Photo-induced degradation of emamectin benzoate: effect of iron amendments and solvent system     

Saadia Rashid Tariq  Nazia Rafique  Sana Kiran  Abdul Muqeet Khan 《Environmental Earth Sciences》2014,72(4):983-988

Photodegradation is the major dissipation pathway for emamectin benzoate (EB) in water. Therefore, the photolysis of EB was studied in distilled water (DW) and methanol under different irradiation conditions such as natural sunlight, UV tube, and artificially stimulated light (mercury lamp 125 W). The results of the study showed that EB degrades rapidly in DW than in methanol as evidenced by a photodegradation efficiency of about 75 % achieved in DW, after 24 h of irradiation with UV light, while in methanol, it was only 59.3 %. The addition of iron to EB solution in DW further enhanced its photodegradation. The rate of photodegradation of EB was recorded to be increased from 5.5 × 10^?2 to 1.0 × 10^?1 k/h after amendment with iron. The order for the rate of photodegradation of EB was DW + Fe > DW > methanol, with their respective t _1/2 values of 6.5, 12.6, and 18.7 h. Fe amendment was also found to enhance the degradation efficiency of EB even in the absence of any light (dark).  相似文献   

Effect of Fe2+ amendment on photodegradation kinetics of imidacloprid in moist soil     

Nazia Rafique  Saadia R. Tariq  Mateen Abbas 《Environmental Earth Sciences》2014,71(6):2869-2874

The present study deals with the effect of Fe²⁺ on degradation kinetics of imidacloprid in moist soil under UV system. The moist soil samples were spiked with imidacloprid and irradiated in specially designed UV-photoreactor. The analysis of imidacloprid was carried out by using HPLC–DAD system. UV irradiation caused about ten fold increase in photodegradation rate of the pesticide. Amendment of soil with Fe²⁺ at concentrations of 30 mg/kg led to a further increase in the rate of photodegradation, i.e., a 98 % degradation of imidacloprid was observed in the presence of iron after 32 days of irradiation. Moreover, the half-life of imidacloprid in Fe²⁺ -amended soil was observed to be reduced to 7 days that in the absence of Fe²⁺ was recorded to be 21 days. Iron was also observed to affect the half-life of imidacloprid in dark. When compared with unsterilized Fe²⁺-amended batch treatments, the t _1/2 in sterilized Fe²⁺-amended batch treatments increased from 58 to 96 days. Imidacloprid-urea was detected by HPLC as the only stable photodegradation byproduct of imidacloprid in the soil.  相似文献   

The geochronology and petrogenesis of Walash volcanic rocks,Mawat nappes: constraints on the evolution of the northwestern Zagros suture zone,Kurdistan Region,Iraq   总被引：1，自引：0，他引：1  

Khalid J. A. Aswad  Azzam H. M. Al-Samman  Nabaz R. H. Aziz  Alan M. A. Koyi 《Arabian Journal of Geosciences》2014,7(4):1403-1432

Geological, geochemical, and geochronological investigations of the upper volcanics (UV) of Lower allochthon (LA) of Mawat nappes (MN) were used to elucidate the geologic relationships between the LA, the Qulqula Rise (i.e., accretionary complex terrane (ACT)) and peripheral Foreland Basin Assemblage (FBA), (Maastrichtian–Paleogene). The ⁴⁰Ar-³⁹Ar geochronological data suggest that the Middle to Late Paleogene magmatic history of Late Walash arc volcanic activity of UV can be divided into an early phase of andesitic volcanism around 43.1?±?0.3 Ma and subsequent extensional arc phase magmatism of a time lapse between 40.1?±?0.3and 32.3?±?0.4 Ma. The geochemical data establish the existence of gradients in trace element ratios (i.e., Ba/La, Th/Yb, U/La, Ba/Th, Rb/Y, Ba/Y, and Nb/Y) throughout the studied samples and reflect differences in the degree of mantle wedge depletion influenced by addition of a considerable proportion of sedimentary derived input of the subducting Arabian slab. The trace, rare earth elements and isotopes of the studied samples have emphasized differences in the geochemical characteristics of andesites in comparison with other members of Walash. The andesites have subduction-related signature with the isotope (low Nd and high Sr isotope ratios) characteristic of a melt component input from cratonically-derived sediments. The diabases intruding in the basalts and andesites have a transitional composition from andesitic to N-type mid-ocean ridge basalts geochemistry with a noticeable subduction-related signature, and are interpreted to form in an extensional arc evolving into back arc basin setting. As evidenced from infant arc magmatism (Albian–Cenomenian), MN recorded protracted kinematic at convergent plate margins with a most notable was the development of the ACT (i.e., Qulqula Rise) adhered to the Arabian platform carbonates (Albian–Cenomenian) leading to the inception of peripheral FBA occurred by the erosion and unroofing of advancing ACT. Notably, the volcano flysch of Walash and Nummulite carbonate of Naopurdan were still accumulating on the remaining oceanic lithosphere further to the northeast and in part coeval with Paleogene molasses sedimentation on flexural FBA further to the southwest of the ACT.  相似文献   

Mean runoff coefficient estimation for ungauged streams in the Kingdom of Saudi Arabia     

Abdul Aziz Saleh Al-Hasan  Yousry El-Sayed Mattar 《Arabian Journal of Geosciences》2014,7(5):2019-2029

Runoff coefficient estimation in ungauged watersheds has a priority for rain water harvesting and management of runoff water, for domestic and agriculture activities, in semi-arid and arid regions. To estimate mean runoff coefficient (C _Re) for ungauged streams, Pearson's coefficient of linear correlation (r) was measured. The method of linear regression (y?=?mx?+?c) was applied for 16 gauged catchments representing several regions in the Kingdom of Saudi Arabia, such as Al Qassim, Al Madinah, Riyadh, Asir, Makkah, and Jazan. The studied catchments were equally divided into two groups based on their main streams slopes; group A includes eight gauged streams having main stream slope less than 0.01, where group B includes eight gauged streams having main stream slope equal to or greater than 0.01. The result yields the constant of the linear regression for each group and the mean runoff coefficient of basin by an independent value (basin slope) for group A and an independent value (stream slope) for group B. The results indicate that the measured runoff coefficient (C _Rm) and the estimated runoff coefficient (C _Re) are almost equal to each other.  相似文献   

Effects of Cyclic Loading on the Shear Behaviour of Infilled Rock Joints Under Constant Normal Stiffness Conditions     

Ali Mirzaghorbanali  Jan Nemcik  Naj Aziz 《Rock Mechanics and Rock Engineering》2014,47(4):1373-1391

The variation of the shear strength of infilled rock joints under cyclic loading and constant normal stiffness conditions is studied. To simulate the joints, triangular asperities inclined at angles of 9.5° and 18.5° to the shear movement were cast using high-strength gypsum plaster and infilled with clayey sand. These joints were sheared cyclically under constant normal stiffness conditions. It was found that, for a particular normal stiffness, the shear strength is a function of the initial normal stress, initial asperity angle, joint surface friction angle, infill thickness, infill friction angle, loading direction and number of loading cycles. Based on the experimental results, a mathematical model is proposed to evaluate the shear strength of infilled rock joints in cyclic loading conditions. The proposed model takes into consideration different initial asperity angles, initial normal stresses and ratios of infill thickness to asperity height.  相似文献   

Mechanical Effect of Vetiver Grass Root for Stabilization of Natural and Terraced Hill Slope     

Aziz  Shamontee  Islam  Mohammad Shariful 《Geotechnical and Geological Engineering》2022,40(6):3267-3286

Geotechnical and Geological Engineering - This paper studies the role of vetiver grass (Vetiveria zizanoides) on the stability of hill slopes through physical and numerical modeling. Vetiver...  相似文献   

Soil erosion assessment on hillslope of GCE using RUSLE model     

Md. Rabiul Islam  Wan Zurina Wan Jaafar  Lai Sai Hin  Normaniza Osman  Moktar Aziz Mohd Din  Fathiah Mohamed Zuki  Prashant Srivastava  Tanvir Islam  Md. Ibrahim Adham 《Journal of Earth System Science》2018,127(4):50

A new method for obtaining the C factor (i.e., vegetation cover and management factor) of the RUSLE model is proposed. The method focuses on the derivation of the C factor based on the vegetation density to obtain a more reliable erosion prediction. Soil erosion that occurs on the hillslope along the highway is one of the major problems in Malaysia, which is exposed to a relatively high amount of annual rainfall due to the two different monsoon seasons. As vegetation cover is one of the important factors in the RUSLE model, a new method that accounts for a vegetation density is proposed in this study. A hillslope near the Guthrie Corridor Expressway (GCE), Malaysia, is chosen as an experimental site whereby eight square plots with the size of \(8\times 8\) and \(5\times 5\) m are set up. A vegetation density available on these plots is measured by analyzing the taken image followed by linking the C factor with the measured vegetation density using several established formulas. Finally, erosion prediction is computed based on the RUSLE model in the Geographical Information System (GIS) platform. The C factor obtained by the proposed method is compared with that of the soil erosion guideline Malaysia, thereby predicted erosion is determined by both the C values. Result shows that the C value from the proposed method varies from 0.0162 to 0.125, which is lower compared to the C value from the soil erosion guideline, i.e., 0.8. Meanwhile predicted erosion computed from the proposed C value is between 0.410 and \(3.925\, \hbox {t ha}^{-1 }\,\hbox {yr}^{-1}\) compared to 9.367 to \(34.496\, \hbox {t ha}^{-1}\,\hbox {yr}^{-1 }\) range based on the C value of 0.8. It can be concluded that the proposed method of obtaining a reasonable C value is acceptable as the computed predicted erosion is found to be classified as a very low zone, i.e. less than \(10\, \hbox {t ha}^{-1 }\,\hbox {yr}^{-1}\) whereas the predicted erosion based on the guideline has classified the study area as a low zone of erosion, i.e., between 10 and \(50\, \hbox {t ha}^{-1 }\,\hbox {yr}^{-1}\).  相似文献   

Improvement in Engineering Properties of Expansive Soils using Ground Granulated Blast Furnace Slag     

Hassan Mujtaba  Tahir Aziz  Khalid Farooq  Nagaratnam Sivakugan  Braja M. Das 《Journal of the Geological Society of India》2018,92(3):357-362

Improvement in engineering properties of expansive soils by mixing ground granulated blast furnace slag (GGBFS) is the main focus of this research. For this purpose two expansive soil samples were collected from DG Khan and Sialkot areas (Pakistan). Classification tests revealed that DG Khan sample belonged to fat clay (CH) while Sialkot soil was lean clay (CL) as classified by Unified Soil Classification System. GGBFS has been added in varying proportions between 0 and 55% in these soil samples to study its role in stabilizing these expansive soils. Based on the laboratory test performed on composite soil samples, it was observed that maximum dry unit weight increased up to 10 % by adding 50% GGBFS in both samples. California bearing ratio (CBR) value showed an increase from 3.2 % to 11.5% for DG Khan soil while CBR values varied from 2.4% to 10.7% for Sialkot soil by mixing 50% GGBFS. Addition of 30 % GGBFS to DG Khan soil reduced swell potential from 8 % to 2 % while in Sialkot soil, 20 % addition of GGBFS reduced swell potential from 5 % to 2 %. Unconfined compressive strength of remoulded sample cured for 28 days increased by about 35% with the addition of 30%GGBFS. The results indicated that mixing of GGBFS in the expansive soil samples have a marked increase in their engineering properties. Also, it is an affective and environmental friendly means to dispose waste of steel industry.  相似文献   

Riverine flood assessment in Jhang district in connection with ENSO and summer monsoon rainfall over Upper Indus Basin for 2010     

Bushra Khalid  Débora Souza Alvim  Shumaila Javeed  Junaid Aziz Khan  Muhammad Asif Javed  Azmat Hayat Khan 《Natural Hazards》2018,92(2):971-993

Pakistan has experienced severe floods over the past decades due to climate variability. Among all the floods, the flood of 2010 was the worst in history. This study focuses on the assessment of (1) riverine flooding in the district Jhang (where Jhelum and Chenab rivers join, and the district was severely flood affected) and (2) south Asiatic summer monsoon rainfall patterns and anomalies considering the case of 2010 flood in Pakistan. The land use/cover change has been analyzed by using Landsat TM 30 m resolution satellite imageries for supervised classification, and three instances have been compared, i.e., pre-flooding, flooding, and post-flooding. The water flow accumulation, drainage density and pattern, and river catchment areas have been calculated by using Shutter Radar Topography Mission digital elevation model 90 m resolution. The standard deviation of south Asiatic summer monsoon rainfall patterns, anomalies and normal (1979–2008) has been calculated for July, August, and September by using rainfall data set of Era interim (0.75° × 0.75° resolution). El Niño Southern Oscillation has also been considered for its role in prevailing rainfall anomalies during the year 2010 over Upper Indus Basin region. Results show the considerable changing of land cover during the three instances in the Jhang district and water content in the rivers. Abnormal rainfall patterns over Upper Indus Basin region prevailed during summer monsoon months in the year 2010 and 2011. The El Niño (2009–2010) and its rapid phase transition to La Niña (2011–2012) may be the cause of severity and disturbances in rainfall patterns during the year 2010. The Geographical Information System techniques and model based simulated climate data sets have been used in this study which can be helpful in developing a monitoring tool for flood management.  相似文献   

Application of Analytic Signal and Euler Deconvolution in Archaeo-Magnetic Prospection for Buried Ruins at the Ancient City of Pelusium, NW Sinai, Egypt: A Case Study   总被引：1，自引：0，他引：1  

Akram Mekhael Aziz  William August Sauck  El-Arabi Hendi Shendi  Mohamed Ahmed Rashed  Mohamed Abd El-Maksoud 《Surveys in Geophysics》2013,34(4):395-411

Progress in the past three decades in geophysical data processing and interpretation techniques was particularly focused in the field of aero-geophysics. The present study is to demonstrate the application of some of these techniques, including Analytic Signal, Located Euler Deconvolution, Standard Euler Deconvolution, and 2D inverse modelling, to help in enhancing and interpreting the archeo-magnetic measurements. A high-resolution total magnetic field survey was conducted at the ancient city of Pelusium (name derived from the ancient Pelusiac branch of the Nile, and recently called Tell el-Farama), located in the northwestern corner of the Sinai Peninsula. The historical city had served as a harbour throughout the Egyptian history. Different ruins at the site have been dated back to late Pharaonic, Graeco-Roman, Byzantine, Coptic, and Islamic periods. An area of 10,000 m², to the west of the famous huge red brick citadel of Pelusium, was surveyed using the magnetic method. The chosen location was recommended by the Egyptian archaeologists, where they suspected the presence of buried foundations of a temple to the gods Zeus and Kasios. The interpretation of the results revealed interesting shallow-buried features, which may represent the Temple’s outer walls. These walls are elongated in the same azimuth as the northern wall of the citadel, which supports the hypothesis of a controlling feature such as a former seacoast or shore of a distributary channel.  相似文献