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91.
A proposed new type of arsenian pyrite: Composition, nanostructure and geological significance 总被引:8,自引:0,他引:8
Artur P. Deditius Udo Becker Stephen E. Kesler 《Geochimica et cosmochimica acta》2008,72(12):2919-2933
This report describes a new form of arsenian pyrite, called As3+-pyrite, in which As substitutes for Fe [(Fe,As)S2], in contrast to the more common form of arsenian pyrite, As1−-pyrite, in which As1− substitutes for S [Fe(As,S)2]. As3+-pyrite has been observed as colloformic overgrowths on As-free pyrite in a hydrothermal gold deposit at Yanacocha, Peru. XPS analyses of the As3+-pyrite confirm that As is present largely as As3+. EMPA analyses show that As3+-pyrite incorporates up to 3.05 at % of As and 0.53 at. %, 0.1 at. %, 0.27 at. %, 0.22 at. %, 0.08 at. % and 0.04 at. % of Pb, Au, Cu, Zn, Ni, and Co, respectively. Incorporation of As3+ in the pyrite could be written like: As3++yAu++1-y(□)⇔2Fe2+; where Au+ and vacancy (□) help to maintain the excess charge. HRTEM observations reveal a sharp boundary between As-free pyrite and the first overgrowth of As3+-pyrite (20-40 nm thick) and co-linear lattice fringes indicating epitaxial growth of As3+-pyrite on As-free pyrite. Overgrowths of As3+-pyrite onto As-free pyrite can be divided into three groups on the basis of crystal size, 8-20 nm, 100-300 nm and 400-900 nm, and the smaller the crystal size the higher the concentration of toxic arsenic and trace metals. The Yanacocha deposit, in which As3+-pyrite was found, formed under relatively oxidizing conditions in which the dominant form of dissolved As in the stability field of pyrite is As3+; in contrast, reducing conditions are typical of most environments that host As1−-pyrite. As3+-pyrite will likely be found in other oxidizing hydrothermal and diagenetic environments, including high-sulfidation epithermal deposits and shallow groundwater systems, where probably kinetically controlled formation of nanoscale crystals such as observed here would be a major control on incorporation and release of As3+ and toxic heavy metals in oxidizing natural systems. 相似文献
92.
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94.
Hans Becker 《International Journal of Earth Sciences》1937,28(5):385-406
Ohne Zusammenfassung 相似文献
95.
The Tamayo transform fault is located at the north end of the East Pacific Rise where it enters the Gulf of California. This paper presents bathymetric, seismic reflection, magnetic, and gravity data from a detailed survey of the transform fault. The dominant feature of the offset region is a bathymetric ridge trending 120°, parallel to the predicted transform plate boundary. This transform ridge is associated with a large (600 ) positive magnetic anomaly, and a very small positive free-air gravity anomaly. Magnetic and gravity models indicate either a basalt or serpentinite composition for the ridge, but cannot distinguish between these possibilities. At its eastern end, the modern zone of strike-slip motion is in a narrow valley south of the transform ridge. The transform plate margin appears to pass through a saddle in the transform ridge and meet the western spreading center segment in the trough north of the transform ridge. On the basis of this survey and previous work, the history of the Tamayo from continental breakup to the present has been reconstructed. Initial rifting occurred along a trend of 130° at approximately 3.5 m.y.b.p. Once the transform fault was free of the constraints imposed by continent-continent and continent-oceanic lithospheric interaction, the trend of the transform fault rotated counter-clockwise. This rotation resulted in a leaky transform fault and intrusion of a large continuous transform ridge. Further adjustments in the spreading center/transform fault plate boundary configuration have given rise to an incipient zone of rifting cutting across the transform ridge and emplacement of diapiric structures.Contribution of the Scripps Institution of Oceanography, new series. 相似文献
96.
Volcanic stratigraphy of DSDP/ODP Hole 395A: An interpretation using well-logging data 总被引:1,自引:0,他引:1
Bartetzko Anne Pezard Philippe Goldberg David Sun Yue-Feng Becker Keir 《Marine Geophysical Researches》2001,22(2):111-127
Deep Sea Drilling Project/Ocean Drilling Program Hole 395A was drilled approximately 500 m deep into young oceanic crust west
of the Mid-Atlantic Ridge. Core recovery is very poor in this hole and therefore continuous downhole measurements are important
to understand the drilled lithology. Geophysical downhole measurements were carried out during several cruises. A new set
of logs was recorded during Leg 174B in summer 1997. The new logging data show a significant improvement in data quality compared
to older measurements from Leg 109. The lithostratigraphy established from cores gives only limited information because of
the poor core recovery in this hole. The gaps in the core lithostratigraphy are filled by reconstructing a synthetic lithological
profile using the standard well-logging data. Three types of lava morphologies, massive basalts, altered lava flows, and pillow
basalts, may be distinguished using the logs because the lava morphologies show differences in their physical properties due
to differences in fracturing and alteration. The synthetic lithological profile gives a more detailed and precise vertical
definition of single layers than the core profile. The integration of further logging and core data enables a detailed reconstruction
of the accretion history at the drill site. Cyclic, upward decreasing trends in the resistivity logs were already observed
during earlier cruises and were referred to magmatic cycles. Similar trends occur in the density log and, inversely, in the
total gamma ray log. The trends reflect gradual changes in fracturing, porosity, permeability, and alteration and cover depth
intervals of several tens of meters. Boundaries between cycles are interpreted to correspond to periods of volcanic quiescence.
Two types of boundaries may be identified. Boundaries correlating with reversals in the magnetic field and/or changes in the
geochemical composition of the basalts are interpreted as long pauses. Basalts separated by these boundaries were probably
fed by separate magma reservoirs. Boundaries identified only by changes in alteration but not in geochemistry are interpreted
to represent shorter pauses. They separate basalts that were probably fed by the same magma chamber.
This revised version was published online in November 2006 with corrections to the Cover Date. 相似文献
97.
H. J. Becker 《Astrophysics and Space Science》1984,99(1-2):157-161
A method is described for an analysis of deconvoluted stellar spectra, and applied to new spectroscopic observations of the close eclipsing system AE Phuenicis, obtained with the 1.52 m telescope of the Southern European Observatory at La Silla, Chile, Results are presented for the rotational velocities of this variable, together with a proposed model of the system.Paper presented at the Lembang-Bamberg IAU Colloquium No. 80 on Double Stars: Physical Properties and Generic Relations, held at Bandung, Indonesia, 3–7 June, 1983. 相似文献
98.
The Chan Hol cave near Tulum (Quintana Roo,Mexico): evidence for long‐lasting human presence during the early to middle Holocene
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99.
Katharine McKinnon Melissa Kennedy Jo Barraket Tracy DeCotta 《The Australian geographer》2020,51(3):361-375
ABSTRACT Work Integration Social Enterprises (WISE) offer supported work environments for people experiencing disadvantage, including people with disability. This paper reflects on a research project that is mapping the ways in which social enterprises in regional Australian cities produce wellbeing for their employees. Through supported employment programs, these organisations are transforming individual lives, helping to build a sense of self-worth and purpose, and increase individuals’ social skills and capacities. Many of the perceived benefits are associated with a belief in the innate good of paid work. Based upon interviews with employees in the social enterprises, it is apparent that the hopes attached to providing ‘meaningful work’ are considerable. At the same time social enterprises are taking on social responsibilities that were once provided by the state, while also selling their services as employers of disabled and disadvantaged members of society and maintaining commercial viability of the enterprise. Using feminist political economy alongside discussion of the distributive economy, this paper explores how contemporary policy conditions, productivist biases and normative discourses about the value of wage work inflect the forms of wellbeing that can be experienced by WISE workers. 相似文献
100.
J.R. Thigpen R.D. Law C.L. Loehn R. A. Strachan R.J. Tracy G.E. Lloyd B.L. Roth S.J. Brown 《Journal of Metamorphic Geology》2013,31(8):813-842
In the Caledonides of northwest Scotland, two independent geothermometers (Fe‐Mg exchange and quartz c‐axis fabric opening angle) are used to characterize the thermal structure of the lower part of the Scandian (435–420 Ma) orogenic wedge within the Moine, Ben Hope and Naver‐Sgurr Beag thrust sheets. Traced from west (foreland) to east (hinterland), Fe‐Mg exchange thermometry yields peak or near‐peak temperatures ranging from 484 ± 50 °C to 524 ± 50 °C in the immediate hangingwall of the Moine thrust to 601 ± 50 °C in the immediate hangingwall of the Ben Hope thrust, to 630 ± 50 °C in the Naver thrust sheet. Preserved metamorphic facies and textural relationships are consistent with thermometric estimates. Deformation temperatures calculated from quartz c‐axis fabric opening angles across two similar orogen‐perpendicular transects also yield systematic increases (Glen Golly – Ben Klibreck, 520–630 °C; Ullapool‐Contin, 465–632 °C) traced towards the Naver and Sgurr Beag thrusts. In addition, deformation temperatures show a pronounced increase along the leading edge of the Moine thrust sheet moving south towards the Assynt window, which is interpreted to reflect deeper exhumation of the thrust plane above the Assynt footwall imbricate stack. Because temperatures calculated from metamorphic assemblages are within error of the quartz fabric‐derived deformation temperatures that are of demonstrably Scandian age, the metamorphic sequence between the Moine and Naver‐Sgurr Beag thrusts is interpreted to have developed during the Scandian orogeny. Integration of our results with previous 2D thermal‐mechanical studies allows development of new conceptual thermal‐kinematic models of Scandian orogenesis that may be broadly applicable to other collisional systems. Furthermore, it highlights the critical nature of coupling between orogen kinematic and thermal evolution. 相似文献