Weathering of phlogopite in simulated bioleaching solutions     

Tariq M. Bhatti  Jerry M. Bigham  Antti Vuorinen  Olli H. Tuovinen 《International Journal of Mineral Processing》2011,98(1-2):30-34

The purpose of this study was to examine structural alterations of finely ground phlogopite, a trioctahedral mica, when exposed to acid, iron- and sulfate-rich solutions typical of bioleaching systems. Phlogopite suspensions were supplemented with ferrous sulfate and incubated with iron- and sulfur-oxidizing bacteria (Acidithiobacillus ferrooxidans) at 22 °C. As bacteria oxidized ferrous iron, ferric iron thus formed partially precipitated as K-jarosite. K-jarosite precipitation was contingent on the preceding ferrous iron oxidation by bacteria and the release of interlayer-K from phlogopite. This chemically and microbially induced weathering involved alteration of phlogopite to a mixed layer structure that included expansible vermiculite. The extent of phlogopite weathering and structure expansion varied with duration of the contact, concentration of ferrous iron and phlogopite, and the presence of monovalent cations (NH₄⁺, K⁺, or Na⁺) in the culture solution. NH₄⁺ and K⁺ ions (100 mM) added to culture suspensions precipitated as jarosite and thereby effectively prevented the loss of interlayer-K and structural alteration of phlogopite. Additional Na⁺ (100 mM) was insufficient to precipitate ferric iron as natrojarosite and therefore the precipitation was coupled with interlayer-K released from phlogopite. When ferrous iron was replaced with elemental sulfur as the substrate for A. ferrooxidans, the weathering of phlogopite was based on chemical dissolution without structural interstratification. The results demonstrate that iron oxidation and the concentration and composition of monovalent ions can have an effect on mineral weathering in leaching systems that involve contact of phlogopite and other mica minerals with acid leach solutions.  相似文献   

Hydrogeophysical investigation of groundwater potential in the El Bawiti, Northern Bahariya Oasis, Western Desert, Egypt   总被引：1，自引：1，他引：0  

Mohamed El Kashouty  Aiman Abdel Aziz  Mamdouh Soliman  Hany Mesbah 《Arabian Journal of Geosciences》2011,5(5):953-970

The future development of agriculture, industry, and civil activity planned to be in the Western Desert. This strategy need to the groundwater resource. Vertical electrical soundings (VES) and electromagnetic (TEM) measurements conducted in the El Bawiti, northern Bahariya Oasis. The measurements give detailed information about the geometry of the different hydrogeological layers in the aquifer system and depth to them. A total of 22 VES and TEM were carried out within El Bawiti area. Thirty-one sub soil samples were collected from eight sites to determine the chemical characteristics and address the effects of lithogenic source and anthropogenic activity on them. The geoelectrical measurements and borehole information indicate the presence of five geoelectrical units, from top to base; the surface cover, sand and shale, upper aquifer (Nubian sandstone), sand and shale, and lower aquifer (Nubian sandstone). Surface cover was equally distributed in thickness and composed of dry sand, gravel, and clay deposits. The regional resistivity of the upper aquifer increased in the southwestern part and decline in the northern, eastern, southern, and western parts. The decline in the resistivity reflects the high water yields and potentiality, as well as low salinity. The resistivity of the lower aquifer increased due the northwestern part and the southwestern part. The information collected during this research provides valuable data for estimating the fresh- to brackish-water resources and for development of a groundwater management plan. The integrated analyses carried out represent a significant and cost-effective method for delineating the main aquifer in this area. In turn, future well locations can be placed with more confidence than before, in accordance with the evaluation of the potentiality of the groundwater aquifers in the area. The electrical conductivity of the soil ranges from 302 to 8,490 μS/cm, increases in the western and central-northern parts. It is attributed to the location from the salt-affected soils (playa), the relatively lower elevation units (depressions) and the position in landscape in the Oasis. Sodium adsorption ratio ranges from 0.44 to 11 and the exchangeable sodium ratio ranges from 0.11 to 5. The estimated magnesium hazard fluctuated below 50%. The statistical analyses were accomplished in soil chemistry and discussed.  相似文献   

Scenario Reduction Applied to Geostatistical Simulations     

Margaret Armstrong  Aziz Ndiaye  Rija Razanatsimba  Alain Galli 《Mathematical Geosciences》2013,45(2):165-182

Having a large number of geostatistical simulations of a mineral or petroleum deposit provides a better idea of its upside potential and downside risk; however, large numbers of simulated realizations of a deposit may pose computational difficulties in subsequent decision-making phases. Hence, depending on the specific case, there can be a need to select a representative subset of conditionally simulated deposit realizations. This paper examines and extends an approach developed by the stochastic optimization community based on stochastic mathematical programming with recourse and is discussed here in the context of mineral deposits while it is possibly suitable for other earth science applications. The approach is based on measuring the “distance” between simulations and the introduced distance measure between simulated realizations of a mineral deposit is based on the metal above a given set of cutoff grades while a pre-existing mine design is available. The approach is tested on 100 simulations of the Walker Lake data with promising results.  相似文献   

A Parametric Study on Stability of Open Excavations in Alluvial Soils of Lahore District, Pakistan     

Muhammad Irfan  Aziz Akbar  Mubashir Aziz  Ammad Hassan Khan 《Geotechnical and Geological Engineering》2013,31(2):729-738

Rapid urbanization and expansion of metropolitans in the developing world is pressing the need of tall structures with multiple basements. In several such projects, open land is available around excavation site and unsupported deep excavations by maintaining appropriate side slopes offer economical solution. In this research, subsoil stratigraphy of Lahore district was established to be comprising of a top clay stratum 1.5–8 m thick, followed by a sand layer. Considering subsoil data from several geotechnical investigation reports, the effect of four key parameters viz., cohesion of clay layer, friction angle of sand layer, thickness of clay layer at the top and slope inclination of underlying sand layer on safety factor of open excavations was studied. Six hundred twenty-five slope stability analyses were conducted by considering different geometries and soil properties. Based on the results of these analyses, a regression model was suggested to estimate safety factor of open excavations in similar stratigraphy which would be useful in feasibility studies and preliminary design of deep excavations. It was established that the clay layer cohesion was the most dominant contributor to safety factor.  相似文献   

Singularity. A manifesto for incomparable geographies     

Tariq Jazeel 《Singapore journal of tropical geography》2019,40(1):5-21

This paper is a methodological response to the challenge of decolonizing geographical knowledge. It mobilizes post‐ and de‐colonial critiques of geographical knowledge production and conceptual work, suggesting how such work unwittingly disfigures the precise contours of the places and socio‐spatial formations on which geographers work, drawing them into implicit and reductive forms of comparison. Drawing on research and sources from South Asia, the paper moves instead toward more uncertain engagements with, and dispositions to, the production of geographical knowledge; ones attuned to the poetics of planetary difference. The paper speculates on five intellectual and methodological resources, or tactics, aimed toward producing geographical scholarship attuned to the tableaux of heterogeneous and incomparable singularities at large across the world: theory and reading; friction and fragments; translation/untranslatability; abiding by; and poetics.  相似文献   

The construction of a third-order secular analytical J-S-U-N theory by the Hori-Lie technique     

Abdel Aziz Bakry  Osman M. Kamel  Salwa M. Waziry 《Earth, Moon, and Planets》1993,63(1):29-66

We expand both parts, the principal and indirect, of the Hamiltonian function up to the third order in the masses for the four major planets Jupiter-Saturn-Uranus-Neptune. Accordingly we write down the secular terms ofF ₁,F ₂,F ₃ and the critical terms ofF ₁,F ₂ in terms of the canonical variables of H. Poincaré neglecting powers higher than the second inH, K, P, Q.  相似文献   

Kernel Principal Component Analysis for Efficient,Differentiable Parameterization of Multipoint Geostatistics   总被引：6，自引：5，他引：1  

Pallav Sarma  Louis J. Durlofsky  Khalid Aziz 《Mathematical Geosciences》2008,40(1):3-32

This paper describes a novel approach for creating an efficient, general, and differentiable parameterization of large-scale non-Gaussian, non-stationary random fields (represented by multipoint geostatistics) that is capable of reproducing complex geological structures such as channels. Such parameterizations are appropriate for use with gradient-based algorithms applied to, for example, history-matching or uncertainty propagation. It is known that the standard Karhunen–Loeve (K–L) expansion, also called linear principal component analysis or PCA, can be used as a differentiable parameterization of input random fields defining the geological model. The standard K–L model is, however, limited in two respects. It requires an eigen-decomposition of the covariance matrix of the random field, which is prohibitively expensive for large models. In addition, it preserves only the two-point statistics of a random field, which is insufficient for reproducing complex structures. In this work, kernel PCA is applied to address the limitations associated with the standard K–L expansion. Although widely used in machine learning applications, it does not appear to have found any application for geological model parameterization. With kernel PCA, an eigen-decomposition of a small matrix called the kernel matrix is performed instead of the full covariance matrix. The method is much more efficient than the standard K–L procedure. Through use of higher order polynomial kernels, which implicitly define a high-dimensionality feature space, kernel PCA further enables the preservation of high-order statistics of the random field, instead of just two-point statistics as in the K–L method. The kernel PCA eigen-decomposition proceeds using a set of realizations created by geostatistical simulation (honoring two-point or multipoint statistics) rather than the analytical covariance function. We demonstrate that kernel PCA is capable of generating differentiable parameterizations that reproduce the essential features of complex geological structures represented by multipoint geostatistics. The kernel PCA representation is then applied to history match a water flooding problem. This example demonstrates that kernel PCA can be used with gradient-based history matching to provide models that match production history while maintaining multipoint geostatistics consistent with the underlying training image.  相似文献   

Rock mass rating and Kinematic analysis for slope stability investigation of Utari dam,Lalitpur district,Uttar Pradesh     

M. E. A. Mondal  Tariq Siddique  Mohammad Alam  M. Masroor Alam 《Journal of the Geological Society of India》2016,87(4):463-468

Rock mass characterization of Utari dam in Lalitpur district of Uttar Pradesh was done to identify different stability classes of rock mass. For better stability of Utari dam, foundation conditions were carefully studied by detailed field investigations of the site supplemented by laboratory tests. During feasibility and preliminary stages, rock mass characterization of slopes was conducted to identify the vulnerable zones of failure. Rock mass characterization was done by compilation of information obtained from intact rock as well as from rock mass to determine its grade and long term slope stability of the site. On the basis of Rock Mass Rating (RMR) and Geological Strength Index (GSI) slope stability is identified which lies under good quality rock mass. Kinematic analysis was conducted to find out the probability for different types of structurally controlled slope failure. Microscopic analyses were conducted to identify the degree of chemical alteration of feldspar. Clay formation by sericitization along joint planes is harmful for the stability of dam structure. Remedial measures must be taken to reduce the extent of chemical alteration. Granitoids at dam site forms a compact and stable foundation consisting of four sets of joints in which two sets were prominent which are dipping on the upstream side of the dam which reveals good condition on the dam site as leakage from reservoir will be minimum and least up-thrust on the dam structure.  相似文献   

SMR geomechanics and kinematic analysis near Rasulpur,Fatehpur Sikri,Uttar Pradesh   总被引：1，自引：0，他引：1  

M. E. A. Mondal  Tariq Siddique  Bulbul Mondal  M. Masroor Alam 《Journal of the Geological Society of India》2016,87(5):623-627

Slope stability of mine slopes is often associated with safety and economics during excavation. Sandstone is excavated from Rasulpur area of Fatehpur Sikri in Uttar Pradesh for the purpose of crushed, decorative and dimension stones. In the present paper an attempt has been made to characterize the rock slope faces into different stability classes. Characterization is based on geological and geotechnical parameters recorded on the outcrop during field investigation and supplemented by geomechanical properties by the laboratory test for strength of the rock intact. SMR Geomechanics classification is used to identify the stability class and remedial measures are also suggested to reduce any possible hazard. Kinematic analysis of slope was also investigated to determine the probability of any possible structurally controlled failure. On the basis of SMR Geomechanics calculations slope under investigation lies under good stability class i.e. 2a and 2b. Installation of nets during excavation can be done and for better safety spot and systematic rock bolting can be done. Kinematic study reveals that toppling failures may occur, special care must be given to the joint set which can trigger toppling failure.  相似文献   

Integration of ASTER and airborne geophysical data for mineral exploration and environmental mapping: a case study,Gabal Dara,North Eastern Desert,Egypt     

Kh. Gemail  N. M. Abd-El Rahman  B. M. Ghiath  R. N. Aziz 《Environmental Earth Sciences》2016,75(7):592

  相似文献