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1.
Natural Resources Research - There have been many studies carried out in the past decades attempting to develop strategies for a safe injection of CO2 into storage sites without leakage and...  相似文献   
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Waste engine oil causes a vital environmental pollution when it spill during change and transportation and products of waste engine oil causes lethal effects to the living systems. Thus, abiotic and biotic approaches are being extensively used for removal of waste engine oil pollution. Therefore in present study, waste engine oil degradation was accomplished by a new bacterial culture, isolated from the soil by an enrichment technique. Morphological, biochemical and gene sequence analysis revealed that isolate was Bacillus cereus. Subsequently, biodegradation potential of B. cereus for waste engine oil was studied. Experimental variables, such as pH, substrate concentration, inoculum size, temperature and time on the biodegradation, were checked in mineral salt medium. The biodegradation efficiency of B. cereus was determined by gravimetry, UV–visible spectrophotometry and gas chromatography. In addition, waste engine oil was also characterized by GC–MS and FTIR for its major constituents, which showed total 38 components in waste engine oil, including hopanes, benzopyrene, long-chain aliphatic hydrocarbons, dibenzothiophenes, biphenyl and their derivatives. Results of successive biodegradation indicated that B. cereus was capable to degrade 1% of waste engine oil with 98.6% degradation potential at pH 7 within 20 days. Hence, B. cereus presents an innovative tool for removing the engine oil from the contaminated area.  相似文献   
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The key objective of the study is to collect the factors which play an important role in the city's sustainability and implementation advantages for the development of cities in future. This article develops an urban sustainability assessment framework by giving GIS-based decision support tools to guide cities toward sustainability. Multicriteria analysis was used as the decision support system and provides an analytical framework for assessing differences in the level of criteria and ranking decision options. It has the capability for assessment of urban sustainability because it brings sustainability criteria from three pillars of sustainability, environmental, social, and economic, which provide an integrated approach for assessment of urban sustainability. The GIS-based multicriteria analysis serves as a sustainability support system that maps urban sustainability and the underlying environmental, social, and economic conditions. The results from the study show that the four cities - Faisalabad, Lahore, Gujranwala, and Multan - have better economic conditions while only Lahore and Faisalabad showed social progress and the remaining cities showed less suitability. For the environmental index, none of the cities attained high suitability. Lahore, Faisalabad, and Rawalpindi showed better conditions than Gujranwala and Multan. It is demonstrated that Punjab cities have made progress in economic condition and improvement in social condition but have poor environmental condition. In the study, the environmental dimension has indicators which have more impact on the urban sustainability. Environmental degradation is observed in all selected regions and not a single region showed suitability toward its environmental condition and due to this none of the cities gained suitable scores for urban sustainability. Consequently, urban sustainability is a multidimensional and dynamic process that needs regular evaluation and monitoring. Thus, this article contends that the tools help to highlight and emphasize those areas that need guidance in achieving urban sustainability.  相似文献   
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A thick sequence of mafic-ultramafic rocks, occurs along a major shear zone (Phulad lineament), running across the length of Aravalli Mountain Range for about 300 kms. It has been suggested, that this sequence may represent a fragment of ophiolite or a rift related metavolcanic suite made up of basalts and fractionated ultramafics. The geological and tectonic significance of the complex is assessed using field relationships, petrography and geochemistry. Structurally, the lowest part of the complex comprises a discontinuous band of plastically deformed harzburgite (mantle component) followed by layered cumulus gabbroic rocks (crustal component). A complex of non-cumulus rocks comprising hornblende schists, gabbros, sheeted dykes and pillowed basalts structurally overlies layered gabbros. Huge bodies of diorite intrude volcanics.

Geochemical classification suggests that all non-cumulus mafic rocks are sub-alkaline basalts except one variety of dykes which shows mildly alkaline character. The sub-alkaline rocks are tholeiite to calc-alkaline with boninite affinity. Tectono-magmatic variation diagrams and MORB normalised patterns suggest a fore arc tectonic regime for the eruption of these rocks.

The mafic rocks of Phulad Ophiolite Suite are zoned across the strike in terms of their distribution from west to east. The hornblende schists and basalts are exposed at the westernmost margin followed by gabbros and dykes. The alkaline dyke occurs at the easternmost part. The rocks of Phulad suite are juxtaposed with shallow water sediments in the east followed by platformal sediments and then continental slope sediments in the further east indicating gradual thickening of the crust from west to east and an eastward subduction. The geochemical interpretation presented in this study, together with discussion of lithological association is used to decipher the tectonic evolution of the Mesoproterozoics of NW Indian shield.  相似文献   

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The discovery of hydrocarbons (mainly gas) in commercial quantities from Gondwanan sediments in the Mandapeta field of Krishna-Godavari Basin, India, provided impetus for intensified exploration in Mandapeta and the adjoining Kommugudem, Draksharama and Endamuru fields. Both oil and gas have been found in the reservoirs of Mandapeta (Triassic) and Golapalli (Early Cretaceous) formations. Mature, localised, basal shales (1.0–1.1% Ro) in the Mandapeta formation have sourced the oils from the Mandapeta Sandstone reservoir (Triassic). The oils being produced from Golapalli Sandstone reservoir (Early Cretaceous) are relatively less mature and have been sourced by the underlying shales in the Mandapeta Formation at a maturity level of 0.80–0.85% Ro. The source and maturity data preclude liquid hydrocarbon sourcing from the Kommugudem (Permian) sequence. Permian coals and shales of the Kommugudem Formation are the major source rocks for gaseous hydrocarbons in this area. The hydrocarbon generation started in Early Cretaceous in the Kommugudem Formation, but the intermittent tectonic activity (with associated structural developments) has resulted in reorientation and redistribution of the then existing trap configurations. The present day maturity level of the Permian sediments in the Mandapeta field is 1.2% Ro or greater, capable of generating gas dominantly. The Raghavapuram shale in the Mandapeta area is adequately mature and has good hydrocarbon potential for oil generation. The probability of finding hydrocarbon reserves in the sands of Raghavapuram shales and other suitable traps is high. Modern seismic information together with geologic models can give new exploration leads.  相似文献   
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The problem regarding environment has been considered as contemporary issue, and to cater this, various technologies have been revolutionized in vehicle transport field. Efforts have been made to make vehicle engine efficient and introducing hybridized vehicles with the aim of reducing emissions and less fuel dependency. In essence of this, trends of solar electric cars in different countries have been reviewed. Feasibility analysis is done by doing fuel cost analysis of two cases, i.e., simple hybrid vehicle and hybrid vehicle equipped with solar module and increased battery energy storage capacity for a specific round trip distance between two cities, i.e., Rawalpindi and Islamabad in comparison with feasibility of third case, i.e., proposed solar electric car model. The solar module selection along with desired number of batteries with charging and discharging time and motor power required to carry five persons weight (70 kg each) is calculated for third case. Moreover, total carbon dioxide emission analysis has been carried out from car material production to its assembly, manufacturing solar module and nickel metal hydride battery for each case. The annual carbon dioxide emitted from fuel in first two cases relative to electric outlet in third case for specific distance has been analyzed. On large scale, emission analyses for hundred cars of each case have been done at 100 km distance. From calculations, it is revealed that overall emissions in third case on large scale and from its material production, assembly, solar module and batteries manufacturing perspective are comparatively less than other cases.  相似文献   
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This is a comprehensive study of the composition, origin and sources of specific polycyclic aromatic hydrocarbons (PAHs) in sediments of mangrove estuary in the western part of Peninsular Malaysia. Mangrove sediments were analyzed for 17 PAHs by gas chromatography–mass spectrometry. Total PAH concentrations in the sediments ranged from 20 to 112 ng/g on a dry-weight basis. High molecular weight PAHs were abundant in the sediments. Parent PAH ratios revealed that pyrogenic input has important contribution to the sedimentary PAHs. Ratios of alkylated PAHs indicate that the sedimentary PAHs were influenced by petrogenic PAHs, which implies that petrogenic input has contribution to the sedimentary PAHs but that it is not a major factor in distribution of PAHs within the estuary. Combustion-derived PAHs show a positive and very strong correlation with total PAHs (R 2 = 0.926, p < 0.05). Total methylphenanthrenes show very weak correlation with total PAHs (R 2 = 0.0928, p < 0.05). The PAH concentrations were found to increase with distance from the upstream of the estuary to the coastal area of the Straits of Malacca. For the assessment of sediment contamination using biological thresholds, none of the individual studied PAH compounds exceeded the values of the effect range low–effect range median guideline and the threshold effects level–probable effects level guideline. This study demonstrates that the sediments of the mangrove ecosystem facing the Straits of Malacca and Sumatra are influenced by anthropogenic PAH inputs as a result of human activities such as biomass burning, vehicle emissions and boating activities.  相似文献   
10.
Four wells (K-109, Hr-1, Tk-3, and Bj-1) in NE Iraq (including parts of the Kurdistan Region) were selected to study the Tithonian–Berriasian Chia Gara Formation from the inorganic geochemical point of view. The intervals studied in each well occurred at present-day burial depths of Hr-1 3,075–3,310 m; K-109 2,780–3,090; Tk-1 2,770–2,890; and Bj-1 2,150–2,310 m. A total of 16 samples from the four studied wells were investigated geochemically using X-ray fluorescence in order to measure their major element oxides and their trace element contents. Among the major oxides, CaO has the highest weight percentages in all samples as expected in this limestone-dominated formation. SiO2 and Al2O3 show higher concentrations only in well Bj-1 than the other sections, due to its shallower depth of deposition and its marginal location within the depositional basin. The general trace element distribution along all studied well successions showed good similarity. However, the ratios of V/Ni and V/Cr were of higher values in the lower part of the formation, which is considered as a good indicator to the deposition of this part of the formation within anoxic depositional environment. An exception was in well Bj-1, where the V/Ni ratio was lower in the this lower part of the formation than the upper part that may be due to the different lithology in this succession which is lacking distinct shale or calcareous shale beds. However, the V/Cr ratio can still indicate the prevailing of reducing condition because V/Cr ratios in all samples are >2. Also, Th/U ratio in the lower part of the studied successions was lower than the upper part, which is also coinciding with the domination of the reducing geochemical conditions in the depositional environment. It may be concluded from this study that the R-mode cluster analysis of the main oxides indicated to the main mineral constituent of the rock which is calcite. It is also confirmed that the SiO2 and Al2O3 contents in the Chia Gara limestones are especially high in well Bj-1, particularly in the lower and upper parts of the succession. On the other hand, R-mode cluster analysis of the trace elements showed lower amounts of Zr and V in relation to silica and confirmed the random distribution of Sr and Ba in the studied samples. Q-mode cluster analysis indicated that the upper part of the studied formation is pure limestone in well H-1 and such purity of limestone beds also occurs in the lower part of the studied formation in well Tk-3. The elemental distribution within the sections as inferred from the studied samples indicates that the anoxic depositional conditions were prevailed during the Chia Gara Formation, especially during the accumulation of the lower part.  相似文献   
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