Amino acid analyses of Antarctic CM2 meteorites using liquid chromatography‐time of flight‐mass spectrometry     

Daniel P. Glavin  Jason P. Dworkin  Andrew Aubrey  Oliver Botta  James H. Doty  Zita Martins  Jeffrey L. Bada 《Meteoritics & planetary science》2006,41(6):889-902

Abstract— Amino acid analyses of the Antarctic CM2 chondrites Allan Hills (ALH) 83100 and Lewis Cliff (LEW) 90500 using liquid chromatography‐time of flight‐mass spectrometry (LC‐ToF‐MS) coupled with UV fluorescence detection revealed that these carbonaceous meteorites contain a suite of indigenous amino acids not present in Antarctic ice. Several amino acids were detected in ALH 83100, including glycine, alanine, β‐alanine, γ‐amino‐n‐butyric acid (γ‐ABA), and α‐aminoisobutyric acid (AIB) with concentrations ranging from 250 to 340 parts per billion (ppb). In contrast to ALH 83100, the CM2 meteorites LEW 90500 and Murchison had a much higher total abundance of these amino acids (440–3200 ppb). In addition, ALH 83100 was found to have lower abundances of the α‐dialkyl amino acids AIB and isovaline than LEW 90500 and Murchison. There are three possible explanations for the depleted amino acid content in ALH 83100: 1) amino acid leaching from ALH 83100 during exposure to Antarctic ice meltwater, 2) a higher degree of aqueous alteration on the ALH 83100 parent body, or 3) ALH 83100 originated on a chemically distinct parent body from the other two CM2 meteorites. The high relative abundance of ?‐amino‐n‐caproic acid (EACA) in the ALH 83100 meteorite as well as the Antarctic ice indicates that Nylon‐6 contamination from the Antarctic sample storage bags may have occurred during collection.  相似文献   

High-resolution observations of a complete sample of 27 FR II radio galaxies and quasars with 0.3 < z < 0.6     

G. M. Gilbert  J. M. Riley  M. J. Hardcastle  J. H. Croston  G. G. Pooley  P. Alexander 《Monthly notices of the Royal Astronomical Society》2004,351(3):845-890

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Erratum: Towards cosmological concordance on galactic scales     

Frank C. van den Bosch  H. J. Mo  Xiaohu Yang 《Monthly notices of the Royal Astronomical Society》2004,348(2):736-736

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The D-CIXS X-ray mapping spectrometer on SMART-1     

M Grande  R BrowningN Waltham  D ParkerS.K Dunkin  B KentB Kellett  C.H PerryB Swinyard  A PerryJ Feraday  C HoweG McBride  K PhillipsJ Huovelin  P MuhliP.J Hakala  O VilhuJ Laukkanen  N ThomasD Hughes  H AlleyneM Grady  R LundinS Barabash  D BakerP.E Clark  C.D MurrayJ Guest  I CasanovaL.C d'Uston  S MauriceB Foing  D.J Heather  V FernandesK Muinonen  S.S RussellA Christou  C OwenP Charles  H KoskinenM Kato  K SipilaS Nenonen  M HolmstromN Bhandari  R ElphicD Lawrence 《Planetary and Space Science》2003,51(6):427-433

The D-CIXS Compact X-ray Spectrometer will provide high quality spectroscopic mapping of the Moon, the primary science target of the ESA SMART-1 mission. D-CIXS consists of a high throughput spectrometer, which will perform spatially localised X-ray fluorescence spectroscopy. It will also carry a solar monitor, to provide the direct calibration needed to produce a global map of absolute lunar elemental abundances, the first time this has been done. Thus it will achieve ground breaking science within a resource envelope far smaller than previously thought possible for this type of instrument, by exploiting two new technologies, swept charge devices and micro-structure collimators. The new technology does not require cold running, with its associated overheads to the spacecraft. At the same time it will demonstrate a radically novel approach to building a type of instrument essential for the BepiColombo mission and potential future planetary science targets.  相似文献   

Mezen Bay—a key area for understanding Weichselian glaciations in northern Russia     

Kurt H. Kjr  Igor N. Demidov  Eiliv Larsen  Andrew Murray  Jan K. Nielsen 《第四纪科学杂志》2003,18(1):73-93

Sediment successions in coastal cliffs around Mezen Bay, southeastern White Sea, record an unusually detailed history of former glaciations, interstadial marine and fluvial events from the Weichselian. A regional glaciation model for the Weichselian is based on new data from the Mezen Bay area and previously published data from adjacent areas. Following the Mikulinian (Eemian) interglacial a shelf‐centred glaciation in the Kara Sea is reflected in proglacial conditions at 100–90 ka. A local ice‐cap over the Timan ridge existed between 75 and 65 ka. Renewed glaciation in the Kara Sea spread southwestwards around 60 ka only, interrupted by a marine inundation, before it advanced to its maximum position at about 55–50 ka. After a prolonged ice‐free period, the Scandinavian ice‐sheet invaded the area from the west and terminated east of Mezen Bay about 17 ka. The previously published evidence of a large ice‐dammed lake in the central Arkhangelsk region, Lake Komi, finds no support in this study. Copyright © 2003 John Wiley & Sons, Ltd.  相似文献   

A multi‐level parallelized substructuring‐frontal solution for coupled thermo/hydro/mechanical problems in unsaturated soil     

H.R. Thomas  H.T. Yang  Y. He  P.J. Cleall 《国际地质力学数值与分析法杂志》2003,27(11):951-965

This paper proposes a multi‐level parallelized substructuring–frontal combined algorithm for the analysis of the problem of thermo/hydraulic/mechanical behaviour of unsaturated soil. Temperature, displacement, pore water pressure and pore air pressure are treated as the primary variables in a non‐linear analysis. Details are given firstly of the substructuring–frontal combined approach. The incorporation of the algorithm in a multi‐level parallel strategy is then discussed. The parallel processing can thus be carried out at different substructural levels. The method thus developed impacts, in a positive way, on both computer storage requirement and execution time. Copyright © 2003 John Wiley & Sons, Ltd.  相似文献   

An empirical model of the daily evolution of the coronal index     

Mavromichalaki  H.  Plainaki  C.  Zouganelis  I.  Petropoulos  B. 《Solar physics》2003,218(1-2):63-78

Global changes of the solar activity can be expressed by the coronal index that is based upon the total irradiance of the coronal 530.3 nm green line from observations at five stations. Daily mean values of the coronal index of solar activity and other well-correlated solar indices are analyzed for the period 1966–1998 covering over three solar cycles. The significant correlation of this index with the sunspot number and the solar flare index have led to an analytical expression which can reproduce the coronal index of solar activity as a function of these parameters. This expression explains well the existence of the two maxima during the solar cycles taking into account the evolution of the magnetic field that can be expressed by some sinusoidal terms during solar maxima and minima. The accuracy between observed and calculated values of the coronal index on a daily basis reaches the value of 71%. It is concluded that the representative character of the coronal index is preserved even when using daily data and can therefore allow us to study long-term, intermediate and short-term variations for the Sun as a star, in association with different periodical solar–terrestrial phenomena useful for space weather studies.  相似文献   

2D/3D Dust Continuum Radiative Transfer Codes to Analyze and Predict VLTI Observations     

I. Pascucci  Th. Henning  J. Steinacker  S. Wolf 《Astrophysics and Space Science》2003,286(1-2):113-118

Radiative Transfer (RT) codes with image capability are a fundamental tool for preparing interferometric observations and for interpreting visibility data. In view of the upcoming VLTI facilities, we present the first comparison of images/visibilities coming from two 3D codes that use completely different techniques to solve the problem of self-consistent continuum RT. In addition, we focus on the astrophysical case of a disk distorted by tidal interaction with by-passing stars or internal planets and investigate for which parameters the distortion can be best detected in the mid-infrared using the mid-infrared interferometric device MIDI. This revised version was published online in July 2006 with corrections to the Cover Date.  相似文献   

The discovery of two distant, massive clusters of galaxies in the ROSAT All-Sky Survey     

A. C. Edge  H. Ebeling  †  M. Bremer  H. Röttgering  M. P. van Haarlem  R. Rengelink  N. J. D. Courtney 《Monthly notices of the Royal Astronomical Society》2003,339(4):913-924

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Laboratory studies of the interaction of carbon monoxide with water ice     

M.P. Collings  J.W. Dever  H.J. Fraser  M.R.S. McCoustra 《Astrophysics and Space Science》2003,285(3-4):633-659

The interaction of carbon monoxide (CO) with vapour-deposited water(H₂O) ices has been studied using temperature programmed desorption (TPD) and Fourier transform reflection-absorption infrared spectroscopy (FT-RAIRS) over a range of astrophysically relevant temperatures. Such measurements have shown that CO desorption from amorphous H₂Oices is a much more complex process than current astrochemical models suggest. Re-visiting previously reported laboratory experiments (Collings et al., 2003), a rate model has been constructed to explain, in a phenomenological manner, the desorption of CO over astronomically relevant time scales. The model presented here can be widely applied to a range of astronomical environments where depletion of CO from the gas phase is relevant. The model accounts for the two competing processes of CO desorption and migration, and also enables the entrapment of some of the CO in the ice matrix and its subsequent release as the water ice crystallises and then desorbs. The astronomical implications of this model are discussed. This revised version was published online in July 2006 with corrections to the Cover Date.  相似文献