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A Study on the Surface Wettability of Clastic Rocks with Potential Application for CO2 Storage Sites
Umar Bappah Adamu Gholami Raoof Raza Arshad Downey William Samuel Sarmadivaleh Mohammad Shah Afroz A. Nayak Prasanta 《Natural Resources Research》2020,29(3):2051-2061
Natural Resources Research - There have been many studies carried out in the past decades attempting to develop strategies for a safe injection of CO2 into storage sites without leakage and... 相似文献
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The coupling of Shukla-Varma (SV) and convective cell modes is discussed in the presence of non-Boltzmannian electron response and parallel equilibrium shear flow. In the linear case, a new dispersion relation is derived and analyzed. It is found that the coupled SV and convective cell modes destabilize in the presence of electron shear flow. On the other hand, in the nonlinear regime, it is shown that Shukla-Varma mode driven counter rotating vortices can be formed for the system under consideration. It is found that these vortices move slowly by comparison with the ion acoustic or electron drift-wave driven counter rotating vortices. The relevance of the present investigation with regard to space plasmas is also pointed out. 相似文献
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Geochemical and oxygen isotope perspective of a new R chondrite Dhofar 1671: Affinity with ordinary chondrites 
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下载免费PDF全文 Arshad Ali Sobhi J. Nasir Iffat Jabeen Ahmed Al Rawas Neil R. Banerjee Gordon R. Osinski 《Meteoritics & planetary science》2017,52(9):1991-2003
Dhofar 1671 is a relatively new meteorite that previous studies suggest belongs to the Rumuruti chondrite class. Major and REE compositions are generally in agreement with average values of the R chondrites (RCs). Moderately volatile elements such as Se and Zn abundances are lower than the R chondrite values that are similar to those in ordinary chondrites (OCs). Porphyritic olivine pyroxene (POP), radial pyroxene (RP), and barred olivine (BO) chondrules are embedded in a proportionately equal volume of matrix, one of the characteristic features of RCs. Microprobe analyses demonstrate compositional zoning in chondrule and matrix olivines showing Fa‐poor interior and Fa‐rich outer zones. Precise oxygen isotope data for chondrules and matrix obtained by laser‐assisted fluorination show a genetic isotopic relationship between OCs and RCs. On the basis of our data, we propose a strong affinity between these groups and suggest that OC chondrule precursors could have interacted with a 17O‐rich matrix to form RC chondrules (i.e., ?17O shifts from ~1‰ to ~3‰). These interactions could have occurred at the same time as “exotic” clasts in brecciated samples formed such as NWA 10214 (LL3–6), Parnallee (LL3), PCA91241 (R3.8–6), and Dhofar 1671 (R3.6). We also infer that the source of the oxidation and 17O enrichment is the matrix, which may have been enriched in 17O‐rich water. The abundance of matrix in RCs relative to OCs, ensured that these rocks would be apparently more oxidized and appreciably 17O‐enriched. In situ analysis of Dhofar 1671 is recommended to further strengthen the link between OCs and RCs. 相似文献
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M. Farooq Ahmed Umer Waqas Muhammad Arshad J. David Rogers 《Arabian Journal of Geosciences》2018,11(22):728
Temperature is one of the variables that influence the elasto-plastic behavior and integrity of rock outcrops. Fluctuations in temperature can trigger alteration of some of the mineral properties and impact the brittle-plastic transition. Initiation and propagation of thermally induced tension cracks tend to weaken most rock types. The principal goal of this study was to anticipate impacts of thermal stress-strain cycles on the dynamic response of representative rock units exposed in the Khewra Gorge of the Salt Range Punjab of Pakistan. Ten types of sedimentary rock units were sampled, including marl, dolomite, three types of limestone, and five different sandstones exhibiting varying characteristics in outcrop. Boulder specimens were collected from the field and transported to the laboratory to prepare 50 drill cores that could be subjected to thermal cycling between 50 and 200 °C in increments of 50 °C. Room temperature core samples were tested using an Erudite resonance frequency meter to measure their Q-factors and the resonance frequency (Fr) at an applied loading frequency of 7 KHz with 0.01 V output voltage. Results suggest that thermal cycling tends to reduce the dynamic Young’s modulus (Ed) and Q-factor. Other parameters, such as damping ratio (ξ), specific damping capacity (Ψ), and loss factor (?) appeared to increase with increasing temperature cycles, likely as a result of developing thermally induced tensile fractures. The resultant values of the null hypothesis (t-critical and t-stats) suggests that the null hypothesis can be discarded because there was no observable difference between the measured and expected values for the cores tested. The observations and data emanating from this study might be useful in designing low-level radioactive waste landfills, nuclear waste repositories, and deep underground excavations where the increased temperature could alter the mechanical behavior of the parent rock mass. 相似文献
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Muhammad Adeel Arshad 《地震科学（英文版）》2016,29(5):259-269
An inversion method was applied to crustal earthquakes dataset to find S-wave attenuation characteristics beneath the Eastern Tohoku region of Japan.Accelerograms from 85 shallow crustal earthquakes up to25 km depth and magnitude range between 3.5 and 5.5were analyzed to estimate the seismic quality factor Q_s. A homogeneous attenuation model Q_s for the wave propagation path was evaluated from spectral amplitudes, at 24 different frequencies between 0.5 and 20 Hz by using generalized inversion technique. To do this, non-parametric attenuation functions were calculated to observe spectral amplitude decay with hypocentral distance. Then, these functions were parameterized to estimate Q_s. It was found that in Eastern Tohoku region, the Q_s frequency dependence can be approximated with the function 33 f~(1.22) within a frequency range between 0.5 and 20 Hz. However,the frequency dependence of Q_s in the frequency range between 0.5 and 6 Hz is best approximated by Q_s(f) = 36f~(0.94) showing relatively weaker frequency dependence as compared to the relation Q_s(f) = 6 f~(2.09) for the frequency range between 6 and 15 Hz. These results could be used to estimate source and site parameters for seismic hazard assessment in the region. 相似文献
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Ten wheat production sites of Pakistan were categorized into four climatic zones i.e. arid, semi-arid, sub-humid and humid to explore the vulnerability of wheat production in these zones to climate change using CSM-Cropsim-CERES-Wheat model. The analysis was based on multi-year (1971–2000) crop model simulation runs using daily weather series under scenarios of increased temperature and atmospheric carbon dioxide concentration (CO2) along with two scenarios of water management. Apart from this, sowing date as an adaptation option to offset the likely impacts of climate change was also considered. Increase in temperature resulted in yield declines in arid, semi-arid and sub-humid zone. But the humid zone followed a positive trend of gain in yield with rise in temperature up to 4°C. Within a water regime, increase in CO2 concentration from 375 to 550 and 700 ppm will exert positive effect on gain in wheat yield but this positive effect is significantly variable in different climatic zones under rainfed conditions than the full irrigation. The highest response was shown by arid zone followed by semi-arid, sub-humid and humid zones. But if the current baseline water regimes (i.e. full irrigation in arid and semi-arid zones and rainfed in sub-humid and humid zones) persist in future, the sub-humid zone will be most benefited in terms of significantly higher percent gain in yield by increasing CO2 level, mainly because of its rainfed water regime. Within a CO2 level the changes in water supply from rainfed to full irrigation shows an intense degree of responsiveness in terms of yield gain at 375 ppm CO2 level compared to 550 and 700 ppm. Arid and semi-arid zones were more responsive compared to sub-humid and humid zones. Rise in temperature reduced the length of crop life cycle in all areas, though at an accelerated rate in the humid zone. These results revealed that the climatic zones have shown a variable intensity of vulnerability to different scenarios of climate change and water management due to their inherent specific and spatial climatic features. In order to cope with the negative effects of climate change, alteration in sowing date towards cooler months will be an appropriate response by the farmers. 相似文献
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Muhammad Saeed Komal Farooq Muhammad Nafees Muhammad Arshad Mohammad Salim Akhter Amir Waseem 《洁净——土壤、空气、水》2020,48(9)
In the current study the application of organo‐modified bentonite for the adsorption of mycotoxins (aflatoxin B1, citrinin, patulin, and zearalenone) is presented. The modification of clays is carried out using benzyl‐tri‐n‐butyl ammonium bromide (BTB), benzethonium chloride (BTC), and dioctyl sodium sulfosuccinate (DSS). Various experimental parameters such as pH, time, adsorbent dose, and mycotoxins concentration are thoroughly studied. The modified clays (B‐BTB, B‐BTC and B‐DSS) are characterized by X‐ray fluorescence, X‐ray diffraction, and Fourier transform infrared spectroscopy. The results depicted the high detoxification efficiency (≈99%) of modified clays for the removal of mycotoxins under optimized conditions (pH 5, time: 30 min, adsorbent amount: 50 mg). The adsorption capacities of modified clays are found in the order of: B‐BTC (AFB1: 18.02, CIT: 18.35, PAT: 18.21, ZEA: 18.09 mg g?1) > B‐BTB (AFB1: 17.7, CIT: 18.11, PAT: 17.95, ZEA: 17.90 mg g?1) > B‐DSS (AFB1: 17.5, CIT: 18.02, PAT: 17.86, ZEA: 17.80 mg g?1). The obtained results fitted well with thermodynamic, isothermal (Langmuir) and pseudo‐second order kinetics. Low cost organo‐modified bentonite shows the promise in mitigating mycotoxin contamination, which could improve food safety and reduce environmental contamination. 相似文献
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In this paper, vortex-induced vibrations of a cylinder are simulated by use of ANSYS CFX simulation code. The cylinder is treated as a rigid body and transverse displacements are obtained by use of a one degree of freedom spring damper system. 2-D as well as 3-D analysis is performed using air as the fluid. Reynolds number is varied from 40 to 16000 approx., covering the laminar and turbulent regimes of flow. The experimental results of （Khalak and Williamson, 1997） and other researchers are used for validation purposes. The results obtained are comparable. 相似文献