Traces of volcanic ash from the Mediterranean,Iceland and North America in a Holocene record from south Wales,UK     

Gwydion Jones  Siwan M. Davies  Richard A. Staff  Neil J. Loader  Sarah J. Davies  Michael J. C. Walker 《第四纪科学杂志》2020,35(1-2):163-174

A tephra record is presented for a sediment core from Llyn Llech Owain, south Wales, spanning the early- to mid-Holocene. Seven cryptotephra deposits are discovered with three thought to correlate with known eruptions and the remaining four considered to represent previously undocumented events. One deposit is suggested to correlate with the ~6.9 cal ka bp Lairg A tephra from Iceland, whereas more distant sources are proposed as the origin for two of the tephra deposits. A peak of colourless shards in early-Holocene sediments is thought to tentatively correlate with the ~9.6 cal ka bp Fondi di Baia tephra (Campi Flegrei) and a second cryptotephra is tentatively correlated with the ~3.6 cal ka bp Aniakchak (CFE) II tephra (Alaska). The Fondi di Baia tephra has never been recorded beyond proximal sites and its discovery in south Wales significantly extends the geographical distribution of ash from this eruption. The remaining four cryptotephra deposits are yet to be correlated with known eruptions, demonstrating that our current understanding of widespread tephra deposits is incomplete. This new tephra record highlights the potential for sites at more southerly and westerly locations in northwest Europe to act as repositories for ash from several volcanic regions.  相似文献   

Highly siderophile element and 187Re‐187Os isotopic systematics of ungrouped achondrite Northwest Africa 7325: Evidence for complex planetary processes     

Gregory J. Archer  Richard J. Walker  Anthony J. Irving 《Meteoritics & planetary science》2019,54(5):1042-1050

The abundances of highly siderophile elements (HSE; including Re, Os, Ir, Ru, Pt, and Pd) and ¹⁸⁷Re‐¹⁸⁷Os isotopic systematics were determined for two fragments from ungrouped achondrite NWA 7325. Rhenium‐Os systematics are consistent with closed‐system behavior since formation or soon after. The abundances of the HSE were therefore largely unaffected by late‐stage secondary processes such as shock or terrestrial weathering. As an olivine gabbro cumulate, this meteorite has a bulk composition consistent with derivation from a body that produced a core, mantle, and crust. Also consistent with derivation from a body that produced a core, both fragments of NWA 7325 have HSE abundances that are highly depleted compared to bulk chondrites. One fragment has ~0.002× CI chondrite Ir and relative HSE abundances similar to bulk chondrites. The other fragment has ~0.0002× CI chondrite Ir and relative HSE abundances that are fractionated compared to bulk chondrites. The chondritic relative HSE abundances of the fragment characterized by higher HSE abundances most likely reflect the addition of exogenous chondritic material during or after crystallization by surface impacts. The HSE in the other fragment is likely more representative of the parent body crust. One formation model that can broadly account for the HSE abundances in this fragment is multiple episodes of low‐pressure metal‐silicate equilibration, followed by limited late accretion and mantle homogenization. Given the different HSE compositions of the two adjoining fragments, this meteorite provides an example of the overprint of global processes (differentiation and late accretion) by localized impact contamination.  相似文献   

Wave diffraction and near-trapping by a multi-column gravity-based structure   总被引：1，自引：0，他引：1  

D.A.G. Walker  R. Eatock Taylor  P.H. Taylor  J. Zang   《Ocean Engineering》2008,35(2):201-229

This paper is concerned with the diffraction of water waves by offshore structures, with the ultimate aim of proposing tools for guiding airgap design. The diffraction of monochromatic waves by an array of four bottom mounted cylinders and a gravity-based structure is studied in detail using linear and second order theory. The phenomenon of near-trapping is investigated, allowing guidelines for airgap design to be established. When contemplating airgap design, however, it is crucially important that consideration is given to the largest waves in a sea state. Therefore, in this study a design wave, called NewWave, is proposed as a realistic model for large ocean waves and is used as the incident wave field in the wave-structure diffraction analysis.  相似文献   

Mapping and monitoring carbon stocks with satellite observations: a comparison of methods     

Scott J Goetz  Alessandro Baccini  Nadine T Laporte  Tracy Johns  Wayne Walker  Josef Kellndorfer  Richard A Houghton  Mindy Sun 《Carbon balance and management》2009,4(1):2-7

Mapping and monitoring carbon stocks in forested regions of the world, particularly the tropics, has attracted a great deal of attention in recent years as deforestation and forest degradation account for up to 30% of anthropogenic carbon emissions, and are now included in climate change negotiations. We review the potential for satellites to measure carbon stocks, specifically aboveground biomass (AGB), and provide an overview of a range of approaches that have been developed and used to map AGB across a diverse set of conditions and geographic areas. We provide a summary of types of remote sensing measurements relevant to mapping AGB, and assess the relative merits and limitations of each. We then provide an overview of traditional techniques of mapping AGB based on ascribing field measurements to vegetation or land cover type classes, and describe the merits and limitations of those relative to recent data mining algorithms used in the context of an approach based on direct utilization of remote sensing measurements, whether optical or lidar reflectance, or radar backscatter. We conclude that while satellite remote sensing has often been discounted as inadequate for the task, attempts to map AGB without satellite imagery are insufficient. Moreover, the direct remote sensing approach provided more coherent maps of AGB relative to traditional approaches. We demonstrate this with a case study focused on continental Africa and discuss the work in the context of reducing uncertainty for carbon monitoring and markets.  相似文献   

Natural aggregates in the performance and durability of concrete: chemical characteristics     

Peter G. Fookes  Mike J. Walker 《Geology Today》2012,28(1):20-25

This article continues from the earlier feature in Geology Today (2011, v.27, n.4) and looks at the influence of chemical reactivity within concrete due to the presence of unsound aggregates or deleterious material incorporated in the aggregate used in the concrete mix. Some of the more disruptive problems from chemical unsoundness come from the presence of chlorides, which cause rusting in reinforced concrete or, sulphate attack from ground waters. Both of these reactions are relatively common in Britain. Alkali–silica reactions with aggregates and cement is not too prevalent in Britain but can be very prevalent and disruptive elsewhere in the world.  相似文献   

Spongy pahoehoe in Hawaii: A study of vesicle-distribution patterns in basalt and their significance     

George P. L. Walker 《Bulletin of Volcanology》1989,51(3):199-209

A well-defined pahoehoe lava type that is very common medially and distally in Hawaii is characterized by a high concentration and fairly uniform distribution of spherical or near-spherical vesicles. Measurements of vesicle sizes and concentrations have been made on ten of these spongy pahoehoe lava flow-units. The vesicles increase in size toward the middle, accompanied by a moderate increase in lava porosity. The close approach to bilateral symmetry on either side of the horizontal median plane and the common occurrence of a median gas blister shows that no significant upward movement of vesicles occurred, suggesting that the lava possessed a yield strength and was more or less static. Olivine phenocrysts when present are, however, concentrated in the lower half of the same flow units, showing that the lava previously lacked a significant yield strength. The vesicles are regarded as early, inherited from the vent, but the size characteristics of the vesicle population are a late-formed feature. Vesicles grew in static lava mostly by coalescence, and it is postulated that coalescence was promoted by the presence of abundant diktytaxitic voids which punctured the walls of contiguous vesicles. Zones in which the vesicle concentration is lower and the vesicles are larger and strongly deformed interrupt the symmetry of some spongy pahoehoe units, and gas blisters higher than the median plane occur in many examples. These zones are interpreted to result from late-stage shearing, and point to a mechanism by which vesicles may be eliminated from a lava.  相似文献   

Recessional and Gulf war impacts on port development and shipping in the Gulf States in the 1980's     

Dr. A. R. Walker 《GeoJournal》1989,18(3):273-284

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Infrared spectroscopic investigation of hydroxyl in β-(Mg,Fe)2SiO4 and coexisting olivine: Implications for mantle evolution and dynamics     

Thomas E. Young  Harry W. Green II  Anne M. Hofmeister  David Walker 《Physics and Chemistry of Minerals》1993,19(6):409-422

Wadsleyite (β-(Mg,Fe)₂SiO₄) is a major constituent of the Earth's transition zone and is known to accommodate OH. The portion of the transition zone between 400–550 km could be an important source or sink for hydroxyl in plumes and slabs intersecting this region. Micro-infrared spectroscopy has been carried out on the β-phase and coexisting metastable olivine synthesized in a multianvil apparatus at 14 GPa and 1550–1650 K under hydrous conditions. Single-crystal and polycrystal specimens of both phases were analyzed in the 1800–8500 cm^?1 frequency region to determine the speciation, abundances, and partitioning behavior of the hydrous components in coexisting β-phase and olivine. β-phase spectra consistently show three distinct OH bands at 3329, 3580, and 3615 cm^?1. OH concentrations range from 10000–65000 H/10⁶ Si. A strong positive correlation of grain size and extent of transformation with OH concentration in the β-phase indicates that grain-growth and transformation rates are enhanced in a hydrous environment. Olivine spectra are variable, but consistently show a prominent broad-band absorbance representing molecular H₂O, consistent with the infrared signature of the starting material. OH concentrations in olivine range from <300–1400 H/10⁶ Si. The highest OH concentrations measured for olivine and the β-phase may represent solubility limits, in which case the OH solubility ratio between these two phases is approximately 1∶40. Where both phases coexist and are undersaturated with OH, the partitioning ratio of OH between them is about 1∶100. The large solubility contrast between olivine and the β-phase suggests a mechanism for hydrating the transition zone via olivine carried down in subducting slabs. Plumes impinging on an OH-rich upper transition region could cause H₂ or H₂O to be released upon transformation of the β-phase to olivine, resulting in initiation of secondary upwellings. If dissolution of OH weakens the β-phase, and if OH is present in the mantle, the region between 400–550 km could be a zone of low viscosity.  相似文献   

Book reviews     

Edward Theriot  Ian R. Walker 《Journal of Paleolimnology》1994,11(2):205-208

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Assessment of Pesticides in Upstate New York Ground Water: Results of a 1985-1987 Sampling Survey     

Mark J. Walker  Keith S. Porter 《Ground Water Monitoring & Remediation》1990,10(1):116-126

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