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61.
Abstract Fifty calc-schists have been systematically collected from the Piemonte zone of the western Italian Alps and examined in terms of petrology, X-ray powder diffractometer (XRD) analysis of carbonaceous materials, and K-Ar ages of white mica separates. The petrological study and XRD analysis of carbonaceous materials have shown that calc-schists have suffered blueschist-facies metamorphism in the subduction zone of the convergent margin between the Apulian (African) continental and Tethyan oceanic plates. The metamorphic sequence is divided into three mineral zones based on increasing metamorphic temperature: chlorite (lower than 300°C), chloritoid, and rutile (higher than 450°C). The chlorite zone has dispersed ages of white mica separates, ranging from 115 to 44 Ma, whereas the rutile zone has a comparatively uniform age distribution from 60 to 40 Ma. The chloritoid zone has an intermediate age variation. The large variation in the chlorite zone is attributed to mixing of variable amounts of detrital mica derived from older high temperature metamorphic rocks in the separates, which have not been completely reset during Alpine metamorphism. The uniform age (average ca 50 Ma) in the rutile zone is the cooling age of blueschist-facies calc-schists, which have been episodically exhumed at the collision event of the European and Apulian continents in the Paleocene-Eocene.  相似文献   
62.
Abstract Elemental and isotopic compositions of noble gases extracted from the bore hole water in Osaka plain, central Japan were examined. The water samples were collected from four shallow bore holes (180-450 m) and seven deep bore holes (600-1370 m) which have been used for an urban resort hot spring zone. The water temperatures of the deep bore holes were 22-50°C and that of the shallow bore holes, 13-23°C. The elemental abundance patterns show the progressive enrichment of the heavier noble gases compared with the atmospheric noble gas composition except for He, which is heavily enriched in deep bore hole water samples. 3He/4He ratios from the bore holes reaching the Ryoke granitic basement were higher than the atmospheric value (1.4 × 10−6), indicating a release of mantle He through the basement. The highest value of 8.2 × 10−6 is in the range of arc volcanism. On the other hand, the bore holes in sedimentary rocks overlying the basement release He enriched in radiogenic 4He, resulted in a low 3He/4He ratio of 0.5 × 10−6. 4He/20Ne and 40Ar/36Ar ratios indicate that the air contamination is generally larger in shallow bore holes than in deep ones from each site. The helium enriched in mantle He is compatible with the previous work which suggested up-rising magma in 'Kinki Spot', the area of Osaka and western Wakayama, in spite of no volcanic activity in the area. A model to explain an initiation of magma generation beneath this area is presented.  相似文献   
63.
We demonstrate that artificial bipolar structure can be detected using spectro-astrometry when the point spread function (PSF) of a point source suffers distortion in a relatively wide slit. Spectro-astrometry is a technique which allows us to probe the spatial structure of astronomical sources on milliarcsec (mas) scales making it possible to detect close binaries and to study the geometry and kinematics of outflowing gas on scales much smaller than the seeing or the diffraction limit of the telescope. It is demonstrated that a distorted PSF, caused by tracking errors of the telescope or unstable active optics during an exposure, can induce artificial signals which may be misinterpreted as a real spectro-astrometric signal. Using simulations, we show that these may be minimized by using a narrow slit relative to the seeing. Spectra should be obtained at antiparallel slit position angles (e.g. 0° and 180°) for comparison in order to allow artificial signatures to be identified.  相似文献   
64.
Tetsumaru Itaya 《Lithos》1981,14(3):215-224
Carbonaceous material in pelitic schists of the Sanbagawa metamorphic belt in central Shikoku, Japan, was separated from the host rocks and its X-ray diffraction and chemical composition were studied. Its crystal structure and chemistry change continously with increasing metamorphic grade and approach those of well-ordered graphite near the biotite isograd. As graphitization is a rate process, the temperature of complete graphitization differs from one metamorphic terrain to another as a function of the duration of metamorphism. In an individual metamorphic terraan, however, the degree of graphitization is a useful indicator of relative metamorphic temperature in lower-grade rocks.  相似文献   
65.
Abstract It was revealed that the asymmetric X-ray diffraction peak of metamorphosed carbonaceous material was a combination of two types of symmetric peaks from the coaly material and graphite crystallite. Numerical synthesis using the two symmetric peaks shows the graphitization process observed in a metamorphic sequence is accompanied by a continuous change of the peak shape and apparent interplanar spacing. Based on the analytical results and geological observations, it is suggested that graphitization of carbonaceous material consists of two processes: (i) the formation of graphite crystallites at the expense of the coaly material through the formation of transitional material and the increasing abundance of crystallites which is observed in the chlorite zone; and (ii) growth of crystallites forming well-ordered graphite, which occurs in the higher-grade zone.  相似文献   
66.
Tsuyoshi  Nohara  Hidemi  Tanaka  Kunio  Watanabe  Noboru  Furukawa  Akira  Takami 《Island Arc》2006,15(4):537-545
Abstract   The spatial hydrogeological and structural character of the active Mozumi-Sukenobu Fault (MSF) was investigated along a survey tunnel excavated through the MSF in the Kamioka Mine, central Japan. Major groundwater conduits on both sides of the MSF are recognized. One is considered to be a subvertical conduit between the tunnel and the surface, and the other is estimated to be a major reservoir of old meteoric water alongside the MSF. Our studies indicate that part of the MSF is a sub-vertical continuous barrier that obstructs younger meteoric water observed in the south-eastern part of the Active Fault Survey Tunnel (AFST) and water recharge to the rock mass intersected by the north-western part of the AFST. The MSF might be a continuous barrier resulting in the storage of a large quantity of older groundwater to the northwest. The observations and results of in situ hydraulic tests indicate that the major reservoir is not the fault breccia associated with the northeast–southwest trending faults of the MSF, but the zone in which blocks of fractured rocks occur beside high angle faults corresponding to X shears whose tectonic stress field coincides with the present regional stress field and antithetic Riedel shears of the MSF. The results from borehole investigations in the AFST indicate that secondary porosity is developed in the major reservoir due to the destruction of filling minerals and fracture development beside these shears. The increase in hydraulic conductivity is not directly related to increased density of fractures around the MSF. Development of secondary porosity could cause the increase in hydraulic conductivity around the MSF. Our results suggest that minor conduits of the fracture network are sporadically distributed in the sedimentary rocks around the MSF in the AFST.  相似文献   
67.
The pre-Mesozoic metamorphic belt runs parallel to the Day Nui Con Voi - Red River shear zone in Vietnam to the south. The belt is mainly composed of hornblende gneisses, amphibolite lenses and mica-schists. Five hornblendes from a gneiss and an amphibolite were analyzed chemically and chronologically by Electron Probe Micro Analysis (EPMA) and 40Ar/39Ar methods. EPMA analyses show that hornblendes in the gneiss and the amphibolite have significant amount of edenite component and similar average composition. However, the recalculated Fe3+ content is significantly heterogeneous in a thin section while total Fe is nearly the same among the analyses. The rim of each crystal is higher in Fe3+/(Fe3+ + Fe2+) than the core. These chemical and petrological features suggest that the hornblendes have suffered significant oxidation, in particular, largely in the gneiss.

40Ar/39Ar analyses showed that the gneiss has a significant variation of plateau ages (2089±14, 1977±19 and 1873±13 Ma) among three hornblende grains, whereas the amphibolite gives the same plateau ages (2056±14 and 2044±21 Ma) for two grains. All grains of both samples have excess ages in the first few fractions at low temperatures and partial-loss ages between the excess and plateau spectra. The Ca/K ratios indicate some disturbed phases for the lower temperature spectra but the partial-loss ages are also derived from hornblende phase. These facts suggest that hornblende in the gneiss has experienced partial argon loss by oxidation and/or thermally activated argon diffusion process. However, the gneiss and the associated amphibolite have preserved the early Proterozoic tectono-metamorphic event in the hornblende crystals except for their rims, giving new evidence for the early Proterozoic event within the pre-Mesozoic metamorphic belt (northern Vietnam) south of the Red River shear zone in Indochina.  相似文献   

68.
Metamorphic rocks experience change in the mode of deformation from ductile flow to brittle failure during their exhumation. We investigated the spatial variation of phengite K–Ar ages of pelitic schist of the Sambagawa metamorphic rocks (sensu lato) from the Saruta River area, central Shikoku, to evaluate if those ages are disturbed by faults or not. As a result, we found that these ages change by ca 5 my across the two boundaries between the lower‐garnet and albite–biotite, and the albite–biotite and upper‐garnet zones. These spatial changes in phengite K–Ar ages were perhaps caused by truncation of the metamorphic layers by large‐scale normal faulting at D2 phase under the brittle‐ductile transition conditions (ca 300°C) during exhumation, because an actinolite rock was formed along a fault near the former boundary. Assuming that the horizontal metamorphic layers and a previously estimated exhumation rate of 1 km/my before the D2 phase, the change of 5 my in phengite K–Ar ages is converted to a displacement of about 10 km along the north‐dipping, low‐angle normal fault documented in the previous study. Phengite 40Ar–39Ar ages (ca 85 to 78 Ma) in the actinolite rock could be reasonably comparable to the phengite K–Ar ages of the surrounding non‐faulted pelitic schist, because the K–Ar ages of pelitic schist could have been also reset at temperatures close to the brittle–ductile transition conditions far below the closure temperature for thermal retention of argon in phengite (about 500–600°C).  相似文献   
69.
Concentrations of peroxy radicals were measured by a chemical amplification technique at a remote forested site as part of the Program for Research on Oxidants in a Forested Region in Nikko (PROFRN). During the measurement period of 22–27 July 2002, the mixing ratios of peroxy radicals averaged for 3 min at midday ranged from 109 to 134 pptv at a height approximately 5 m above the forest canopy. Significant diurnal variation in concentrations of peroxy radicals was observed, with the maximum usually occurring around noon. Most of the variation was driven by changes in the intensity of solar radiation. However, it was found that the peroxy radical concentration reached its peak about 3-h later than that of solar radiation on 24 and 26 July. The origins of this delay are discussed based on an analysis of the total radical budget in that period. A transport of polluted air masses to the site was one of possible causes for the inconsistency. In addition, the measured peroxy radical concentrations were compared with those derived from the deviations of NO-NO2-O3 photo-stationary state (PSSD) for clear days. The estimated half-hour-average concentrations of peroxy radical were in agreement with the PERCA measured in the morning and late afternoon. However the two techniques differed by as much as a factor of two during the time of near midday.  相似文献   
70.
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