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61.
Rainwater, groundwater and soil-water samples were analysed to assess groundwater geochemistry and the origin of salinity in the Ochi-Narkwa basin of the Central Region of Ghana. The samples were measured for major ions and stable isotopes (δ18O, δ2H and δ13C). The Cl? content in rainwater decreased with distance from the coast. The major hydrochemical facies were Na-Cl for the shallow groundwaters and Ca-Mg-HCO3, Na-Cl and Ca-Mg-Cl-SO4 for the deep groundwaters. Groundwater salinization is caused largely by halite dissolution and to a minor extent by silicate weathering and seawater intrusion. Stable isotope composition of the groundwaters followed a slope of 3.44, suggesting a mixing line. Chloride profiles in the soil zone revealed the existence of salt crusts, which support halite dissolution in the study area. A conceptual flow model developed to explain the mechanism of salinization showed principal groundwater flow in the NW–SE direction.
EDITOR D. Koutsoyiannis

ASSOCIATE EDITOR K. Heal  相似文献   
62.
The Håkon Mosby mud volcano is a 1.5-km-diameter geological structure located on the Southwest Barents Sea slope at a water depth of 1,270 m. High-definition seabed mapping of the mud volcano has been carried out in 2003 and 2006. A comparative analysis of the bathymetry and backscatter maps produced from the two surveys shows subtle morphological changes over the entire crater of the mud volcano, interpreted to be the consequence of mud eruption events. Mud temperature measurements point to a persistently warm mud at shallow depth in the crater. This is explained by upward fluid advection, rather than conductive cooling of mud flows. The small-scale spatial variability in the temperature distribution may be related to mud outflows or changes in the fluid flow regime. Furthermore, the locations of free gas venting observed in 2006 were found to differ from those of 2003. Our observations of overall similar topographic profiles across the mud volcano in 2003 and 2006 suggest that eruption events would have been modest. Nevertheless, the data bring evidence of significant change in activity even over short time intervals of only 3 years. This may be a characteristic shared by other submarine mud volcanoes, notably those considered to be in a quiescent stage.  相似文献   
63.
64.
Saltwater intrusion in coastal aquifers depends on the distribution of hydraulic properties, on the climate, and on human interference such as land reclamation. In order to analyze the key processes that control saltwater intrusion, a hypothetical steady-state salt distribution in a representative cross-section perpendicular to the coastline was calculated using a two-dimensional density-dependent solute transport model. The effects of changes in groundwater recharge, lowering of drainage levels, and a rising sea level on the shape and position of the freshwater/saltwater interface were modeled in separate simulations. The results show that the exchange of groundwater and surface water in the marsh areas is one of the key processes influencing saltwater intrusion. A rising sea level causes rapid progression of saltwater intrusion, whereas the drainage network compensates changes in groundwater recharge. The time scale of changes resulting from altered boundary conditions is on the order of decades and centuries, suggesting that the present-day salt distribution does not reflect a steady-state of equilibrium.  相似文献   
65.
66.
The ongoing loss of Arctic sea-ice cover has implications for the wider climate system. The detection and importance of the atmospheric impacts of sea-ice loss depends, in part, on the relative magnitudes of the sea-ice forced change compared to natural atmospheric internal variability (AIV). This study analyses large ensembles of two independent atmospheric general circulation models in order to separate the forced response to historical Arctic sea-ice loss (1979–2009) from AIV, and to quantify signal-to-noise ratios. We also present results from a simulation with the sea-ice forcing roughly doubled in magnitude. In proximity to regions of sea-ice loss, we identify statistically significant near-surface atmospheric warming and precipitation increases, in autumn and winter in both models. In winter, both models exhibit a significant lowering of sea level pressure and geopotential height over the Arctic. All of these responses are broadly similar, but strengthened and/or more geographically extensive, when the sea-ice forcing is doubled in magnitude. Signal-to-noise ratios differ considerably between variables and locations. The temperature and precipitation responses are significantly easier to detect (higher signal-to-noise ratio) than the sea level pressure or geopotential height responses. Equally, the local response (i.e., in the vicinity of sea-ice loss) is easier to detect than the mid-latitude or upper-level responses. Based on our estimates of signal-to-noise, we conjecture that the local near-surface temperature and precipitation responses to past Arctic sea-ice loss exceed AIV and are detectable in observed records, but that the potential atmospheric circulation, upper-level and remote responses may be partially or wholly masked by AIV.  相似文献   
67.
Weathering fluxes of arsenic from a small catchment in Slovak Republic   总被引:1,自引:1,他引:0  
Inputs of As to a small catchment due to chemical weathering of bedrock, mechanical weathering of bedrock, and atmospheric precipitation were 71.53, 23.98 and 0.02 g ha−1 year−1, respectively. The output fluxes of As due to mechanical erosion of soil, biological uptake, stream discharge, and groundwater flow were 6.32, 4.77, 0.37 and 0.02 g ha−1 year−1, respectively. The results indicate that arsenic accumulates in soil and regolith with a very high rate. This is attributed to the selective weathering and erosion with respect to arsenic and fixation of arsenic in the secondary solids produced by weathering. The output fluxes of As in stream and groundwater in Vydrica catchment in Slovak Republic (0.39 g ha−1 year−1) based on muscovite–biotite granites and granodiorites were much lower compared to catchments in a gold district in the Czech Republic. These results may be ascribed to the low levels of arsenic pollution measured in Vydrica catchment. The arsenic fluxes were estimated by calculation of mechanical and chemical weathering rates of the bedrocks in Vydrica catchment from mass balance data on sodium and silica. The justification of the steady state of Na and Si is that neither of the elements is appreciably accumulated in plants and in exchangeable pool of ions in soil.  相似文献   
68.
Fluid inclusions act as sealed vessels containing information about the fluid environment in which the minerals precipitated, and until decrepitated, the chemical composition of the fluid inside the inclusion stays intact. In many cases fluid inclusions contain trapped hydrocarbons, which may provide useful information in paleontological, organic geochemical and astrobiological research since they act as containers of non-contaminated organic matter with a defined minimum age. Here we present a novel concept for extraction of fluid inclusions in preparation for application to extract single fluid inclusions. The method is based on the illumination of a sample with an ErYAG laser (). The wavelength of the laser is absorbed by water and organic material, and with the minerals encapsulating the inclusions transparent to the wavelength, the fluid will expand and the inclusion will decrepitate. The initial results of our study demonstrate that fluid inclusions can be extracted by the use of an ErYAG laser, and that organic biomarkers may survive the process, readily available for GC–MS analysis.  相似文献   
69.
This study explores the potential of integrating state-of-the-art physically based hydrogeological modeling into slope stability simulations to identify the hydrogeological triggers of landslides. Hydrogeological models considering detailed morphological, lithological, and climatic factors were elaborated. Groundwater modeling reveals locations with elevated pore water pressures in the subsurface and allows the quantification of temporal dynamics of the pore water pressures. Results of the hydrogeological modeling were subsequently applied as boundary conditions for the slope stability simulations. The numerical models illustrate that the hydrogeological impacts affecting hillslope stability are strongly controlled by local groundwater flow conditions and their conceptualization approach in the hydrogeological model. Groundwater flow itself is heavily influenced by the inherent geological conditions and the dynamics of climatic forcing. Therefore, both detailed investigation of the landslide’s hydrogeology and appropriate conceptualization and scaling of hydrogeological settings in a numerical model are essential to avoid an underestimation of the landslide risk. The study demonstrates the large potential in combining state-of-the-art computational hydrology with slope stability modeling in real-world cases.  相似文献   
70.
The landscapes of the world are constantly changing under the influence of human activities leading to the growth of artificial surfaces. The covering of soil by artificial surfaces is referred to as soil sealing. Aerial and satellite images or data derived from them (for instance CORINE land cover — CLC data used here) provide important information that makes it possible to assess the occurrence, area and rate of soil sealing. As the term sealed soil cannot be wholly identified with the content of the appropriate CLC classes, the term land cover flow urbanization (LCFU) will be used here. The essence of this study is the demonstration and documentation of the trends of the LCFU in Europe for the periods 1990–2000 and 2000–2006 on a single map. This may contribute to a better spatial awareness of the ongoing transformation of landscape under the effects of human activities in an pan-European context. Changes in the LCFU can be seen on a map, compiled from 3 × 3 km squares at an all-European scale, using colours and their hues, to fulfil the role both of identification and classification. The colour method employed makes it possible to perceive three groups of LCFU changes on two time horizons, that is, whether the rate of LCFU in 2000–2006 increased or remained the same (hues of red); or dropped compared to the 1990–2000 period (hues of light to dark blue). The third group represents the LCFU with rates higher or lower than the average (countries with changes recorded in only one time horizon are presented in dark and light magenta colours).  相似文献   
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