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1.
Geotechnical and Geological Engineering - Understanding the local stratigraphy and geometry of sediment units is necessary for successful 3D modelling and the prediction of ground behaviour and...  相似文献   
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Long‐term fluctuations in lake‐water optical properties were examined using a Holocene sediment sequence and multi‐proxy palaeolimnological approach in Lake Einstaken, Nordaustlandet, Svalbard. UV‐absorbance of sedimentary cladoceran remains provided information on underwater UV exposure and changes in lake‐catchment coupling processes were inferred from sediment geochemistry. In addition, aquatic community succession was used as an indicator for lake‐water bio‐optical properties and a Holocene record of sun activity (sunspots) was utilized to evaluate long‐term solar forcing. The results indicated that the UV‐absorbance of cladoceran remains was highest (i.e. maximum UV‐induced pigmentation) for a short period during the early Holocene and for several millennia during the mid‐Holocene. Sun activity was high during these time intervals, probably impacting the UV intensities, but it is probable that the amount of UV‐attenuating compounds (e.g. dissolved organic carbon (DOC)) also significantly affected the underwater UV environment and were low during high UV exposure. Benthic autotrophic communities also responded to the millennial changes in lake‐water optical properties. UV‐resistant Nostoc cyanobacterial colonies were established during the mid‐Holocene, indicative of high underwater UV intensities, and Fontinalis mosses thrived during the early Holocene, indicating a highly transparent water column. The results further suggested that underwater UV exposure decreased during the late Holocene, which is probably attributable to increased DOC and decreased solar forcing. Owing to the location of Lake Einstaken and its catchment in the periglacial barren landscape of the polar desert, the fluctuations of bio‐optical lake‐water properties were apparently forced by postglacial environmental processes and Holocene climate development. These factors controlled sea shoreline proximity, water discharge, ice‐cover duration and littoral‐benthic primary production and further affected the underwater UV environment. Although the role of solar forcing cannot be underestimated, the current record emphasizes the role of climate‐mediated lake‐catchment interactions in impacting bio‐optical properties and UV exposure of high arctic aquatic systems.  相似文献   
3.
The purpose of this study was to examine structural alterations of finely ground phlogopite, a trioctahedral mica, when exposed to acid, iron- and sulfate-rich solutions typical of bioleaching systems. Phlogopite suspensions were supplemented with ferrous sulfate and incubated with iron- and sulfur-oxidizing bacteria (Acidithiobacillus ferrooxidans) at 22 °C. As bacteria oxidized ferrous iron, ferric iron thus formed partially precipitated as K-jarosite. K-jarosite precipitation was contingent on the preceding ferrous iron oxidation by bacteria and the release of interlayer-K from phlogopite. This chemically and microbially induced weathering involved alteration of phlogopite to a mixed layer structure that included expansible vermiculite. The extent of phlogopite weathering and structure expansion varied with duration of the contact, concentration of ferrous iron and phlogopite, and the presence of monovalent cations (NH4+, K+, or Na+) in the culture solution. NH4+ and K+ ions (100 mM) added to culture suspensions precipitated as jarosite and thereby effectively prevented the loss of interlayer-K and structural alteration of phlogopite. Additional Na+ (100 mM) was insufficient to precipitate ferric iron as natrojarosite and therefore the precipitation was coupled with interlayer-K released from phlogopite. When ferrous iron was replaced with elemental sulfur as the substrate for A. ferrooxidans, the weathering of phlogopite was based on chemical dissolution without structural interstratification. The results demonstrate that iron oxidation and the concentration and composition of monovalent ions can have an effect on mineral weathering in leaching systems that involve contact of phlogopite and other mica minerals with acid leach solutions.  相似文献   
4.
Defining reference conditions for lakes situated in areas of human settlement and agriculture is rarely straightforward, and is especially difficult within easily eroding and nutrient rich watersheds. We used diatoms, cyanobaterial akinetes, remains of green algae and chironomid head capsules from sediment samples of Lake Kirmanjärvi, Finland, to assess its deviation from the initial ecological status. These site-specific records of change were compared to current type-specific ecological status assessment. All paleolimnological data indicated deviation from natural conditions and mirrored the current, monitoring-based assessment of “moderate” ecological lake status. However, the sediment data showed that the lake should be re-typified as a naturally eutrophic lake. Sediment records as well as current monitoring data indicated temporary improvement in water quality in response to extensive fish manipulation. Our results suggest that paleolimnological records can be used to derive site-specific reference conditions and that extensive restoration efforts can result in gradual, observable improvements of water quality and ecological status.  相似文献   
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We present four case studies of exceptional wave events of meteorological origin, observed on the Finnish coast in the summers of 2010 and 2011. Eyewitnesses report unusually rapid and strong sea-level variations (up to 1 m in 5–15 min) and strong oscillating currents during these events. High-resolution sea-level measurements confirm the eyewitness observations, but the oscillations recorded by tide gauges mostly have a considerably smaller amplitude. The oscillations coincide with sudden jumps in surface air pressure at coastal observation stations, related to the passage of squall lines or gust fronts. These fronts propagate above the sea at a resonant speed, allowing efficient energy transfer between the atmospheric disturbance and the sea wave that it generates. Thus, we interpret the observed sea-level oscillations as small meteotsunamis, long tsunami-like waves generated by meteorological processes and resonance effects.  相似文献   
7.
A preliminary optical classification of lakes in Estonia and south Finland which can also be used for small bays of the Baltic Sea is elaborated. The classification is based on the optical properties of water (diffuse attenuation coefficient, diffuse reflectance) and parameters that are routinely monitored in water bodies (Secchi depth, concentration of chlorophyll-a, total suspended matter and yellow substance). The data complex used for our classification covers different types of water ecosystems (ranging from oligotrophic to hypertrophic) and the variability of water constituent concentrations in the ice-free period in Estonia and south Finland. Using cluster analysis, we found 5 optical classes of waters: clear (C), moderate (M), turbid (T), very turbid (V) and brown (B). There is satisfactory correspondence between class of water, shape of diffuse attenuation coefficient and diffuse reflectance spectra and trophic state of the lakes.  相似文献   
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9.
Time series of freshwater runoff, seawater salinity, temperature and oxygen were used in transfer functions (TF) to model changes of mesozooplankton taxa in the Baltic Sea from the 1960’s to the 1990’s. The models were then compared with long term zooplankton monitoring data from the same period. The TF models for all taxa over the whole Baltic proper and at different depth layers showed statistically significant estimates in t-tests. TF models were further compared using parsimony as a criterion. We present models showing 1) r2 > 0.4, 2) the smallest residual standard error with the combination of exploratory variables, 3) the lowest number of parameters and 4) the highest proportional decrease in error term when the TF model residual standard error was compared with those of the univariate ARIMA model of the same response variable. Most often (7 taxa out of a total of 8), zooplankton taxa were dependent on freshwater runoff and/or seawater salinity. Cladocerans and estuarine copepods were more conveniently modelled through the inclusion of seawater temperature and oxygen data as independent variables. Our modelling, however, explains neither the overall increase in zooplankton abundance nor a simultaneous decrease found in the neritic copepod, Temora longicornis. Therefore, biotic controlling agents (e.g. nutrients, primary production and planktivore diets) are suggested as independent variables for further TF modelling. TF modelling enabled us to put the controlling factors in a time frame. It was then possible, despite the inherent multiple correlation among parameters studied to deduce a chain-of-events from the environmental controls and biotic feedback mechanisms to changes in zooplankton species. We suggest that the documented long-term changes in zooplankton could have been driven by climatic regulation only. The control by climate could be mediated to zooplankton through marine chemical and physical factors, as well as biotic factors if all of these were responding to the same external control, such as changes in the freshwater runoff. Increased runoff would explain both the increasing eutrophication, causing the overall increase of zooplankton, and the changes in selective predation, contributing to decline of Temora.  相似文献   
10.
Clinopyroxenes from pyroxenite, ijolite and nepheline syenite from the main intrusion of the Alnö complex define two sub-parallel compositional trends with respect to Na, Ca and FeTOT plotted against alkali-pyroxene fractionation index (Na–Mg). Both trends define a smooth fractionation of increasing Na and FeTOT and decreasing Ca with increasing Na–Mg, but one set of samples contain clinopyroxenes that constantly plot at higher Na and lower FeTOT and Ca (at similar Na–Mg) than the rest of the samples. Clinopyroxenes with higher Ca and FeTOT and lower Na (trend 1) co-exist with substantial amounts of Ti-andradite (up to 70 vol.%), while the sample set defining the more Na-rich trend (trend 2) lack co-existing Ti-andradite. Clinopyroxenes from both trends show fractionated REE patterns with a distinct difference in HREE content, reflecting the content of co-existing Ti-andradite. The rocks of the first Ti-andradite-bearing trend crystallized slightly prior to the rocks of the second trend, probably from a primitive, Ca- and Ti-rich nephelinitic magma. Crystallisation of pyroxenite and melteigite occurred under low aSiO2 and high aCaO and aTiO2 as evidenced by the presence of perovskite and sometimes substantial amounts of magnetite. Subsequent increase in aSiO2 is evidenced in the overgrowth of perovskite by titanite, which in turn is overgrown by Ti-andradite. Nepheline syenitic residuals crystallized under higher aSiO2 and aNa2O and lower aCaO and aTiO2, which reduced Ti-andradite into an accessory phase and produced more Si- and Na-rich clinopyroxenes. Some of these residuals probably also mixed with new primitive magma producing a hybrid magma that crystallised the more Na-rich and Ca- and FeTOT-poor clinopyroxenes of trend 2. The complete lack of Ti-andradite in these rocks indicates different crystallisation conditions and also a different magma composition.  相似文献   
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