Crystal structure, Raman and FTIR spectroscopy, and equations of state of OH-bearing MgSiO3 akimotoite     

Yu Ye  Joseph R. Smyth  Steven D. Jacobsen  Wendy R. Panero  David A. Brown  Tomoo Katsura  Yun-Yuan Chang  Joshua P. Townsend  Przemyslaw Dera  Sergey Tkachev  Cayman Unterborn  Zhenxian Liu  Céline Goujon 《Contributions to Mineralogy and Petrology》2013,166(5):1375-1388

MgSiO₃ akimotoite is stable relative to majorite-garnet under low-temperature geotherms within steeply or rapidly subducting slabs. Two compositions of Mg–akimotoite were synthesized under similar conditions: Z674 (containing about 550 ppm wt H₂O) was synthesized at 22 GPa and 1,500 °C and SH1101 (nominally anhydrous) was synthesized at 22 GPa and 1,250 °C. Crystal structures of both samples differ significantly from previous studies to give slightly smaller Si sites and larger Mg sites. The bulk thermal expansion coefficients of Z674 are (153–839 K) of a ₁ = 20(3) × 10^?9 K^?2 and a ₀ = 17(2) × 10^?6 K^?1, with an average of α ₀ = 27.1(6) × 10^?6 K^?1. Compressibility at ambient temperature of Z674 was measured up to 34.6 GPa at Sector 13 (GSECARS) at Advanced Photon Source Argonne National Laboratory. The second-order Birch–Murnaghan equation of state (BM2 EoS) fitting yields: V ₀ = 263.7(2) Å³, K _T0 = 217(3) GPa (K′ fixed at 4). The anisotropies of axial thermal expansivities and compressibilities are similar: α _a  = 8.2(3) and α _c  = 10.68(9) (10^?6 K^?1); β _a  = 11.4(3) and β _c  = 15.9(3) (10^?4 GPa). Hydration increases both the bulk thermal expansivity and compressibility, but decreases the anisotropy of structural expansion and compression. Complementary Raman and Fourier transform infrared (FTIR) spectroscopy shows multiple structural hydration sites. Low-temperature and high-pressure FTIR spectroscopy (15–300 K and 0–28 GPa) confirms that the multiple sites are structurally unique, with zero-pressure intrinsic anharmonic mode parameters between ?1.02 × 10^?5 and +1.7 × 10^?5 K^?1, indicating both weak hydrogen bonds (O–H···O) and strong OH bonding due to long O···O distances.  相似文献   

Formation of weathering-derived magnesite deposits in the New England Orogen, New South Wales, Australia: Implications from mineralogy, geochemistry and genesis of the Attunga magnesite deposit     

Hans C. Oskierski  Judy G. Bailey  Eric M. Kennedy  Geraldine Jacobsen  Paul M. Ashley  Bogdan Z. Dlugogorski 《Mineralium Deposita》2013,48(4):525-541

Nodular, cryptocrystalline, weathering-derived magnesite deposits in the New England Orogen, Australia, provide a significant source of high-purity magnesite. Common textural features and related isotopic fingerprints indicate a close genetic relationship between weathering-derived magnesite deposits hosted by ultramafic rocks at Attunga and by sediments at Kunwarara while silica-carbonate rock alteration and rare hydrothermal magnesite vein deposits reflect contrasting conditions of formation. Localised weathering of carbonates in a soil environment shifts stable isotopic composition towards low δ ¹³C and high δ ¹⁸O typical for weathering-derived magnesites while intrusion-related fluids do not significantly change the isotopic composition of affected carbonates. At Attunga, magnesite consists of irregular, nodular veins and masses filling faults and cracks in the weathered serpentinite host rock as well as soft powdery magnesite in pervasive serpentinite alteration zones. The high-grade magnesite at Attunga can be contaminated by amorphous silica and serpentine relicts but does not contain dolomite or ferroan magnesite as observed for its hydrothermal equivalent, the Piedmont magnesite deposit, or other widespread deposits of silica-carbonate rock in the Great Serpentinite Belt. Heavy δ ¹⁸O values are compatible with a supergene formation from meteoric waters while low δ ¹³C suggests C3-photosynthetic plants as the predominant source of carbon for the Attunga magnesites. We infer that weathering-derived, nodular magnesite deposits hosted in ultramafic rocks like the Attunga magnesite deposit have formed in a two-step process involving the hypogene formation of a pre-cursor magnesite deposit and complete supergene overprinting by meteoric waters that acquired carbon from percolation through soil.  相似文献   

The Importance of Microbial Iron Sulfide Oxidation for Nitrate Depletion in Anoxic Danish Sediments     

Sarka Vaclavkova  Christian Juncher Jørgensen  Ole Stig Jacobsen  Jens Aamand  Bo Elberling 《Aquatic Geochemistry》2014,20(4):419-435

Nitrate (NO₃ ^?) reduction processes are important for depleting the NO₃ ^? load from agricultural source areas before the discharge water reaches surface waters or groundwater aquifers. In this study, we experimentally demonstrate the co-occurrence of microbial iron sulfide oxidation by NO₃ ^? (MISON) and other NO₃ ^?-depleting processes in a range of contrasting sediment types: sandy groundwater aquifer, non-managed minerotrophic freshwater peat and two brackish muddy sediments. Approximately 1/3 of the net NO₃ ^? reduction was caused by MISON in three of the four environments despite the presence of organic carbon in the sediment. An apparent salinity limitation to MISON was observed in the most brackish environment. Addition of high surface area synthetically precipitated iron sulfide (FeS _x ) to the aquifer sediment with the lowest natural FeS _x reactivity increased both the relative fraction of NO₃ ^? reduction linked to MISON from approximately 30–100 % and the absolute rates by a factor of 17, showing that the potential for MISON-related NO₃ ^? reduction is environmentally significant and rate limited by the availability of reactive FeS _x .  相似文献   

Hydraulic fracturing in unconventional gas reservoirs: risks in the geological system, part 2   总被引：2，自引：2，他引：0  

Alexander Kissinger  Rainer Helmig  Anozie Ebigbo  Holger Class  Torsten Lange  Martin Sauter  Michael Heitfeld  Johannes Klünker  Wiebke Jahnke 《Environmental Earth Sciences》2013,70(8):3855-3873

Hydraulic fracturing is a method used for the production of unconventional gas resources. Huge amounts of so-called fracturing fluid (10,000–20,000 m³) are injected into a gas reservoir to create fractures in solid rock formations, upon which mobilised methane fills the pore space and the fracturing fluid is withdrawn. Hydraulic fracturing may pose a threat to groundwater resources if fracturing fluid or brine can migrate through fault zones into shallow aquifers. Diffuse methane emissions from the gas reservoir may not only contaminate shallow groundwater aquifers, but also escape into the atmosphere where methane acts as a greenhouse gas. The working group “Risks in the Geological System” as part of ExxonMobil’s hydrofracking dialogue and information dissemination processes was tasked with the assessment of possible hazards posed by migrating fluids as a result of hydraulic fracturing activities. In this work, several flow paths for fracturing fluid, brine and methane are identified and scenarios are set up to qualitatively estimate under what circumstances these fluids would leak into shallower layers. The parametrisation for potential hydraulic fracturing sites in North Rhine-Westphalia and Lower Saxony (both in Germany) is derived from literature using upper and lower bounds of hydraulic parameters. The results show that a significant fluid migration is only possible if a combination of several conservative assumptions is met by a scenario.  相似文献   

Notes on the distribution of organic nitrogen in the seabottom of the Danish Waddensea     

Vøgg H. Jacobsen 《Geografisk tidskrift / udgivet af Bestyrelsen for Det Kongelige danske geografiske selskab》2013,113(1):46-53

Determination of organic nitrogen in the seabottom of a tidal area along the coast of western Denmark has been performed at bi-weekly intervals throughout one year. Temperatures, salinities and some environmental factors affecting intertidal communities have been noted; grain size determinations have been performed on a selected number of samples.  相似文献   

Inversion of Scholte wave dispersion and waveform modeling for shallow structure of the Ninetyeast Ridge     

Xuan Nhi Nguyen  Torsten Dahm  Ingo Grevemeyer 《Journal of Seismology》2009,13(4):543-559

The construction of S-wave velocity models of marine sediments down to hundreds of meters below the seafloor is important in a number of disciplines. One of the most significant trends in marine geophysics is to use interface waves to estimate shallow shear velocities which play an important role in determining the shallow crustal structure. In marine settings, the waves trapped near the fluid–solid interface are called Scholte waves, and this is the subject of the study. In 1998, there were experiments on the Ninetyeast Ridge (Central Indian Ocean) to study the shallow seismic structure at the drilled site. The data were acquired by both ocean bottom seismometer and ocean bottom hydrophone. A new type of seafloor implosion sources has been used in this experiment, which successfully excited fast and high frequency (>500 Hz) body waves and slow, intermediate frequency (<20 Hz) Scholte waves. The fundamental and first higher mode Scholte waves have both been excited by the implosion source. Here, the Scholte waves are investigated with a full waveform modeling and a group velocity inversion approach. Shear wave velocities for the uppermost layers of the region are inferred and results from the different methods are compared. We find that the full waveform modeling is important to understand the intrinsic attenuation of the Scholte waves between 1 and 20 Hz. The modeling shows that the S-wave velocity varies from 195 to 350 m/s in the first 16 m of the uppermost layer. Depths levels of high S-wave impedance contrasts compare well to the layer depth derived from a P-wave analysis as well as from drilling data. As expected, the P- to S-wave velocity ratio is very high in the uppermost 16 m of the seafloor and the Poisson ratio is nearly 0.5. Depth levels of high S-wave impedance contrasts are comparable to the layer depth derived from drilling data.  相似文献   

Petrologic study of SJ101, a new forsterite-bearing CAI from the Allende CV3 chondrite     

Michail I. Petaev  Stein B. Jacobsen 《Geochimica et cosmochimica acta》2009,73(17):5100-7046

The forsterite-bearing Type B (FoB) CAI SJ101 consists of three major structural units: (1) light patches of sector-zoned, poikilitic Al-rich clinopyroxene (Cpx) with numerous inclusions of small spinel grains and aggregates and subordinate amounts of Mg-rich melilite (Mel) and anorthite (An) (Sp-Cpx lithology), (2) dark sinuous bands of Al-rich clinopyroxene with large (up to ∼300 × 60 μm) poikilitically enclosed euhedral forsterite (Fo) crystals (Fo-Cpx lithology), and (3) the external Cpx-Sp-An rim overlying the entire inclusion. The two major lithologies are always separated by a transition zone of clinopyroxene poikilitically enclosing both forsterite and spinel. The patches of the Sp-Cpx lithology exhibit significant textural and mineralogical variability that is size-dependent. Small patches typically consist of Cpx and spinel with minor remnants of melilite and/or its alteration products. Large patches contain Mel-An-rich cores with either equigranular-ophitic-subophitic or ‘lacy’ textures reminiscent of those in Types B or C CAIs, respectively. All silicates poikilitically enclose numerous spinel grains of identical habit. Both melilite and anorthite gradually disappear toward the boundary with the Fo-Cpx lithology. Neither the evaporation mantle of Al-rich melilite typical of other FoBs nor the Wark-Lovering rim is present. Secondary minerals include grossular, monticellite, magnetite, and a few grains of wollastonite, andradite, and nepheline.Being a rather typical FoB mineralogically and chemically, texturally SJ101 differs from other FoBs in displaying the nearly complete segregation of forsterite from spinel which occur only in the Fo-Cpx and Sp-Cpx lithologies, respectively. The complex, convoluted internal structure of SJ101 suggests that the coarse-grained Sp-An-Mel-Cpx cores and Fo-Cpx lithology represent the precursor materials of FoBs, proto-CAIs and Fo-rich accretionary rims. While the inferred chemistry and mineralogy of the Fo-rich rims are fairly typical, the high Åk content in SJ101 melilite (78.7-82.3 mol.%) implies that the SJ101 proto-CAIs represent a new type of CAIs that has not been sampled before. This type of CAIs might have formed by remelting of spinel-rich condensates.The Group II REE pattern, slightly negative δ²⁹Si and δ²⁵Mg values, and nearly solar ratios of the major elements in the bulk SJ101 suggest that its precursors, proto-CAIs and Fo-rich rims, could have formed by a non-equilibrium condensation in a closed system of solar composition somewhat depleted in a super-refractory evaporation residue. The proposed formation scenario of SJ101 invokes a non-steady cooling and condensation of the nebular gas interrupted by at least two distinct melting episodes required to account for the igneous textures of the Mel-An-Cpx-rich cores (proto-CAIs) and the Fo-Cpx lithology.  相似文献   

Energy dissipation within the wave run-up at stepped revetments     

Nils B. Kerpen  Daniel B. Bung  Daniel Valero  Torsten Schlurmann 《中国海洋大学学报(英文版)》2017,16(4):649-654

To understand the processes and energy dissipation performance caused by turbulence during the wave run-up over a stepped revetment, hydraulic model tests with steady flow conditions are conducted and correlated with unsteady flow conditions of the wave run-up within a short time frame. Under irregular waves, the run-up reduction over a stepped revetment is dependent on the Iribarren number and decreases for decreasing Iribarren numbers. Velocity gradients are found to be similar in a steady and unsteady flow regime near the pseudo-bottom.  相似文献   

Southern hemispheric westerlies control the spatial distribution of modern sediments in Laguna Potrok Aike,Argentina     

Stephanie Kastner  Christian Ohlendorf  Torsten Haberzettl  Andreas Lücke  Christoph Mayr  Nora I. Maidana  Frank Schäbitz  Bernd Zolitschka 《Journal of Paleolimnology》2010,44(4):887-902

We studied the internal lake processes that control the spatial distribution and characteristics of modern sediments at the ICDP (International Continental Scientific Drilling Program) deep drilling site in Laguna Potrok Aike, southern Patagonia, Argentina. Sediment distribution patterns were investigated using a dense grid of 63 gravity cores taken throughout the lake basin and 40 additional shoreline samples. Analysis of the surficial sediment distribution points to distinct internal depositional dynamics induced by wind-driven lake internal currents. Distribution maps illustrate that the spatial characteristics of analysed variables are linked to high erosional wave activity. Persistent wave action and littoral erosion along all shores, especially the eastern shore, is caused by prevailing Southern Hemispheric Westerlies. Several sediment variables (grain size, benthic diatoms, total inorganic carbon and calcium) indicate re-suspension of littoral sediment followed by re-distribution to profundal accumulation areas near the eastern shore. Variations within the catchment influence sediment characteristics in the north-eastern bay. That area is characterized by different mineralogical and sedimentological conditions as well as greater accumulation of pollen, inorganic carbon and diatoms. These findings are related to the influence of episodic inflow into this bay. Spatial differences in stable isotope values throughout the lake suggest that ephemeral tributaries around the lake basin may also contribute to the detected spatial sediment variations.  相似文献   

INTERNATIONAL SOCIETY FOR PHOTOGRAMMETRY AND REMOTE SENSING SYMPOSIA, 1998 EARTH OBSERVATION SYSTEMS FOR SUSTAINABLE DEVELOPMENT     

K. Jacobsen 《The Photogrammetric Record》1999,16(93):533-534

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