甲醛对Nessler法和次氯酸酚盐法测定养殖水体总氨氮的影响   总被引：1，自引：0，他引：1  

罗国芝  谭洪新  朱学宝  霍少勇 《中国海洋大学学报(自然科学版)》2002,32(3):397-402

水体中含一定浓度的甲醛 ,用 Nessler法测得的总氨氮 (TAN)浓度远远高于实际浓度 ,差异百分数最高达 4 5 0 .0 6 % ;用次氯酸酚盐法测得的总氨氮 (TAN)浓度则明显低于实际浓度 ,差异百分数最高可达 84 .77%。甲醛浓度范围为 10～ 4 0 mg/ L、TAN浓度为 1～ 10 mg/ L,通过双因素有重复观察值的交叉实验 ,得到如下矫正式 :(1)用 Nessler法测 TAN时 ,Y=4 .0 5 2 9- 0 .0 72 4 x1+ 0 .2 0 6 4x2 ,标准误差为 1.3381;(2 )用次氯酸酚盐法测 TAN时 ,Y=0 .1196 + 0 .0 345 x1+ 1.0 0 2 2 x2 ,标准误差为 0 .4 6 2 7。 Y为 TAN实际浓度 (mg/ L) ,x1为甲醛浓度 (mg/ L) ,x2 为测得的 TAN浓度(mg/ L )。比较含氨氮水体与不含氨氮水体中的甲醛浓度 ,方差分析结果表明 ,没有显著差异。  相似文献   

Spatial and temporal variations of mesozooplankton in the Pearl River estuary, China   总被引：10，自引：0，他引：10  

K.Z. Li  J.Q. Yin  L.M. Huang  Y.H. Tan   《Estuarine, Coastal and Shelf Science》2006,67(4):543-552

This paper examines spatial and temporal variations of mesozooplankton abundance, biomass and community structure during three cruises of July 2002 (summer), January 2003 (winter), and April 2003 (spring) in the Pearl River estuary, China. Zooplankton abundance and biomass fluctuated widely and showed distinct heterogeneity in the Pearl River estuary. A total of 154 species were identified during three surveys. The number of zooplankton species richness was strongly linked to salinity. Hierarchical cluster analysis identified three zooplankton groups during this study. Estuarine, neritic and pelagic groups corresponded to the upper, middle and lower reaches in the Pearl River estuary. The difference among groups could be mainly ascribed to changes in the relative contributions of the dominant species. The fluctuations in the zooplankton abundance, biomass and community structure were determined by the interactive effects of freshwater inflow, tidal and coastal currents, chlorophyll a, salinity and temperature. Significant spatial variability in the distribution of zooplankton species, abundance and biomass can be ascribed to the virtual presence of a horizontal gradient in salinity.  相似文献   

Impact of 4DVAR assimilation of rainfall data on the simulation of mesoscale precipitation systems in a mei-yu heavy rainfall event   总被引：1，自引：0，他引：1  

储可宽  谈哲敏 《大气科学进展》2007,24(2):281-300

The multi-scale weather systems associated with a mei-yu front and the corresponding heavy precipitation during a particular heavy rainfall event that occurred on 4 5 July 2003 in east China were successfully simulated through rainfall assimilation using the PSU/NCAR non-hydrostatic, mesoscale, numerical model （MM5） and its four-dimensional, variational, data assimilation （4DVAR） system. For this case, the improvement of the process via the 4DVAR rainfall assimilation into the simulation of mesoscale precipitation systems is investigated. With the rainfall assimilation, the convection is triggered at the right location and time, and the evolution and spatial distribution of the mesoscale convective systems （MCSs） are also more correctly simulated. Through the interactions between MCSs and the weather systems at different scales, including the low-level jet and mei-yu front, the simulation of the entire mei-yu weather system is significantly improved, both during the data assimilation window and the subsequent 12-h period. The results suggest that the rainfall assimilation first provides positive impact at the convective scale and the influences are then propagated upscale to the meso- and sub-synoptic scales.
Through a set of sensitive experiments designed to evaluate the impact of different initial variables on the simulation of mei-yu heavy rainfall, it was found that the moisture field and meridional wind had the strongest effect during the convection initialization stage, however, after the convection was fully triggered, all of the variables at the initial condition seemed to have comparable importance.  相似文献   

不同海域沉积物对尿素吸附的实验模拟研究     

薛峤娜  胡博  谭丽菊  王江涛 《海洋学报》2018,40(10):190-199

本文对采自渤海、黄海和东海3个典型海域的沉积物进行了尿素吸附/解吸的实验室模拟研究,用Freundlich吸附模型和Henry吸附模型分析了不同沉积物对尿素吸附的热力学特性,并研究了温度、沉积物粒径、有机质含量等因素对尿素在沉积物表面吸附的影响。结果表明,沉积物对尿素的吸附/解吸过程总体呈现3个阶段:快速吸附阶段（0~5 h）—慢速吸附阶段（5~12 h）—平衡阶段（12 h之后）。当水体中的尿素浓度较低时,沉积物解吸释放尿素,随着上覆水中尿素浓度逐渐增加,沉积物对上覆水中的尿素产生吸附行为,各海区沉积物对尿素的吸附能力由强至弱依次为渤海、东海、黄海,这可能与沉积物的类型有关。Freundlich方程和Henry方程均可模拟沉积物对尿素的吸附,温度、粒径以及沉积物中有机质含量等因素均对尿素在沉积物上的吸附产生影响,随着温度升高,尿素在沉积物上的吸附量变小,沉积物粒径越小,有机质含量越高,吸附尿素的能力越强,因此,揭示尿素在沉积物表面的环境行为时,必须考虑以上因素的影响。  相似文献   

Leak-off mechanism and pressure prediction for shallow sediments in deepwater drilling     

Qiang Tan  Jingen Deng  Jin Sun  Wei Liu  Baohua Yu 《中国海洋大学学报(英文版)》2018,17(1):65-71

Deepwater sediments are prone to loss circulation in drilling due to a low overburden gradient. How to predict the magnitude of leak-off pressure more accurately is an important issue in the protection of drilling safety and the reduction of drilling cost in deep water. Starting from the mechanical properties of a shallow formation and based on the basic theory of rock-soil mechanics, the stress distribution around a borehole was analyzed. It was found that the rock or soil on a borehole is in the plastic yield state before the effective tensile stress is generated, and the effective tangential and vertical stresses increase as the drilling fluid density increases; thus, tensile failure will not occur on the borehole wall. Based on the results of stress calculation, two mechanisms and leak-off pressure prediction models for shallow sediments in deepwater drilling were put forward, and the calculated values of these models were compared with the measured value of shallow leak-off pressure in actual drilling. The results show that the MHPS (minimum horizontal principle stress) model and the FIF (fracturing in formation) model can predict the lower and upper limits of leak-off pressure. The PLC (permeable lost circulation) model can comprehensively analyze the factors influencing permeable leakage and provide a theoretical basis for leak-off prevention and plugging in deepwater drilling.  相似文献   

Compact and tunable mid-infrared source based on a 2 μm dual-wavelength KTiOPO₄ intracavity optical parametric oscillator     

耿优福  谭晓玲  李学金  姚建铨 《海洋学报(英文版)》2010,29(11)

Using a double resonant KTiOPO₄ (KTP) intracavity optical parametric oscillator operating at degenerated point of 2 μm, we demonstrate a unique mid-infrared source based on difference frequency generation in GaSe crystal. The output tuning range is 8.42-19.52 μm, and a peak power of 834 W for type-I phase matching scheme and 730 W for type-II phase matching scheme are achieved. Experimental results show that this oscillator is a good alternative to the generator of a compact and tabletop mid-infrared radiation with a widely tunable range.  相似文献   

Characterizing the hydraulic properties of unsaturated sand considering various porosities and drying‐wetting paths of the retention curve     

Kai‐yuan Ke  Yih‐Chi Tan  Chu‐Hui Chen  Hsien‐Tsung Lin 《水文研究》2013,27(4):592-604

Previous studies have shown that water retention curve (WRC) and the hydraulic conductivity vary because of changes of the void ratio or porosity of soil. However, limited documents pointed out the change of hydraulic properties of soil when compacted to different porosities while considering both of the drying and wetting processes of the WRC. This information is sometimes necessary for research like finger flow analysis or the occurrence of wetting and drying cycles as what would be seen in the field. Therefore, this study aims to examine the change of WRC characteristics with varied porosity considering both of the drying and wetting path in WRC by conducting a sand box experiment. Results show that the same type of sand compacted to various porosities have different hydraulic parameters. Hydraulic conductivities generally decrease with reduced porosities; shape parameter α of the van Genuchten equation (1980) linearly decreases with declining porosity and shape parameter n in a reversal manner for the sands of interest whether in the drying process or wetting process. The unsaturated properties of sand are further characterized by inspecting the variations of moisture content, matric suction and vertical displacement of soil body subject to periodic changes of the water level by another sand box experiment. The outcomes suggest that the saturated water content and residual water content are changing during the wetting–drying process, which can be an implication of the changed properties of WRC. The characteristics of volumetric deformation might be varied as well because of the observation of the dissimilar patterns of the changing vertical displacements among each wetting–drying process. Infiltration patterns of the sands also are identified through numerical modelling by introducing a constant infiltration flux from the surface followed by a no‐influx condition. Results indicate that less water accumulates in the sand near the surface for the sand compacted to higher porosity, but water can move deeper. Hydraulic conductivity is found as the prime factor dominating the evolvement of wetting fronts. However, shape parameters of water retention curves also affect the infiltration pattern to some extent. In addition, different sands with similar porosities can have quite different infiltrating characteristics. Copyright © 2012 John Wiley & Sons, Ltd.  相似文献   

天然河道一维不恒定流计算的守恒格式   总被引：2，自引：2，他引：2       下载免费PDF全文

谭维炎  胡四一 《水科学进展》1990,1(1):22-32

本文从数值计算的角度分析和讨论了天然河道一维不恒定流方程组的各种形式及其差分格式的守恒性。据此,本文总结了建立守恒差分格式的途径和应遵循的原则,并就差分格式如何达到准确或近似守恒提出了实际的处理方法。  相似文献   

焦耳效应标定高温卡尔维微量热计     

Tang Yuanjun Tan Dafang Mao Yi 《地球科学》1989,(3)

根据热流式量热计的Tian氏方程,用焦耳效应标定高温卡尔维微量热计。用偏差法得到的灵敏度值与积分法测得的值一致。用回归曲线对灵敏度实验值进行拟合,利用计算机求得灵敏度—温度回归曲线,得到了室温至700℃的全部灵敏度值,从而即可使用微量热计测量此温度范围内的未知样品热效应。  相似文献   

地震拓扑预测     

谭承业  阮圣娜 《地震研究》1989,12(3):193-200

本文对地震参数建立了地震拓扑空间并把灰色系统理论中的拓扑预测方法引入地震预测之中,研究地震长趋势的预测问题。  相似文献