapani Bhishm Kumar 《Journal of Paleolimnology》2009,42(4):571-586
Rapid urbanization and increased tourism around Nainital Lake in the Kumaun Himalayan region in north India has raised concerns
about sediment and water pollution. Lead-210 dated sediment cores from the lake represent ~95 years of accumulation and yield
a mean sedimentation rate of ~4.7 mm year−1. Total organic carbon (TOC), percent N and S and their atomic C/N and C/S ratios, stable isotopes (δ13C, δ15N, and δ34S), and specific biomarkers (n-alkanes and pigments) were measured in the core. Organic matter is primarily derived from in-lake algal production and TOC
flux varies from 1.0 to 3.5 g m−2 year−1. Sediments are anoxic (Eh −328 to −187 mV) and have low (0.10–0.30 g m−2 year−1) N, but high (0.37–1.0 g m−2 year−1) S flux. Shifts in δ13C, δ15N, and δ34S suggest in-lake microbial processes dominated by denitrification and sulfate reduction. The sediments are dominated by short-chain
hydrocarbons with low Carbon Preference Index values. The pigments indicate a gradual shift to cyanobacterial domination of
the phytoplankton community in recent years. Despite an increase in external input of nutrients, the trophic state of the
lake has remained largely unchanged, and the perceived human-induced impacts are limited. 相似文献
7.
Kasun Gayantha Joyanto Routh Krishnamurthy Anupama Jean Lazar Srinivasan Prasad Rohana Chandrajith Patrick Roberts Gerd Gleixner 《第四纪科学杂志》2020,35(4):514-525
The catastrophic impact and unpredictability of the Indian Ocean Monsoon (IOM) over South Asia are evident from devastating floods, mudslides and droughts in one of the most densely populated regions of the globe. However, our understanding as to how the IOM has varied in the past, as well as its impact on local environments, remains limited. This is particularly the case for Sri Lanka, where erosional landscapes have limited the availability of well-stratified, high-resolution terrestrial archives. Here, we present novel data from an undisturbed sediment core retrieved from the coastal Bolgoda Lake. This includes the presentation of a revised Late Holocene age model as well as an innovative combination of pollen, source-specific biomarkers, and compound-specific stable carbon isotopes of n-alkanes to reconstruct the shifts in precipitation, salinity and vegetation cover. Our record documents variable climate between 3000 years and the present, with arid conditions c. 2334 and 2067 cal a bp. This extreme dry period was preceded and followed by more wet conditions. The high-resolution palaeoenvironmental reconstruction fills a major gap in our knowledge on the ramifications of IOM shifts across South Asia and provides insights during a time of major redistribution of dense human settlements across Sri Lanka. 相似文献
8.
Preetam Choudhary Joyanto Routh Govind J. Chakrapani 《Environmental Earth Sciences》2010,60(4):837-843
Organic geochemical proxies have been studied in a 45-cm-long core retrieved from Lake Naukuchiyatal in Kumaun Himalayas, India. Increase in TOC, N, hydrocarbons and pigments concentration from bottom to surface sediments of the core indicates increase in the lake productivity. Stable isotopes (δ13C and δ 15 N), biomarkers (TAR, CPI and n-ΣC15,17,19) and C/N atomic (between 9 and 12) suggest dominance of algal derived organic matter in these sediments. Decrease in organic δ13C values (between ?27 and ?31‰) in surface sediments indicate influence of sewage and land runoff in shifting organic δ13C values, whereas low (between ?0.23 and 2.2‰) δ15N values together with high pigment concentrations (zeaxanthin and echinenone) represent dominance of cyanobacteria in the lake. 相似文献
9.
Joyanto Routh Aparajita Bhattacharya Ambujom Saraswathy Gunnar Jacks Prosun Bhattacharya 《Journal of Geochemical Exploration》2007
Weathering of mine tailings have resulted in high As concentrations in water (up to 2900 μg l− 1) and sediment (up to 900 mg kg− 1) samples around the Adak mine. Notably, As occurs as As(III) species (15–85%) in the oxic surface and ground water samples, which is not common. Time-series based sediment incubations were set up in the laboratory with contaminated sediments to study the microbial processes involved in transformation and remobilization of As across the sediment–water interface. The microcosm experiments indicate that microorganisms are capable of surviving in As-rich sediments and reduce As(V) to As(III). A decrease in total As concentration in sediments is coupled to an increase in As(III) concentration in the aqueous media. In contrast, the controls (treated with HgCl2 and formaldehyde) did not show growth, and As(V) concentrations increased steadily in the sediments and aqueous medium. The results imply that active metabolism is necessary for As(V) reduction. These microorganisms possess reduction mechanisms that are not necessarily coupled to respiration, but most likely impart resistance to As toxicity. 相似文献
10.
Joyanto Routh Preetam Choudhary Philip A. Meyers Bhishm Kumar 《Journal of Paleolimnology》2009,42(3):325-341
Human-induced perturbations in the Lake Norrviken catchment, Sweden, over the last 100+ years have left distinctive geochemical
imprints in the sediments. Disposal of sewage, industrial, and agricultural run-off into the lake since the end of the nineteenth
century changed the trophic status from eutrophic to hyper-eutrophic. The primary organic matter (OM) source in the lake is
in situ algal material. Total organic carbon (TOC) concentrations increased near the mid-section of a short sediment core
collected from the deepest part of the lake, reflecting elevated epilimnetic productivity and consequent hypolimnetic anoxia.
Accompanying shifts to lighter stable organic C and total N isotopic compositions suggest that cyanobacterial productivity
increased during this period. The distribution of pigments in the core indicates a shift in the phytoplankton community to
a cyanobacteria-dominated system. Moreover, pigments confirm that N2-fixing versus non-N2-fixing phytoplankton varied depending upon the external inputs of N and P. Conditions in the lake improved after sewage input
was diverted and the lake is currently mesotrophic. 相似文献