Pressure and temperature dependence of cation distribution in Mg-Mn olivine     

Tadashi Akamatsu  Kiyoshi Fujino  Mineo Kumazawa  Akio Fujimura  Manabu Kato  Hiroshi Sawamoto  Takamitsu Yamanaka 《Physics and Chemistry of Minerals》1988,16(2):105-113

Synthetic (Mg_0.51, Mn_0.49)₂SiO₄ olivine samples are heat-treated at three different pressures; 0, 8 and 12 GPa, all at the same temperature (～500° C). X-ray structure analyses on these single crystals are made in order to see the pressure effect on cation distribution. The intersite distribution coefficient of Mg and Mn in M1 and M2 sites, K _D = (Mn/Mg) _M1/(Mn/Mg) _M2, of these samples are 0.192 (0 GPa), 0.246 (8 GPa) and 0.281 (12 GPa), indicating cationic disordering with pressure. The small differences of cell dimensions between these samples are determined by powder X-ray diffraction. Cell dimensions b and c decrease, whereas a increases with pressure of equilibration. Cell volume decreases with pressure as a result of a large contraction of the b cell dimension. The effect of pressure on the free energy of the cation exchange reaction is evaluated by the observed relation between the cell volume and the site occupancy numbers. The magnitude of the pressure effect on cation distribution is only a fifth of that predicted from the observed change in volume combined with thermodynamic theory. This phenomenon is attributed to nonideality in this solid solution, and nonideal parameters are required to describe cation distribution determined in the present and previous experiments. We use a five-parameter equation to specify the cationic equilibrium on the basic of thermodynamic theory. It includes one energy parameter of ideal mixing, two parameters for nonideal effects, one volume parameter, and one thermal parameter originated from the lattice vibrational energy. The present data combined with some of the existing data are used to determine the five parameters, and the cation distribution in Mg-Mn olivine is described as a function of temperature, pressure, and composition. The basic framework of describing the cationic behavior in olivine-type mineral is worked out, although the result is preliminary: each of the determined parameters is not accurate enough to enable us to make a reliable prediction.  相似文献   

Pressure effect on the divalent cation distribution in nonideal solid solution of forsterite and fayalite     

Tadashi Akamatsu  Mineo Kumazawa  Nobuyuki Aikawa  Humihiko Takei 《Physics and Chemistry of Minerals》1993,19(7):431-444

The divalent cation distribution in olivine (Mg, Fe)₂SiO₄ under high pressure and temperature was studied to clarify the detailed state of olivine in the mantle. Single crystal samples were heated for a sufficient period of time for the cations to migrate and quenched fast enough to preserve the equilibrated state under high pressures, and the crystal structure was determined with X-ray method. The pressure effect on the distribution coefficient K _D[= (Fe/Mg) _M1/(Fe/Mg) _M2] was determined for the first time; dK _D/dP?0.02 GPa^?1. A set of five thermodynamic parameters required to describe the regular solution model was determined from data concerning the pressure dependence and the known temperature and compositional effects. As a result we have shown how K _D depends on pressure, temperature, and composition. The notable feature clarified is the very large contribution of nonideality in the olivine solid solution. The K _D of olivine crystals in the mantle is predicted; K _D increases to ～ 2.2 at the depth of 400 km, in contrast to 0.9 ～ 1.2 of natural samples available at the surface of the Earth.  相似文献   

Slowness-backazimuth weighted migration: A new array approach to a high-resolution image     

Tadashi Kito  reas Rietbrock  Christine Thomas 《Geophysical Journal International》2007,169(3):1201-1209

We have developed a new array method combining conventional migration with a slowness-backazimuth deviation weighting scheme. All seismic traces are shifted based on the theoretical traveltime of the scattered wave from specific gridpoints in a 3-D volume. Observed slowness and backazimuth are calculated for each raypath and compared with theoretical values in order to estimate slowness and backazimuth deviations. Subsequently, stacked energy calculated by a conventional migration method is weighted by the slowness and backazimuth deviations to suppress any arrival energy whose slowness and backazimuth are inconsistent with the expected theoretical values. This new method was applied to two P- wave data sets which comprise (1) underside reflections at the 410 and 660 km mantle discontinuities and (2) D" reflections as well as their corresponding synthetic data sets. The results show that the weighting scheme dramatically increases the resolution of the migrated images and enables us to obtain well-constrained, focused images, making upper-mantle discontinuities and D" reflections more distinct by reducing their surrounding energy.  相似文献   

New insights into the P- and S-wave velocity structure of the D" discontinuity beneath the Cocos plate     

Tadashi Kito  Sebastian Rost  Christine Thomas  Edward J. Garnero 《Geophysical Journal International》2007,169(2):631-645

Broad-band P - and S -waves from earthquakes in South America recorded at Californian network stations are analysed to image lateral variations of the D"-discontinuity beneath the Cocos plate. We apply two array processing methods to the data set: a simplified migration method to the P -wave data set and a double-array method to both the P - and S -wave data sets, allowing us to compare results from the two methods. The double-array method images a dipping reflector at a depth range from 2650 to 2700 km in the southern part of the study area. We observe a step-like topography of 100 km to a shallower reflector at about 2600 km depth to the north, as well as evidence for a second (deeper) reflector at a depth range from 2700 to 2750 km in the north. Results from the simplified migration agree well with those from the double-array method, similarly locating a large step in reflector depth in a similar location (about 2650 km depth in the south and about 2550 km in the north) as well as the additional deeper reflector at the depth of about 2750 km in the north. Waveform modelling of the reflected waves from both methods suggests a positive velocity contrast for S waves, but a negative velocity contrast for P waves for the upper reflector in agreement with predictions from mineral physical calculations for a post-perovskite phase transition. The data also show some evidence for the existence of another deeper reflector that could indicate a double intersection of the geotherm with the post-perovskite stability field, that is, the back-transformation of post-perovskite to perovskite close to the core–mantle boundary.  相似文献   

Logic-tree Approach for Probabilistic Tsunami Hazard Analysis and its Applications to the Japanese Coasts   总被引：2，自引：0，他引：2  

Tadashi Annaka  Kenji Satake  Tsutomu Sakakiyama  Ken Yanagisawa  Nobuo Shuto 《Pure and Applied Geophysics》2007,164(2-3):577-592

For Probabilistic Tsunami Hazard Analysis (PTHA), we propose a logic-tree approach to construct tsunami hazard curves (relationship between tsunami height and probability of exceedance) and present some examples for Japan for the purpose of quantitative assessments of tsunami risk for important coastal facilities. A hazard curve is obtained by integration over the aleatory uncertainties, and numerous hazard curves are obtained for different branches of logic-tree representing epistemic uncertainty. A PTHA consists of a tsunami source model and coastal tsunami height estimation. We developed the logic-tree models for local tsunami sources around Japan and for distant tsunami sources along the South American subduction zones. Logic-trees were made for tsunami source zones, size and frequency of tsunamigenic earthquakes, fault models, and standard error of estimated tsunami heights. Numerical simulation rather than empirical relation was used for estimating the median tsunami heights. Weights of discrete branches that represent alternative hypotheses and interpretations were determined by the questionnaire survey for tsunami and earthquake experts, whereas those representing the error of estimated value were determined on the basis of historical data. Examples of tsunami hazard curves were illustrated for the coastal sites, and uncertainty in the tsunami hazard was displayed by 5-, 16-, 50-, 84- and 95-percentile and mean hazard curves.  相似文献   

The use of sintered diamond anvils in the MA8 type high-pressure apparatus     

Tadashi Kondo  Hiroshi Sawamoto  Akira Yoneda  Manabu Kato  Akihito Matsumuro  Takehiko Yagi  Takumi Kikegawa 《Pure and Applied Geophysics》1993,141(2-4):601-611

A new multi-anvil type high-presure apparatus has been developed using sintered diamond anvils to generate pressures over 30 GPa and temperatures up to about 2000°C. A maximum sample volume of about 1 mm³ is available in this system. The pressure was confirmed by dissociation of forsterite into Mg-perovskite and periclase. The basic techniques and problems in utilizing sintered diamond in the MA8 type high-pressure apparatus are discussed with an emphasis on the future prospect of incorporating simultancous X-ray diffraction observation.  相似文献   

Tectonic implications of damage zone-related fault-fracture networks revealed in drill core through the Nojima fault, Japan   总被引：1，自引：0，他引：1  

Aiming Lin  Tadashi Maruyama  Kenta Kobayashi 《Tectonophysics》2007,443(3-4):161

1800 m of drill core through the Nojima fault zone, Japan, reveals subsidiary fault and fracture networks that developed in the fault zone that triggered the 1995 Ms 7.2 Kobe earthquake. The subsidiary fault zones contain a fault gouge of < 1 cm bounded by thin zones of foliated cataclasite or breccia. Fractures are filled with calcite veins, calcite-cemented breccias, clay, and iron-oxide and carbonate alternation of the granitic host rock. These features are typical of extensional fractures that form the conduit network for fluid flux close to a major fault zone. The zone of distributed deformation surrounding the main fault is 50 m in width, and the dip of the Nojima fault at > 1 km depth is 75°. The fault-fracture networks associated with the Nojima fault zone are coseismic and were filled with carbonate and fine-grained material during repeated seismic-related infiltration of the fault zone by carbonate-bearing subsurface water. This study shows that fault-related fracture networks plays an important role as fluid flow conduits within seismically active faults, and can change in character from zones of high permeability to low permeability due to cementation and/or pore collapse.  相似文献   

Resonance sticking in the scattered disk     

Patryk Sofia Lykawka  Tadashi Mukai 《Icarus》2007,192(1):238-247

We investigate the dynamical evolution of trans-neptunian objects (TNOs) in typical scattered disk orbits (scattered TNOs) by performing simulations using several thousand particles lying initially on Neptune-encountering orbits. We explore the role of resonance sticking in the scattered disk, a phenomenon characterized by multiple temporary resonance captures (‘resonances’ refers to external mean motion resonances with Neptune, which can be described in the form r:s, where the arguments r and s are integers). First, all scattered TNOs evolve through intermittent temporary resonance capture events and gravitational scattering by Neptune. Each scattered TNO experiences tens to hundreds of resonance captures over a period of 4 Gyr, which represents about 38% of the object's lifetime (mean value). Second, resonance sticking plays an important role at semimajor axes , where the great majority of such captures occurred. It is noteworthy that the stickiest (i.e., dominant) resonances in the scattered disk are located within this distance range and are those possessing the lowest argument s. This was evinced by r:1, r:2 and r:3 resonances, which played the greatest role during resonance sticking evolution, often leading to captures in several of their neighboring resonances. Finally, the timescales and likelihood of temporary resonance captures are roughly proportional to resonance strength. The dominance of low s resonances is also related to the latter. In sum, resonance sticking has an important impact on the evolution of scattered TNOs, contributing significantly to the longevity of these objects.  相似文献   

Pressure dependence of Néel transition in (Mg,Fe)O     

Atsuhiro Fujii  Tadashi Kondo  Toshifumi Taniguchi 《Physics and Chemistry of Minerals》2014,41(1):27-32

Pressure dependence of Néel temperature (T _N) in (Mg_0.20Fe_0.80)O, (Mg_0.25Fe_0.75)O, and (Mg_0.30Fe_0.70)O was newly measured up to 1.14 GPa, using superconducting quantum interference device magnetometer and piston–cylinder-type pressure cell under hydrostatic condition. The dT _N/dP values of (Mg_0.20Fe_0.80)O, (Mg_0.25Fe_0.75)O, and (Mg_0.30Fe_0.70)O were determined as 4.0 ± 0.3, 2.7 ± 0.3, and 4.4 ± 0.4 K/GPa, respectively, in linear approximation; however, the T _N deviated from the linearity under nonhydrostatic conditions. The compositional dependence of dT _N/dP in (Mg_1?X Fe _X )O showed a rapid decay with increasing Mg components at X ≥ 0.75 and the trend ended at X = 0.70. The estimated Néel transition pressure at room temperature by extrapolating these linearities are very similar to the rhombohedral distortion determined by previous X-ray diffraction studies for X ≥ 0.75, which suggests that the rhombohedral phase of (Mg_1?X Fe _X )O (X ≥ 0.75) at room temperature is antiferromagnetic under hydrostatic conditions.  相似文献   

North-south asymmetries of solar particle events in upper stratospheric ozone     

Kaichi Maeda  Donald F. Heath  Tadashi Aruga 《Planetary and Space Science》1984,32(7):857-870

Stratospheric ozone depressions, following intense solar particle events (SPE) observed by the backscattered ultraviolet (BUV) experiment on the Nimbus-4 satellite, indicate the existence of distinct asymmetries between the Northern and Southern Hemispheres. These asymmetries are observed in the magnitude of the depressions above the 5-mb level, their temporal variations, and the spatial (i.e., latitude and longitude) dependence of these variations. Possible causes of asymmetries, shown by two events on 4 August 1972 and 25 January 1971, can be attributed to: (1) tilt of the interplanetary magnetic field (IMF) with respect to the Earth's dipole magnetic field which influences the precipitation of energetic solar particles into the polar atmospheres; (2) differences in ozone chemistry caused by the large change in atmospheric temperature between summer and winter hemispheres; (3) seasonal differences of the stratosphere's dynamic states which are affected by upward propagating planetary waves in winter in contrast to the relatively undisturbed zonal flow in summer; (4) topographic asymmetry between Northern and Southern Hemispheres.These effects are shown by three-dimensional plots of the events in geographic coordinates and by color contour plots of the stratospheric ozone distributions in geomagnetic and geographic polar coordinates, respectively.  相似文献