Optimization of dissolved urea measurements in coastal waters with the combination of a single reagent and high temperature     

Md. Shafiul Alam  Beatriz E. Casareto  Yoshimi Suzuki  Rumana Sultana  Toshiyuki Suzuki 《Journal of Oceanography》2017,73(2):249-258

Urea is an unstable and intermediate organic nitrogenous compound present in coastal environments and is derived from the excretion of some aquatic organisms and wastewater discharges. Urea plays an important role in the nitrogen cycle, where it is utilized by algae, including diatoms. However, there are very limited relevant data on the production, consumption, and degradation of urea because of the lack of appropriate measurement techniques. The conventional method is based on the formation of a colored product when urea reacts with diacetyl monoxime in a sulfuric acid solution. We examined the optimal conditions for the formation of the colored product; specifically, we evaluated different temperatures (22–80 °C), reaction times, mixing ratios of color reagents, and sample storage times. Application of the single mixed color-developing reagent (COLDER) at 70 °C resulted in the optimal formation of the colored product within a short reaction time of 60 min. This method was then used to measure dissolved urea in different coastal environments. The concentrations detected were as follows: 0.65–0.72, 0.49–0.58, and 1.09–2.28 µM urea-N at coral reef, seagrass, and mangrove sites, respectively. Our results showed high precision (SD = 0.02, CV = 1.2%), a low detection limit (0.03 µM urea-N), and a high recovery rate (94–99%). In summary, this high-temperature procedure for urea measurements should be valuable for obtaining high-precision data that can further the understanding of urea dynamics and its role in coastal ecosystems.  相似文献   

Assessment of village-wise groundwater draft for irrigation: a field-based study in hard-rock aquifers of central India     

R. K. Ray  T. H. Syed  Dipankar Saha  B. C. Sarkar  A. K. Patre 《Hydrogeology Journal》2017,25(8):2513-2525

Extracted groundwater, 90% of which is used for irrigated agriculture, is central to the socio-economic development of India. A lack of regulation or implementation of regulations, alongside unrecorded extraction, often leads to over exploitation of large-scale common-pool resources like groundwater. Inevitably, management of groundwater extraction (draft) for irrigation is critical for sustainability of aquifers and the society at large. However, existing assessments of groundwater draft, which are mostly available at large spatial scales, are inadequate for managing groundwater resources that are primarily exploited by stakeholders at much finer scales. This study presents an estimate, projection and analysis of fine-scale groundwater draft in the Seonath-Kharun interfluve of central India. Using field surveys of instantaneous discharge from irrigation wells and boreholes, annual groundwater draft for irrigation in this area is estimated to be 212 × 10⁶ m³, most of which (89%) is withdrawn during non-monsoon season. However, the density of wells/boreholes, and consequent extraction of groundwater, is controlled by the existing hydrogeological conditions. Based on trends in the number of abstraction structures (1982–2011), groundwater draft for the year 2020 is projected to be approximately 307 × 10⁶ m³; hence, groundwater draft for irrigation in the study area is predicted to increase by ～44% within a span of 8 years. Central to the work presented here is the approach for estimation and prediction of groundwater draft at finer scales, which can be extended to critical groundwater zones of the country.  相似文献   

Investigating the impact of the properties of pilot points on calibration of groundwater models: case study of a karst catchment in Rote Island,Indonesia     

Dua K. S. Y. Klaas  Monzur Alam Imteaz 《Hydrogeology Journal》2017,25(6):1703-1719

A robust configuration of pilot points in the parameterisation step of a model is crucial to accurately obtain a satisfactory model performance. However, the recommendations provided by the majority of recent researchers on pilot-point use are considered somewhat impractical. In this study, a practical approach is proposed for using pilot-point properties (i.e. number, distance and distribution method) in the calibration step of a groundwater model. For the first time, the relative distance–area ratio (d/A) and head-zonation-based (HZB) method are introduced, to assign pilot points into the model domain by incorporating a user-friendly zone ratio. This study provides some insights into the trade-off between maximising and restricting the number of pilot points, and offers a relative basis for selecting the pilot-point properties and distribution method in the development of a physically based groundwater model. The grid-based (GB) method is found to perform comparably better than the HZB method in terms of model performance and computational time. When using the GB method, this study recommends a distance–area ratio of 0.05, a distance–x-grid length ratio (d/X _grid) of 0.10, and a distance–y-grid length ratio (d/Y _grid) of 0.20.  相似文献   

Hydrogeochemical assessment of surface and groundwater resources of Korba coalfield,Central India: environmental implications     

Rambabu Singh  Tajdarul H. Syed  Suresh Kumar  Manoj Kumar  A. S. Venkatesh 《Arabian Journal of Geosciences》2017,10(14):318

The present study assesses the impact of coal mining on surface and groundwater resources of Korba Coalfield, Central India. Accordingly, water samples collected from various sources are analyzed for major ions, trace elements, and other mine effluent parameters. Results show that the groundwater samples are slightly acidic, whereas river water and mine water samples are mildly alkaline. Elevated concentrations of Ca²⁺, Na⁺, HCO₃ ^?, and SO₄ ^2? alongside the molar ratios (Ca²⁺+Mg²⁺)/(SO₄ ^2?+HCO₃ ^?) <1 and Na⁺/Cl^? >1 suggest that silicate weathering (water-rock interaction) coupled with ion exchange are dominant solute acquisition processes controlling the chemistry of groundwater in the study area. The overall hydrogeochemistry of the area is dominated by two major hydrogeochemical facies (i.e., Ca–Cl–SO₄ and Ca–HCO₃). Analysis of groundwater and river water quality index (GRWQI) elucidates that majority (82%) of samples are of “excellent” to “good” category, and the remaining 12% are of “poor” quality. Similarly, the effluent water quality index (EWQI) indicates that 6 out of 8 samples belong to excellent quality. Concentration of trace element constituents such as As, Zn, Cu, Cr, and Cd is found to be well within the stipulated limits for potable use, except for Fe, Mn, and Pb. Suitability of water samples for irrigation purpose, established using standard tools like Wilcox and USSL diagrams, reveal “excellent to permissible” category for majority of the samples. The present study also substantiates the effectiveness of the measures implemented for the treatment of mine effluent water.  相似文献   

Benthic foraminiferal response to changes in mining pattern: a case study from the Zuari estuary,Goa, India     

Syed Mohammad Saalim  R. Saraswat  T. Suokhrie  S. R. Bhadra  S. R. Kurtarkar  R. Nigam 《Environmental Earth Sciences》2017,76(20):706

Being sensitive to environmental changes, foraminifera have been extensively used to monitor pollution level in the marine environment, including the effect of mining in coastal areas. In the Goa state of India, the rejects from opencast mining on land largely find their way to the estuaries, as washout during monsoon. Additionally, the Mormugao Port at the mouth of the Zuari estuary is the hub of activities due to the transport of ore from hinterland areas by barges and its subsequent loading for export. On the directive of the Supreme Court of India, all the mining-related activities abruptly stopped throughout India, including that in Goa in 2012, and got reinstated in 2015. Therefore, it provided a fit case to test the effectiveness of benthic foraminifera as an indicator of environmental impact due to mining activities. A total of ten surface sediment samples from five locations in Zuari estuary were collected from a depth range of 4.5–8.5 m in the years of 2013 and 2016 and were analyzed for both the living (stained) and dead benthic foraminifera. The year 2013 represents a time interval immediately after the closure of extensive mining activity, and the sampling during 2016 represents minimal mining. The living benthic foraminiferal abundance was higher (19–54/g sediment) during 2013 and decreased substantially during 2016 (3–22/g sediment), suggesting an adverse effect of activities associated with mine closure on benthic foraminifera. Additionally, the relative abundance of Ammonia was also significantly low during the year 2016. The temporal variation in dead foraminifera was, however, different than that of the living foraminifera. The differential response was attributed to the terrigenous dilution as a result of change in sedimentation rate. Therefore, we conclude that living foraminifera correctly incorporate the changes in mining pattern and may be used as an effective tool to monitor the impact of mining. We further suggest that the potential counter effect of terrigenous dilution on total and living benthic foraminiferal population should be considered while interpreting temporal variations in foraminiferal abundance in marginal marine settings.  相似文献   

Fractured Rock Permeability as a Function of Temperature and Confining Pressure     

A. K. M. Badrul Alam  Yoshiaki Fujii  Daisuke Fukuda  Jun-ichi Kodama  Katsuhiko Kaneko 《Pure and Applied Geophysics》2015,172(10):2871-2889

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Sea Level Variations and Geomorphological Changes in the Coastal Belt of Pakistan     

Tariq Masood Ali Khan  D. A. Razzaq  Qamar-Uz-Zaman Chaudhry  Dewan Abdul Quadir  Anwarul Kabir  Majajul Alam Sarker 《Marine Geodesy》2013,36(1-2):159-174

The UNEP in its regional seas program in 1989 has included Pakistan in a group of countries which are vulnerable to the impact of rising sea level. If the present trend of sea level rise (SLR) at Karachi continues, in the next 50 years the sea level rise along the Pakistan Coast will be 50 mm (5 cm). Since the rising rates of sea level at Karachi are within the global range of 1-2 mm/year, the trends may be treated as eustatic SLR. Historical air temperature and sea surface temperature (SST) data of Karachi also show an increasing pattern and an increasing trend of about 0.67°C has been registered in the air temperature over the last 35 years, whereas the mean SST in the coastal waters of Karachi has also registered an increasing trend of about 0.3°C in a decade. Sindh coastal zone is more vulnerable to sea level rise than Baluchistan coast, as uplifting of the coast by about 1-2 mm/year due to subduction of Indian Ocean plate is a characteristic of Baluchistan coast. Within the Indus deltaic creek system, the area nearby Karachi is more vulnerable to coastal erosion and accretion than the other deltaic region, mainly due to human activities together with natural phenomena such as wave action, strong tidal currents, and rise in sea level. Therefore, The present article deals mainly with the study of dynamical processes such as erosion and accretion associated with sea level variations along the Karachi coast and surrounding Indus deltaic coastline. The probable beach erosion in a decade along the sandy beaches of Karachi has been estimated. The estimates show that 1.1 mm/year rise in sea level causes a horizontal beach loss of 110 mm per year. Therefore, coast eroded with rise in sea level at Karachi and surrounding sandy beaches would be 1.1 m during a period of next 10 years. The northwestern part of Indus delta, especially the Gizri and Phitti creeks and surrounding islands, are most unstable. Historical satellite images are used to analyze the complex pattern of sediment movements, the change in shape of coastline, and associated erosion and accretion patterns in Bundal and Buddo Islands. The significant changes in land erosion and accretion areas at Bundal and Buddo Islands are evident and appear prominently in the images. A very high rate of accretion of sediments in the northwestern part of Buddo Island has been noticed. In the southwest monsoon season the wave breaking direction in both these islands is such that the movement of littoral drift is towards west. Erosion is also taking place in the northeastern and southern part of Bundal Island. The erosion in the south is probably due to strong wave activities and in the northeast is due to strong tidal currents and seawater intrusion. Accretion takes place at the northwest and western parts of Bundal Island. By using the slope of Indus delta, sea encroachment and the land area inundation with rising sea level of 1 m and 2 m have also been estimated.  相似文献   

Offshore sand sources for beach replenishment: Potential borrows on the continental shelf of the Eastern Gulf of Mexico     

Charles W. Finkl Jr.  Syed M. Khalil  Jeffrey L. Andrews 《Marine Georesources & Geotechnology》2013,31(2):155-173

Erosion of sandy beaches is a worldwide problem that elicits innovative geoengineer‐ing techniques to reduce adverse impacts of shoreline retreat. Beach replenishment has emerged as the “soft”; shore‐stabilization technique of choice for mitigating beach erosion. This method of shore protection involves the addition of sand to the littoral sediment budget for sacrificial purposes. Because inland sand sources are often uneconomical or impractical to use, and known nearshore sources are limited, finding adequate quantities of suitable sand on the inner continental shelf is often vital to beach replenishment projects. The technical studies of survey and materials analysis that identify and delineate usable sand sources are sometimes almost as expensive as small‐project dredging, pumping, and placing the sand on the beach as fill. Inadequate quantity or substandard quality of shelf sand, as well as often‐prohibitive overhead expenses, thus compel shoreline managers to seek suitable sand sources offshore.

In the study area off the central‐west coast of Florida, offshore potential borrow areas (PBAs) were identified on the basis of studies conducted in reconnoitory and detailed phases. Sophisticated state‐of‐the‐art equipment used in this investigation provided more detailed subbottom mapping information than is normally obtained with conventional seismic equipment. An example of sand exploration studies was incorporated in a 215‐km² survey of offshore areas by conducting bathymetric surveys and subbottom seismic profiling, collecting jet probes, grab samples, and vibrocores, and analyzing sediment grading in subsamples from vibrocores. These combined analyses indicated that at least 8.8 ×10⁶ m³ of sand is available in potential borrow areas from 7.0 to 12 km offshore in water depths of 8.0 to 11.5 m. In the PBAs, mean grain size of sand falls into the range 0.13–0.53 mm, sorting averages 0.65–1.31ø, and the overall silt content varies from 3.9–8.5%. High silt contents (13–19%) mapped in some areas make these sedimentary deposits unsuitable as fill for artificial beach renourishment.  相似文献   

Coulomb stress evolution in Northeastern Caribbean over the past 250 years due to coseismic, postseismic and interseismic deformation   总被引：5，自引：0，他引：5  

Syed Tabrez Ali  rew M. Freed  Eric Calais  David M. Manaker  William R. McCann 《Geophysical Journal International》2008,174(3):904-918

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巴基斯坦达尔巴丁(Dalbandin）地震前观测到的电离层foF2异常变化     

穆罕默德?伊尔凡  阿夫塔?阿拉姆  默罕默德?朱奈德  默罕默德?埃亚茨?阿明  达拉?伊克巴尔  黄辅琼 《中国地震研究》2015,29(4):567-575

电离层foF2变化对地震反应非常敏感,与地震有关的电离层扰动变化结果似乎非常有望用于地震短期预测。格林威治时间2011年1月18日20:23分,一次7.2级的大地震发生在巴基斯坦的达尔巴丁(28.73oＮ, 63.92oＥ）。本文研究中,我们必须利用架设在巴基斯坦的伊斯兰堡（33.78oN, 73.06oE）、玛尔坦（32.26oN,71.51oE）和卡拉奇（24.89oN,67.02oE）三个垂直探测台站获得的白天（08:00 a.m. - 05:00 p.m.）小时值数据找出地震前的foF2异常变化特征。结果显示,在达尔巴丁地震前几天,foF2出现了显著变化;并且距离震中最近的台站观测到的频率与幅度异常变化大于较远的位于孕震区边缘的台站。尽管地震异常特征显著,但增加其它电离层参数可以提高foF2异常的高置信度水平。  相似文献