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1.
To date, passive flux meters have predominantly been applied in temperate environments for tracking the movement of contaminants in groundwater. This study applies these instruments to reduce uncertainty in (typically instantaneous) flux measurements made in a low-gradient, wetland dominated, discontinuous permafrost environment. This method supports improved estimation of unsaturated and over-winter subsurface flows which are very difficult to quantify using hydraulic gradient-based approaches. Improved subsurface flow estimates can play a key role in understanding the water budget of this landscape.  相似文献   
2.
The giant impact hypothesis is the dominant theory explaining the formation of our Moon. However, the inability to produce an isotopically similar Earth–Moon system with correct angular momentum has cast a shadow on its validity. Computer-generated impacts have been successful in producing virtual systems that possess many of the observed physical properties. However, addressing the isotopic similarities between the Earth and Moon coupled with correct angular momentum has proven to be challenging. Equilibration and evection resonance have been proposed as means of reconciling the models. In the summer of 2013, the Royal Society called a meeting solely to discuss the formation of the Moon. In this meeting, evection resonance and equilibration were both questioned as viable means of removing the deficiencies from giant impact models. The main concerns were that models were multi-staged and too complex. We present here initial impact conditions that produce an isotopically similar Earth–Moon system with correct angular momentum. This is done in a single-staged simulation. The initial parameters are straightforward and the results evolve solely from the impact. This was accomplished by colliding two roughly half-Earth-sized impactors, rotating in approximately the same plane in a high-energy, off-centered impact, where both impactors spin into the collision.  相似文献   
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Texturally complex monazite grains contained in two granulite-facies pelitic migmatites from southern Baffin Island, Arctic Canada, were mapped by laser ablation-inductively coupled plasma-mass spectrometry (using spot sizes ≤5 µm) to quantitatively determine the spatial variation in trace element chemistry (with up to 1,883 analyses per grain). The maps highlight the chemical complexity of monazite grains that have experienced multiple episodes of growth, resorption and chemical modification by dissolution–precipitation during high-grade metamorphism. Following detailed chemical characterization of monazite compositional zones, a related U–Pb data set is re-interpreted, allowing petrologically significant ages to be extracted from a continuum of concordant data. Synthesis of these data with pseudosection modelling of prograde and peak conditions allows for the temporal evolution of monazite trace element chemistry to be placed in the context of the evolving PT conditions and major phase assemblage. This approach enables a critical evaluation of three commonly used petrochronological indicators: linking Y to garnet abundance, the Eu anomaly to feldspar content and Th/U to anatectic processes. Europium anomalies and Th/U behave in a relatively systematic fashion, suggesting that they are reliable petrochronological witnesses. However, Y systematics are variable, both within domains interpreted to have grown in a single event, between grains interpreted to be part of the same age population, and between samples that experienced similar metamorphic conditions and mineral assemblages. These observations caution against generalized petrological interpretations on the basis of Y content, as it suggests Y concentrations in monazite are controlled by domainal equilibria. The results reveal a c. 45 Myr interval between prograde metamorphism and retrograde melt crystallization in the study area, emphasizing the long-lived nature of heat flow in high-grade metamorphic terranes. Such long timescales of metamorphism would be assisted by the growth, retention and dominance of high-Th suprasolidus monazite, as observed in this study, contributing to the radiogenic heating budget of mid- to lower-crustal environments. Careful characterization of monazite grains suggests that continuum-style U–Pb data sets can be decoded to provide insights into the duration of metamorphic processes.  相似文献   
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Natural Resources Research - There have been many studies carried out in the past decades attempting to develop strategies for a safe injection of CO2 into storage sites without leakage and...  相似文献   
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The development of coal forests during the Carboniferous is one of the best-known episodes in the history of life. Although often reconstructed as steamy tropical rainforests, these ancient ecosystems were a far cry from anything we might encounter in the Amazon today. Bizarre giant club-mosses, horsetails and tree ferns were the dominant plants, not flowering trees as in modern rainforests. At their height, coal forests stretched all the way from Kansas to Kazakhstan, spanning the entire breadth of tropical Pangaea. Most of what we know of their biodiversity and ecology has been quite literally mined out of the ground through two centuries of hard labour. Without coal mining, our knowledge would be greatly impoverished. Over the past few years, we've been exploring underground coal mines in the United States, where entire forested landscapes have been preserved intact over huge areas. Never before have geologists had the opportunity to walk out through mile upon mile of fossilized forest. In this feature article, we describe some of our recent explorations and attempt to shed new light on these old fossils.  相似文献   
7.
Abstract— Martian meteorites (MMs) have been launched from an estimated 5–9 sites on Mars within the last 20 Myr. Some 80–89% of these launch sites sampled igneous rock formations from only the last 29% of Martian time. We hypothesize that this imbalance arises not merely from poor statistics, but because the launch processes are dominated by two main phenomena: first, much of the older Martian surface is inefficient in launching rocks during impacts, and second, the volumetrically enormous reservoir of original cumulate crust enhances launch probability for 4.5 Gyr old rocks. There are four lines of evidence for the first point, not all of equal strength. First, impact theory implies that MM launch is favored by surface exposures of near‐surface coherent rock (≤102 m deep), whereas Noachian surfaces generally should have ≥102 m of loose or weakly cemented regolith with high ice content, reducing efficiency of rock launch. Second, similarly, both Mars Exploration Rovers found sedimentary strata, 1–2 orders of magnitude weaker than Martian igneous rocks, favoring low launch efficiency among some fluvial‐derived Hesperian and Noachian rocks. Even if launched, such rocks may be unrecognized as meteorites on Earth. Third, statistics of MM formation age versus cosmic‐ray exposure (CRE) age weakly suggest that older surfaces may need larger, deeper craters to launch rocks. Fourth, in direct confirmation, one of us (N. G. B.) has found that older surfaces need larger craters to produce secondary impact crater fields (cf. Barlow and Block 2004). In a survey of 200 craters, the smallest Noachian, Hesperian, and Amazonian craters with prominent fields of secondaries have diameters of ?45 km, ?19 km, and ?10 km, respectively. Because 40% of Mars is Noachian, and 74% is either Noachian or Hesperian, the subsurface geologic characteristics of the older areas probably affect statistics of recognized MMs and production rates of secondary crater populations, and the MM and secondary crater statistics may give us clues to those properties.  相似文献   
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A variety of measures of organic matter concentration and quality were made on samples collected from the top few mm of intertidal mudflat sediment over the course of a year, in order to assess the relative importance of biological and sedimentological influences on sedimentary organic matter. Winter and summer were times of relatively fine-grained sediment accumulation, caused by biological deposition or stabilization processes and resulting in higher organic matter concentrations. Stable carbon isotope and Br:C ratios indicated a planktonic source of bulk organic matter. Ratios of organic carbon to specific surface area of the sediments were consistent with an organic monolayer coverage of sediment grains. Correction for changing grain size during the year showed no change in the organic concentration per unit surface area, in spite of organic matter inputs by in situ primary production, buildup of heterotroph biomass and mucus coatings, and biodeposition of organic-rich seston. There were also no indications of changes in bulk organic quality, measured as hydrolyzable carbohydrates and amino acids, in response to these biological processes. It is concluded that biological processes on a seasonal time scale affect the bulk organic matter of these sediments via a modulation of grain size rather than creation or decay of organic matter.  相似文献   
10.
We present new 1.45-1.75 μm spectra of Europa's dark non-ice material with a spectral resolution (λ/δλ) of 1200, obtained by using adaptive optics on the Keck telescope to spatially separate the spectrum of the non-ice material from that of the surrounding ice-rich regions. Despite the great increase in spectral resolution over the previous best spectra of the non-ice material, taken with Galileo's near-infrared mapping spectrometer (NIMS) with λ/δλ=66, no new fine-scale spectral structure is revealed. The smoothness of the spectra is inconsistent with available laboratory spectra of crystalline hydrated salts at Europa temperatures, but is more consistent with various combinations of non-crystalline hydrated salts and/or hydrated sulfuric acid, as have been matched to the lower-resolution NIMS spectra.  相似文献   
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