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181.
182.
Field relations and whole-rock geochemistry indicate that magma mixing has been important in the genesis of the late Mesozoic I-type igneous complexes at Pingtan and Tonglu in SE China. Morphological and trace-element studies of zircon populations in rocks from each of these complexes have defined several distinct growth stages [Mineral. Mag. (2001)]. In-situ LAM-MC-ICPMS microanalysis shows large variations in 176Hf/177Hf (up to 15 Hf units) between zircons of different growth stages within a single rock, and between zones within single zircon grains (up to 9 Hf units). These variations suggest that each of the observed magmas in both complexes developed through hybridisation of ≥2 magmas with different sources. Although this mixing has produced similar Sr and Nd isotopic compositions in the different rock types of each complex, the zircons have functioned as “tape recorders” and have preserved details of the assembly of the different magmas.

In the Tonglu complex the most primitive magma is a mafic monzonite (preserved as enclaves), whose isotopic composition suggests derivation from the lower crust; rhyodacites, rhyolites and quartz diorites reflect the mixing of the monzonite with ≥2 more felsic magmas, derived from older crustal materials. In the Pingtan complex, zircons in a quartz diorite enclave suggest mixing between a crustal magma and a more primitive mantle-derived component. Zircons from granites and granodiorite enclaves indicate mixing between the quartz diorite and more felsic melts with lower 176Hf/177Hf. Major changes in 176Hf/177Hf correlate with discontinuous changes in the trace-element composition and morphology of the zircons, in particular the development of sector zoning that suggests rapid disequilibrium crystallisation. We suggest that the magma mixing recorded by the changes in 176Hf/177Hf occurred during transport in magma conduits. The in-situ analysis of Hf-isotopic stratigraphy in zircons is a new and powerful tool for the detailed study of magma generation processes.  相似文献   

183.
184.
This experimental investigation examined the controls on the geometry of cross‐sets formed by subaqueous dunes. A range of steady, unidirectional flow conditions spanning the field of dune existence was investigated, and aggradation rate ranged from 0 mm s?1 to 0·014 mm s?1. Data from an ultrasonic depth profiler consist of high‐resolution temporal and spatial series of bed profiles from which dune height and length, migration rate and the depth of trough scour were measured. Cross‐set thickness and length were measured from sediment peels. The size and shape of dunes from an equilibrium assemblage change continuously. Individual dunes commonly increase in height by trough scouring and, occasionally, by being caught‐up by the upstream dune. Both types of behaviour occur suddenly and irregularly in time and, hence, do not appear to depend on dunes further upstream. However, dune climbing or flattening is a typical response of dunes that disappear under the influence of the upstream dune. All types of behaviour occur at any flow velocity or aggradation rate. Successive dune‐trough trajectories, defined by dunes showing various behaviours, affect the geometry of the preserved cross‐sets. Mean cross‐set thickness/mean dune height averages 0·33 (±0·7), and mean cross‐set length/mean dune length averages 0·49 (±0·08), and both show no systematic variation with aggradation rate or flow velocity. Mean cross‐set thickness/mean cross‐set length tends to decrease with increasing flow velocity and Froude number, therefore allowing a qualitative estimation of flow conditions. Quantitative analysis of the temporal changes in the geometry and migration rate of individual dunes allows the development of a two‐dimensional stochastic model of dune migration and formation of cross‐sets. Computer realizations produced stacks of cross‐sets of comparable shape and thickness to laboratory flume observations, indicating a good empirical understanding of the variability of dune‐trough trajectories. However, interactions among dunes and aggradation rates of the order of 10?2 mm s?1 should be considered in future improved models.  相似文献   
185.
The compositional structure and thermal state of the subcontinental lithospheric mantle (SCLM) beneath the Kalahari Craton and the surrounding mobile belts have been mapped in space and time using >3400 garnet xenocrysts from >50 kimberlites intruded over the period 520–80 Ma. The trace-element patterns of many garnets reflect the metasomatic refertilisation of originally highly depleted harzburgites and lherzolites, and much of the lateral and vertical heterogeneity observed in the SCLM within the craton is the product of such metasomatism. The most depleted, and possibly least modified, SCLM was sampled beneath the Limpopo Belt by early Paleozoic kimberlites; the SCLM beneath other parts of the craton may represent similar material modified by metasomatism during Phanerozoic time. In the SW part of the craton, the SCLM sampled by “Group 2” kimberlites (>110 Ma) is thicker, cooler and less metasomatised than that sampled by “Group 1” kimberlites (mostly ≤95 Ma) in the same area. Therefore, the extensively studied xenolith suite from the Group 1 kimberlites probably is not representative of primary Archean SCLM compositions. The relatively fertile SCLM beneath the mobile belts surrounding the craton is interpreted as largely Archean SCLM, metasomatised and mixed with younger material during Paleoproterozoic to Mesoproterozoic rifting and compression. This implies that at least some of the observed secular evolution in SCLM composition worldwide may reflect the reworking of Archean SCLM. There are strong correlations between mantle composition and the lateral variations in seismic velocity shown by detailed tomographic studies. Areas of relatively low Vp within the craton largely reflect the progressive refertilisation of the Archean root during episodes of intraplate magmatism, including the Bushveld (2 Ga) and Karroo (ca. 180 Ma) events; areas of high Vp map out the distribution of relatively less metasomatised Archean SCLM. The relatively low Vp of the SCLM beneath the mobile belts around the craton is consistent with its fertile composition. The seismic data may be used to map the lateral extent of different types of SCLM, taking into account the small lateral variations in the geotherm identified using the techniques described here.  相似文献   
186.
Trapped-gas content in natural porous media, also called residual gas saturation (Sgr), corresponds to the imbibition end-point. To define the parameters controlling Sgr, two parameters were studied: the influence of rock characteristics (on 400 sandstone samples) and initial gas saturation (Sgi), on the basis of 60 experimental curves between Sgr and Sgi. Based on an extensive experimental database, this study establishes the dominant influence of microporosity on trapped gas saturation, and indirectly that of the contained clays. To cite this article: K. Suzanne, J. Billiotte, C. R. Geoscience 336 (2004).  相似文献   
187.
Melt inclusions in clinopyroxenes from lherzolitic xenoliths from the deep lithospheric mantle beneath the Slave Craton (Lac de Gras area, Canada) reveal multiple origins for carbonatitic melts. One type of inclusions consists of a series of silicate–carbonate–silicate concentric layers, interpreted to have unmixed under disequilibrium conditions during rapid ascent to the surface. Bulk major- and trace-element compositions are typical of Group 1 kimberlites and quantitative nuclear microprobe imaging of the globules reveals fractionation of related elements (e.g. F–Br, Nb–Ta) between the silicate and carbonate components. The globules probably formed by partial melting of carbonated peridotite, consistent with results of melting experiments and some models for the generation of kimberlite magmas. They provide evidence for a genetic relationship between some carbonate-rich magmas and ultramafic silicate magmas, and for the possibility of unmixing processes of these melts during their evolution.

The second inclusion type comprises carbonate-rich globules interpreted as samples of Mg-carbonatite melt that quenched on ascent to the surface. Bulk major- and trace-element compositions indicate that the melts were derived from a carbonate-rich source and oxygen, carbon, and strontium isotope data are consistent with the involvement of recycled crustal material and suggest that some mantle-derived carbonatites are unrelated to kimberlites.  相似文献   

188.
The time evolution of a model system for mixtures of sodium and potassium feldspars is investigated by computer simulations in order to determine what effects aluminum-silicon ordering may have on phase separation in these minerals. We assume that there is a greater energetic advantage for Al atoms to move onto preferred sites in the vicinity of Na atoms than in the vicinity of K atoms. This couples Al/Si ordering to the phase separation. We find that in such a system phase separation is slowed substantially compared to a system in which the two processes are not coupled.  相似文献   
189.
The earliest representatives in the sequence of Tertiary to Recent magmatic rocks on Adak island in the central Aleutians, are the Finger Bay Volcanics and associated small shallow-level gabbroic intrusives. The tholeiitic Finger Bay pluton (gabbro to quartz monzodiorite) is among the least altered representatives of this earliest period. The field relations, mineralogy, and geochemistry of the Finger Bay pluton contrast with the more recent calcalkaline plutons in the arc (e.g. on Adak, Hidden Bay pluton: 33 m.y. and on Kagalaska, Kagalaska pluton: 15 m.y.). Compared with the Hidden Bay pluton, the Finger Bay pluton is smaller (8 km2 versus 100 km2), has a greater proportion of gabbro (84% versus 5%), has a somewhat different mineralogy, and has higher whole rock and mafic mineral FeO/MgO ratios, higher K2O, and higher concentrations of incompatable elements in rocks of equivalent SiO2 (particularly for the more siliceous units). Magmatic amphibole occurs only in the most siliceous units in the Finger Bay pluton, whereas it is common in the calc-alkaline plutons. Except for the size, these differences parallel those between tholeiitic and calc-alkaline volcanic rocks from the active Aleutian volcanic centers. Textural, miner-alogical, and trace element analyses indicate that mixing of magmas and gabbros generated some of the rocks of intermediate (monzodiorite) composition in the Finger Bay pluton. Most of the differences in magmatic trends between the calc-alkaline and tholeiitic plutons are attributed to the physical conditions of magmatic evolution in the crust, rather than to differences in initial magmatic types. This conclusion rests on the similarity of fractionation-independent isotope ratios and trace element ratios in Aleutian magmas of all ages. In particular, compared to magmas of the north Pacific ocean basin (MORB, oceanic islands), Aleutian magmas show excess enrichment of Ba, K, Rb, and U relative to REE and high 207Pb/204Pb ratios for a given 206Pb/204Pb ratio. Recognition of tholeiitic series plutons in the arc provides direct evidence for magmatic conditions accompanying fractionation, and serves to emphasize the diversity of magmatic trends that are found over time and space at convergent plate margins.  相似文献   
190.
A suite of spinel peridotite xenoliths in Mesozoic basalts of the Tuoyun basin in the Tianshan area of northwest China has a high proportion of amphibole/mica-bearing lherzolites, with high Cpx/Opx ratios (mean 0.74). Many aspects of mineral chemistry in the Tuoyun peridotites are intermediate between those of refractory Archean cratonic mantle and fertile Phanerozoic mantle. These include Ni/Cr and the contents of transition metals and Y in olivine and orthopyroxene and the abundances of elements such as Na, Al, Ti, Y, Sr and LREE in clinopyroxene. The data suggest that the mantle in Tuoyun is moderately depleted in basaltic components relative to both the refractory Archean mantle and the fertile Phanerozoic mantle. The wide variations in the CaO/Al2O3 (0.9–3.5) of whole rocks and LREE/HREE (0.8–14.2) and Ti/Eu (971–5,765) of clinopyroxenes in the Tuoyun peridotites are interpreted as the metasomatism of hydrous carbonatitic and potassic melt or the cumulative effects of mantle metasomatism by different agents (carbonatite and small-volume silicate melts) through time. The Tuoyun mantle shows closer affinity to the type of mantle found beneath the Proterozoic Cathaysia block, and especially to that beneath the East Central Asia Orogenic Belt (ECAOB), than to the mantle beneath the Archean North China Craton. This implies that the Tianshan subcontinental lithospheric mantle may have been generated during the accretion of the ECAOB. The high proportion of fine-grained microstructures, high Cpx/Opx ratio, obvious Ca enrichment and lower overall depletion in the Tuoyun mantle relative to that in other parts of the ECAOB reflect stronger mechanical and chemical modification of the Tuoyun mantle, near the translithospheric Talas-Ferghana strike-slip fault, which played a major role in controlling the strength of the mantle lithosphere and has channeled the upwelling mantle.  相似文献   
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