Hydrogen isotopic substitution of solid methylamine through atomic surface reactions at low temperatures: A potential contribution to the D/H ratio of methylamine in molecular clouds     

Yasuhiro Oba  Takeshi Chigai  Yoshihiro Osamura  Naoki Watanabe  Akira Kouchi 《Meteoritics & planetary science》2014,49(1):117-132

We experimentally studied hydrogen (H)–deuterium (D) substitution reactions of solid methylamine (CH₃NH₂) under astrophysically relevant conditions. We also calculated the potential energy surface for the H–D substitution reactions of methylamine isotopologues using quantum chemical methods. Despite the relatively large energy barrier of more than 18 kJ mol^?1, CH₃NH₂ reacted with D atoms to yield deuterated methylamines at 10 K, suggesting that the H–D substitution reaction proceeds through quantum tunneling. Deuterated methylamines reacted with H atoms as well. On the basis of present results, we propose that methylamine has potential for D enrichment through atomic surface reactions on interstellar grains at very low temperatures in molecular clouds. D enrichment would occur in particular in the methyl group of methylamine.  相似文献   

Rates of Thermal and Chemical Evolution of Magmas in a Cooling Magma Chamber: a Chronological and Theoretical Study on Basaltic and Andesitic Lavas from Rishiri Volcano, Japan     

Kuritani  Takeshi; Yokoyama  Tetsuya; Nakamura  Eizo 《Journal of Petrology》2007,48(7):1295-1319

Rates of magmatic processes in a cooling magma chamber wereinvestigated for alkali basalt and trachytic andesite lavaserupted sequentially from Rishiri Volcano, northern Japan, bydating of these lavas using ²³⁸U–²³⁰Th radioactive disequilibriumand ¹⁴C dating methods, in combination with theoretical analyses.We obtained the eruption age of the basaltic lavas to be 29·3± 0·6 ka by ¹⁴C dating of charcoals. The eruptionage of the andesitic lavas was estimated to be 20·2 ±3·1 ka, utilizing a whole-rock isochron formed by U–Thfractionation as a result of degassing after lava emplacement.Because these two lavas represent a series of magmas producedby assimilation and fractional crystallization in the same magmachamber, the difference of the ages (i.e. 9 kyr) is a timescaleof magmatic evolution. The thermal and chemical evolution ofthe Rishiri magma chamber was modeled using mass and energybalance constraints, as well as quantitative information obtainedfrom petrological and geochemical observations on the lavas.Using the timescale of 9 kyr, the thickness of the magma chamberis estimated to have been about 1·7 km. The model calculationsshow that, in the early stage of the evolution, the magma cooledat a relatively high rate (>0·1°C/year), and thecooling rate decreased with time. Convective heat flux fromthe main magma body exceeded 2 W/m² when the magma was basaltic,and the intensity diminished exponentially with magmatic evolution.Volume flux of crustal materials to the magma chamber and rateof convective melt exchange (compositional convection) betweenthe main magma and mush melt also decreased with time, from 0·1 m/year to 10^–3 m/year, and from 1 m/yearto 10^–2 m/year, respectively, as the magmas evolved frombasaltic to andesitic compositions. Although the mechanism ofthe cooling (i.e. thermal convection and/or compositional convection)of the main magma could not be constrained uniquely by the model,it is suggested that compositional convection was not effectivein cooling the main magma, and the magma chamber is consideredto have been cooled by thermal convection, in addition to heatconduction. KEY WORDS: convection; magma chamber; heat and mass transport; timescale; U-series disequilibria  相似文献   

The 2010 European Venus Explorer (EVE) mission proposal     

Colin Frank Wilson  Eric Chassefière  Emmanuel Hinglais  Kevin H. Baines  Tibor S. Balint  Jean-Jacques Berthelier  Jacques Blamont  Georges Durry  Csaba S. Ferencz  Robert E. Grimm  Takeshi Imamura  Jean-Luc Josset  Fran?ois Leblanc  Sebastien Lebonnois  Johannes J. Leitner  Sanjay S. Limaye  Bernard Marty  Ernesto Palomba  Sergei V. Pogrebenko  Scot C. R. Rafkin  Dean L. Talboys  Rainer Wieler  Liudmila V. Zasova  Cyrill Szopa 《Experimental Astronomy》2012,33(2-3):305-335

The European Venus Explorer (EVE) mission described in this paper was proposed in December 2010 to ESA as an ‘M-class’ mission under the Cosmic Vision programme. It consists of a single balloon platform floating in the middle of the main convective cloud layer of Venus at an altitude of 55?km, where temperatures and pressures are benign (～25°C and ～0.5 bar). The balloon float lifetime would be at least 10 Earth days, long enough to guarantee at least one full circumnavigation of the planet. This offers an ideal platform for the two main science goals of the mission: study of the current climate through detailed characterization of cloud-level atmosphere, and investigation of the formation and evolution of Venus, through careful measurement of noble gas isotopic abundances. These investigations would provide key data for comparative planetology of terrestrial planets in our solar system and beyond.  相似文献   

Inflations prior to Vulcanian eruptions and gas bursts detected by tilt observations at Semeru Volcano,Indonesia     

Takeshi Nishimura  Masato Iguchi  Ryohei Kawaguchi  Surono  Muhamad Hendrasto  Umar Rosadi 《Bulletin of Volcanology》2012,74(4):903-911

We examine the basic characteristics of inflations at Semeru Volcano, Indonesia, to clarify the pressurization process prior to two different styles of explosive eruptions: Vulcanian eruptions and gas bursts. Analysis of data obtained from tilt meters installed close to the active crater allows clarification of the common features and the differences between the two styles of eruptions. To improve the signal-to-noise ratio and to determine the mean characteristics of the inflations, we stack tilt signals obtained from eruptions of different magnitudes and evaluate the maximum amplitude of the seismic signal associated with these eruptions. Vulcanian eruptions, which explosively release large amounts of ash, are preceded by accelerating inflation about 200–300 s before the eruption, which suggests volume expansion of the gas phase. In contrast, gas bursts, which rapidly effuse water steam accompanied by explosive sounds, follow non-accelerating changes of inflation starting 20 s before each emission. Tilt amplitudes increase with the magnitude of eruptions for both eruption styles. This suggests that the volume and/or pressure of magma or gas stored in the conduit before eruptions controls the magnitude of volcanic eruptions. These results further suggest that the magnitude of eruptions can be predicted from geodetic measurements of volcano inflation.  相似文献   

Lagrangian ensemble model of Copepoda (Neocalanus cristatus) in the northwestern subarctic Pacific     

Takeshi Terui  Michio J. Kishi  Hiromichi Ueno 《Journal of Oceanography》2012,68(5):727-741

A Lagrangian ensemble model describing the population dynamics of Neocalanus cristatus was developed. To describe the ecology of N. cristatus, life stage must be included in the model. For this purpose, a new zooplankton compartment, divided into nine life stages, was added to the North Pacific ecosystem model for understanding regional oceanography. In addition, we introduced Lagrangian particles for the copepod population. Each Lagrangian particle represented a population of the same cohort of copepods with information on representative age, developmental stage, growth rate, structural weight, and food satiation. The new model revealed that surviving cohorts are only matched with the phytoplankton bloom after the nauplii stages. The model showed that the existing phytoplankton concentration when copepodites of N. cristatus appear in the surface water determines the development pattern of copepodite stages. The timing of the seasonal phytoplankton bloom depends on climate change, and a sensitivity analysis showed that the multiple spawning strategy through time has an important role in matching the unstable seasonal bloom cycle on a daily basis. The model including the cohorts can collaborate closely with weekly or monthly observations to reveal the rapid response of the marine ecosystem.  相似文献   

Sound velocity measurements in dhcp-FeH up to 70 GPa with inelastic X-ray scattering: Implications for the composition of the Earth's core     

Yuki Shibazaki  Eiji Ohtani  Hiroshi Fukui  Takeshi Sakai  Seiji Kamada  Daisuke Ishikawa  Satoshi Tsutsui  Alfred Q.R. Baron  Naoya Nishitani  Naohisa Hirao  Kenichi Takemura 《Earth and Planetary Science Letters》2012

We have determined the density evolution of the sound velocity of dhcp-FeH_x (x ≈ 1) up to 70 GPa at room temperature, by inelastic X-ray scattering and by X-ray diffraction. We find that the variation of V_P with density is different for the ferromagnetic and nonmagnetic dhcp-FeH_x, and that only nonmagnetic dhcp-FeH_x follows Birch's law. Combining our results with Birch's law for iron and assuming an ideal two-component mixing model, we obtain an upper bound of the hydrogen content in the Earth's inner core, 0.23(6) wt.% H, corresponding to FeH_0.13(3). The iron alloy with 0.23(6) wt.% H can satisfy the density, and compressional and shear sound velocities of the PREM inner core, assuming that there are no other light elements in the inner core.  相似文献   

Recursive formula for the peak delay time with travel distance in von Kármán type non-uniform random media on the basis of the Markov approximation     

Tsutomu Takahashi  Haruo Sato  Takeshi Nishimura 《Geophysical Journal International》2008,173(2):534-545

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Characteristics of outer shelf water in the East China Sea     

Shigefumi Yanao  Takeshi Matsuno 《Journal of Oceanography》2013,69(2):245-258

Water mass properties along cross-sections of the Kuroshio in the East China Sea (ECS) are investigated in detail. We used temperature, salinity and dissolved oxygen data from 2000 and 2002, together with historical temperature and salinity data from 1987 to 2004. Water properties were divided into two groups: high and low salinities or oxygen at temperatures warmer than 15 and 12 °C, respectively. We found the existence of outer shelf water W2, as defined by clear modes in frequency distributions of salinity and oxygen within various temperature segments. The outer shelf water was different from both Kuroshio Tropical Water (KTW) and coastal water. We mapped horizontal and vertical distributions of W2, along with W1 and KTW. The outer shelf water was distributed with density σ _t = 22.5–25.5 over a relatively broad area, from the outer continental shelf to the continental slope, particularly in autumn. Vertical distribution of the water suggests that W2 spread from the outer shelf to just the shelf side of the Kuroshio Current velocity maximum. Seasonal variations are examined with historical data along PN section over 17 years, and suggest that the appearance of W2 is distinct in summer and autumn. By comparing temperature–salinity (T–S) diagrams from Taiwan Strait and east of Taiwan, the outer shelf water (W2) originates from South China Sea Tropical Water (SCSTW), as suggested by Chen, J Geophys Res 110:C05012 (2005). The present study of the ECS clearly shows that SCSTW is transported along the east coast of Taiwan or through the Taiwan Strait into the ECS. It then spreads over a relatively wide area from the outer shelf to just the shelf side of the Kuroshio axis, and there is some horizontal mixing between SCSTW and KTW around the shelf break.  相似文献   

Impacts of elevated CO2 on particulate and dissolved organic matter production: microcosm experiments using iron-deficient plankton communities in open subarctic waters     

Takeshi Yoshimura  Koji Suzuki  Hiroshi Kiyosawa  Tsuneo Ono  Hiroshi Hattori  Kenshi Kuma  Jun Nishioka 《Journal of Oceanography》2013,69(5):601-618

Response of phytoplankton to increasing CO₂ in seawater in terms of physiology and ecology is key to predicting changes in marine ecosystems. However, responses of natural plankton communities especially in the open ocean to higher CO₂ levels have not been fully examined. We conducted CO₂ manipulation experiments in the Bering Sea and the central subarctic Pacific, known as high nutrient and low chlorophyll regions, in summer 2007 to investigate the response of organic matter production in iron-deficient plankton communities to CO₂ increases. During the 14-day incubations of surface waters with natural plankton assemblages in microcosms under multiple pCO₂ levels, the dynamics of particulate organic carbon (POC) and nitrogen (PN), and dissolved organic carbon (DOC) and phosphorus (DOP) were examined with the plankton community compositions. In the Bering site, net production of POC, PN, and DOP relative to net chlorophyll-a production decreased with increasing pCO₂. While net produced POC:PN did not show any CO₂-related variations, net produced DOC:DOP increased with increasing pCO₂. On the other hand, no apparent trends for these parameters were observed in the Pacific site. The contrasting results observed were probably due to the different plankton community compositions between the two sites, with plankton biomass dominated by large-sized diatoms in the Bering Sea versus ultra-eukaryotes in the Pacific Ocean. We conclude that the quantity and quality of the production of particulate and dissolved organic matter may be altered under future elevated CO₂ environments in some iron-deficient ecosystems, while the impacts may be negligible in some systems.  相似文献   

Middle Jurassic spinicaudatan <Emphasis Type="Italic">Shizhuestheria</Emphasis> from the Sichuan Basin and its ontogenetic implication     

Gang Li  Hiromichi Hirano  Takeshi Kozai  Takashi Sakai  YanHong Pan 《中国科学D辑(英文版)》2009,52(12):1962-1968

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