渤海湾表层沉积物重金属与污染评价   总被引：10，自引：2，他引：10       下载免费PDF全文

秦延文  苏一兵  郑丙辉  张雷  万峻 《海洋科学》2007,31(12):28-33

用原子吸收法测定了渤海湾表层沉积物中重金属的含量,同时用2种评价方法对该海域底质环境进行了评价。结果表明:沉积物中汞、锌含量平均值超过标准,其余项目未发现超标;其分布特征由于受沿岸不同污染源的污染影响,重金属污染物难以形成一定规律的分布状态。同时该海域底质环境质量总指数已达到污染程度和很强的生态危害,其中主要污染元素是Hg,已达重污染,并形成极强的生态危害。  相似文献   

Photoinduced toxicity single and binary mixtures of four polycyclic aromatic hydrocarbons to the marine diatom Skeletonema costatum   总被引：1，自引：0，他引：1  

MENG Wei  WANG Liping  ZHENG Binghui 《海洋学报(英文版)》2007,26(6):41-50

Diatom Skeletonema costatum Cleve is one of the main predominant phytoplankton species in the Changjiang Estuary in China. In order to provide some basic information for future assessment of the potential risk on phytoplankton communities in this estuary caused by polycyclic aromatic hydrocarbons(PAHs), this alga was selected as a representative to investigate the photoinduced toxicity of PAHs, in single and mixture. Four PAHs including three-ring phenanthrene and anthracene, four-ring fluoranthene and pyrene were tested in the laboratory. The single toxicity of each PAH on this microalga was compared with and without the simulated solar UV radiation. The results showed that this microalga was sensitive to PAH's photoinduced toxicity. Ratios of the 72 h median effect concentration obtained for fluorescent and UV light tests were about 8.4 for phenanthrene, 13.0 for anthracene, 6.5 for fluoranthene, and 5.7 for pyrene, indicating that UV light enhanced the PAH toxicity to this alga significantly. Under the fluorescent radiation (lacking UV), the dose-response curves based on chemical concentrations revealed that the order of toxic strength was fluoranthene greater than pyrene greater than anthracene greater than phenanthrene; while under the UV radiation (476 μW/cm2 for UVA, 6.5 μW/cm2 for UVB) it became fluoranthene approximately equaling anthracene greater than pyrene greater than phenanthrene, indicating that the UV light also changed its relative toxicity to this alga. The photoinduced toxicity of PAHs to the marine diatom S. costatum might be a synergistic effect of photosensitization reactions (e.g., generation of single-state oxygen) and photomodification (photooxidation and/or photolysis).The combined effects of six binary mixtures on the marine diatom S. costatum were investigated using the additive-index method. Four binary-mixtures (phenanthrene plus anthracene; phenanthrene plus pyrene; anthracene plus fluoranthene; anthracene plus pyrene) were found to be synergistic joint action mode, while two binary-mixtures (phenanthrene plus fluoranthene; fluoranthene plus pyrene) displayed antagonist, revealing a complex pattern of possible interactions. The combined action mode of PAHs might be related to various factors such as the mixture compounds, mixture ratios and test conditions, etc.  相似文献   

软粘土中插入式大直径薄壁圆筒结构的一种极限状态分析模型     

王乐芹  周锡礽  张伟 《海洋技术学报》2005,24(1):95-100

根据插入式大直径薄壁圆筒结构的工作特点建立了其合理的破坏机制，以此为基础建立了受横向荷载作用的插入式大直径薄壁圆筒结构的上限法极限分析模型，从中可以得到作用于插入式大直径薄壁圆筒结构上的横向极限荷载近似的上限解；并根据上限法模型计算结果，提出了计算受横向荷载作用的插入式大圆筒结构侧壁极限抗力的简化修正模型，利用此修正模型，基于极限平衡法，可以求解作用于插入式大直径薄壁圆筒结构上的横向极限荷载。  相似文献   

Application of LICOM to the numerical study of the water exchangebetween the South China Sea and its adjacent oceans   总被引：8，自引：1，他引：8  

CAI Shuqun  LIU Hailong  LI Wei  LONG Xiaomin 《海洋学报(英文版)》2005,24(4):10-19

1 IntroductionThe South China Sea (SCS) is the largestmarginal sea in the western Pacific (see Fig. 1). It con-nects with the SCS through the Taiwan Strait, with thePacific through the Luzon Strait, with the Sulu Seathrough the Mindoro and Balabac Straits and with theJava Sea and Andaman Sea through the Sunda Shelf(For convenience, here we refer to the section at 1.5°N,Fig. 2). It is shown that the seasonal SCS circulation ismostly affected by the summer/winter monsoon, andthe no…  相似文献   

溴素的有机化学──Ⅴ.溴代脂肪酸—2,3,5,6—四溴—1,4—苯二酯的合成     

崔伟  孙明昆  钱佐国  刘升一 《中国海洋大学学报(自然科学版)》1996,(3)

以1，4—苯二酚和不同的短链脂肪酸为基本原料，经溴代、加成、形成酰卤和酰化等反应，合成了六种新的溴化脂肪酸—2，3，5，6—四溴—1，4—苯二酯。通过对产物的碳、氢、溴等元素的定量分析，以及红外吸收光谱和氢核磁共振谱的研究，验证了化合物的结构。  相似文献   

中国沿海星虫动物门名录   总被引：2，自引：0，他引：2  

李凤鲁  周红  王玮 《中国海洋大学学报(自然科学版)》1992,(2)

取1980～1989年间在我国沿海进行星虫动物区系调查的标本和有关资料做了整理、鉴定,共39种,分隶于2纲,4目,6科,12属。其中1种在我国为首次记录。  相似文献   

Simulations of Annual Cycle of Phytoplankton Production and the Utilization of Nitrogen in the Yellow Sea     

Tian?TianEmail author  Hao?Wei  Jian?Su  Changsoo?Chung 《Journal of Oceanography》2005,61(2):343-357

A nutrient dynamic model coupled with a 3D physical model has been developed to study the annual cycle of phytoplankton production in the Yellow Sea. The biological model involves interactions between inorganic nitrogen (nitrate and ammonium), phosphate and phytoplankton biomass. The model successfully reproduces the main features of phytoplankton-nutrient variation and dynamics of production. 1. The well-mixed coastal water is characterized by high primary production, as well as high new production. 2. In summer, the convergence of tidal front is an important hydrodynamic process, which contributes to high biomass at frontal areas. 3. The evolution of phytoplankton blooms and thermocline in the central region demonstrate that mixing is a dominant factor to the production in the Yellow Sea. In this simulation, nitrate- and ammonium-based productions are estimated regionally and temporally. The northern Yellow Sea is one of the highly ranked regions in the Yellow Sea for the capability of fixing carbon and nitrogen. The annual averaged f-ratio of 0.37 indicates that regenerated production prevails over the Yellow Sea. The result also shows that phosphate is the major nutrient, limiting phytoplankton growth throughout the year and it can be an indicator to predict the bloom magnitude. Finally, the relative roles of external nutrient sources have been evaluated, and benthic fluxes might play a significant role in compensating 54.6% of new nitrogen for new production consumption.  相似文献   

海洋环流模式中不同近似假设下的海表高度   总被引：1，自引：1，他引：1  

李薇  张学洪  金向泽 《海洋科学进展》2003,21(2):132-141

Boussinesq近似是现代海洋环流模式中经常采用的假设，但随着海洋模式的不断发展完善以及气候研究应用的需要，有必要估算Boussinesq近似造成的模式误差。分别利用一个非Boussinesq近似的海洋模式与另一个结构相同且采用Boussinesq近似的模式计算海表高度，并同时利用模式预报的温度、盐度资料计算了比容异常高度。分析结果显示，这3种不同定义的海表高度无论空间结构，还是时间演变，都基本类似，尤其在热带海区最接近，差值≤1cm。Boussinesq近似意味着在模式中以体积守恒代替质量守恒，通常的做法是对其进行简单的质量补偿来保持质量守恒。比较说明，以质量补偿方法进行的高度订正对减小Boussinesq近似带来的误差没有本质的意义。  相似文献   

东太平洋地区DSDP573孔始新世末期的微玻璃陨石   总被引：5，自引：1，他引：5  

尹延鸿  万天丰  孙嘉诗 《海洋地质与第四纪地质》2001,21(4):37-42

通过研究 DSDP5 73孔的岩心样品 ,首次在该孔始新世与渐新世的界线地层含金属粘土层中发现了微玻璃陨石 ,且主要富集在其底部。一个样品 (5 g)中最多可达 12粒。这些微玻璃陨石主要呈球形、椭球形。用电子探针测试了其化学成分 ,Si O2 含量为 2 9.6 4%～ 5 8.93%,Al2 O3 为 3.42 %～ 2 0 .96 %,Fe O为 9.98%～ 2 9.5 5 %,Mg O为 4.32 %～ 16 .0 5 %,Ir为 0 .0 6 %～ 0 .81%。总体来说 ,微玻璃陨石的化学成分变化较大 ,可能与靶岩的成分变化较大有关。始新世末期北美微玻璃陨石场的展布方向约为 2 5 0°,这与太平洋板块运动方向改变所需要的矢量变化(2 45°)仅相差 5°,推测很可能是始新世末期陨星的撞击引起了太平洋板块在该时期的运动方向由 NNW突然变为NWW。  相似文献   

西边界流在边界“豁口”的形变及其机制   总被引：1，自引：0，他引：1  

李薇  刘秦玉 《中国海洋大学学报(自然科学版)》1997,(3)

大洋西边界流在边界豁口处由于失去边界的支持而发生形变。本文将西边界流视为一种惯性射流，遵循绝对涡度守恒原理，推导了流轴及其两侧流体在西边界豁口处不同形式的弯曲，发现在一定的豁口尺度条件下，西边界流自身的相对涡度分布特点和地球旋转的β效应决定了在失去西侧陆坡支持时，其主体会沿反气旋路径发生一段经向的位移而圈回入射点所在的经度位置。主轴变形的经向尺度与初始速度及西边界流的入射角度有关；主轴西侧可能会出现一小部分分支进入邻近的内海并形成气旋或反气旋式环流；主轴东侧的流体则在豁口以东沿反气旋路径弯曲，从而论证了西边界豁口处形成西边界流弯曲的可能性和原因  相似文献