Decoding the complex internal chemical structure of garnet porphyroblasts from the Zermatt area,Western Alps   总被引：1，自引：0，他引：1  

Kurt Bucher  Tobias Bjrn Weisenberger  Oliver Klemm  Sebastian Weber 《Journal of Metamorphic Geology》2019,37(9):1151-1169

Garnet is a prototypical mineral in metamorphic rocks because it commonly preserves chemical and textural features that can be used for untangling its metamorphic development. Large garnet porphyroblasts may show extremely complex internal structures as a result of a polycyclic growth history, deformation, and modification of growth structures by intra‐ and intercrystalline diffusion. The complex internal structure of garnet porphyroblasts from garnet–phengite schists (GPS) of the Zermatt area (Western Alps) has been successfully decoded. The centimetre‐sized garnet porphyroblasts are composed of granulite facies garnet fragments overgrown by a younger generation of grossular‐rich eclogite facies garnet. The early granulite facies garnet (G‐Grt) formed from low‐P, high‐T metamorphism during a pre‐Alpine orogenic event. The late garnet (E‐Grt) is typical of high‐pressure, low‐temperature (HPLT) metamorphism and can be related to Alpine subduction of the schists. Thus, the garnet of the GPS are polycyclic (polymetamorphic). G‐Grt formation occurred at ~670 MPa and 780°C, E‐Grt formed at ~1.7 GPa and 530°C. The G‐Grt is relatively rich in Prp and poor in Grs, while E‐Grt is rich in Grs and poor in Prp. The Alm content (mol.%) of G‐Grt is 68 of E‐Grt 55. After formation of E‐Grt between and around fragmented G‐Grt at 530°C, the GPS have been further subducted and reached a maximum temperature of 580°C before exhumation started. Garnet composition profiles indicate that the initially very sharp contacts between the granulite facies fragments of G‐Grt and fracture seals of HPLT garnet (E‐Grt) have been modified by cation diffusion. The profiles suggest that Ca did not exchange at the scale of 1 µm, whereas Fe and Mg did efficiently diffuse at the derived maximum temperature of 580°C for the GPS at the scale of 7–8 µm. The Grt–Grt diffusion profiles resulted from spending c. 10 Ma at 530–580°C along the P–T–t path. The measured Grt composition profiles are consistent with diffusivities of log D_MgFe = ?25.8 m²/s from modelled diffusion profiles. Mg loss by diffusion from G‐Grt is compensated by Fe gain by diffusion from E‐Grt to maintain charge balance. This leads to a distinctive Fe concentration profile typical of uphill diffusion.  相似文献   

Effect of anorthite on granite phase relations: Experimental data and models   总被引：1，自引：1，他引：0  

Michel Pichavant  Catherine Weber  Arnaud Villaros 《Comptes Rendus Geoscience》2019,351(8):540-550

New experimental data on the effect of anorthite (An) on liquidus phase equilibria in the system Qz–Ab–Or are presented. The data were obtained for 5 wt% An added to variable Qz/Ab/Or compositions at 300 MPa and under H₂O-saturated conditions. Crystal–liquid equilibria were determined for 13 synthetic glass compositions made from gels in experiments performed between 660 and 750 °C in cold-seal pressure vessels. Forward and reversal experiments were systematically conducted on each composition to demonstrate equilibrium. A total of 51 charges was examined. Three crystalline phases, quartz, alkali feldspar and plagioclase appear on the H₂O-saturated liquidus surface. The determined minimum liquidus 5 wt% An “piercing” point (39% Qz, 33% Ab, 28% Or) is shifted away from the Ab apex toward the Qz–Or sideline when compared with the An-free 300 MPa H₂O-saturated minimum. This shift is of the same type as that observed at 100 MPa in the same system and at 200 MPa in a rhyolitic system. The new experimental results are used to test both empirical and thermodynamic models for silicic magmas. Empirical models reproduce reasonably well the new experimental data, although more sophisticated calculations schemes appear to be required to improve their accuracy. The new experimental results in the haplogranodiorite system are not well reproduced with the model of Holland and Powell (2001), mainly because plagioclase stability appears greatly enhanced in the model. Rhyolite-MELTS satisfactorily reproduces the Qz-, Pl- and Af-liquid phase equilibria, but model H₂O solubilities are significantly lower and crystallization temperatures higher than in experiments.  相似文献   

Element partitioning between magnesium silicate perovskite and ferropericlase: New insights into bulk lower-mantle geochemistry     

Anne-Line Auzende  James Badro  Frederick J. Ryerson  Peter K. Weber  Stewart J. Fallon  Ahmed Addad  Julien Siebert  Guillaume Fiquet   《Earth and Planetary Science Letters》2008,269(1-2):164-174

In this study, we investigated iron–magnesium exchange and transition-metal trace-element partitioning between magnesium silicate perovskite (Mg,Fe)SiO₃ and ferropericlase (Mg,Fe)O synthetised under lower-mantle conditions (up to 115 GPa and 2200 K) in a laser-heated diamond anvil cell. Recovered samples were thinned to electron transparency by focused ion beam and characterized by analytical transmission electron microscopy (ATEM) and nanometer-scale secondary ion mass spectroscopy (nanoSIMS). Iron concentrations in both phases were obtained from X-ray energy dispersive spectroscopy measurements and nanoSIMS. Our results are the first to show that recently reported spin-state and phase transitions in the lower mantle directly affect the evolution of Fe–Mg exchange between both phases. Mg-perovskite becomes increasingly iron-depleted above 70–80 GPa possibly due to the high spin–low spin transition of iron in ferropericlase. Conversely, the perovskite to post-perovskite transition is accompanied by a strong iron enrichment of the silicate phase, ferropericlase remaining in the Fe-rich phase though. Nanoparticles of metallic iron were observed in the perovskite-bearing runs, suggesting the disproportionation of ferrous iron oxide, but were not observed when the post-perovskite phase was present. Implications on the oxidation state of the Earth and core segregation will be discussed. Transition trace-element (Ni, Mn) concentrations (determined with the nanoSIMS) show similar trends and could thus be used to trace the origin of diamonds generated at depth. This study provides new results likely to improve the geochemical and geophysical models of the Earth's deep interiors.  相似文献   

Airborne Fungal Spores of Subalpine Zone of the Karkonosze and Izerskie Mountains （Poland）   总被引：4，自引：1，他引：3  

Wojciech PUSZ  Wlodzimierz KITA  Andrzej DANCEWICZ  Ryszard WEBER 《山地科学学报》2013,10(6):940-952

The incidence of the airborne fungal spores was determined in the air of subalpine zone of the Karkonosze Mountains and of the Izerskie Mountains in the borderland between Poland and the Czech Republic. The experiment was conducted in 2011 and 2012 at three to four week intervals from May to October. Air samples were taken from three locations in the Karkonosze Mts. and one from the Izerskie Mts. To examine the air, the Air Ideal 3P sampler and acidified PDA medium were used. The results show that Cladosporium cladosporioides was the most abundant spore type in all the sampling locations （up to 30%）, followed by Alternaria alternata （16%-20%）, Fusarium （up to 10%） and Sclerotinia sclerotiorium （up to 6%）. The lower spore counts were recorded in May samples, compared to the other months. In this case the snow cover, that was still present in the area at the beginning of May, may be the reason for the lower, compared to June, July and August samplings, CFU （Colony Forming Unit） counts in that month.. The influx of air masses from SE, S and SW sectors in the area under study may affect dissemination of the plant-pathogenic fungi from the Czech Republic and from the South of Europe in general.  相似文献   

The effect of climate change on extreme waves in front of the Dutch coast   总被引：1，自引：1，他引：0  

Renske C. de Winter  Andreas Sterl  Johannes W. de Vries  Susanne L. Weber  Gerben Ruessink 《Ocean Dynamics》2012,62(8):1139-1152

Coastal safety may be influenced by climate change, as changes in wave conditions (height, period, direction) may increase the vulnerability of dunes and other coastal defences. Dune erosion depends on mean water level, storm surge height and wave conditions. In this paper, we investigate the change in wave conditions in the North Sea in a changing climate. Until now, the effect of climate change on annual maximum wave conditions has been investigated, while events with higher return periods are actually most damaging for the coast (e.g. severe dune erosion). Here, we use the 17-member Ensemble SimulationS of Extreme weather under Non-linear Climate changeE (ESSENCE) change of climate change simulations, to analyse A1b-induced changes in the mean wave climate, the annual maxima and wave conditions with return periods of up to 1:10,000?years in front of the Dutch coast. The mean wave climate is not projected to differ between 1961–1990 and 2071–2100, with both wave height (H _s) and wave period (T _m) remaining unaltered. In the annual maximum conditions, a decrease is projected; especially, the annual T _m maximum decreases significantly by 0.3 to 0.6?s over the whole study area. Furthermore, we find that the direction of the annual maximum wave conditions shifts from north and north-west to west and south-west for both H _s and T _m. This is induced by a similar shift in the direction of the extreme wind speeds. Despite the decrease in annual maximum conditions, the return H _s and T _m are not projected to change significantly as a result of climate change in front of the Dutch coast for the period 2071–2100 relative to 1961–1990.  相似文献   

Effective elimination of subharmonic ghost events from vibroseis data     

M. Stiller  K.‐H. Jaeckel  M. Weber 《Geophysical Prospecting》2012,60(6):1095-1113

Harmonic or subharmonic noise is often present in vibroseis data as reverberation‐like, laterally coherent bands occurring parallel to and before or after, the main events. Such periodic noise is typically generated during the standard correlation process when the actual source signal travelling through the subsurface is, for whatever reason, different from the desired source signal, i.e., the pilot‐sweep controlling the baseplate and used for correlation. A typical cause can be that harmonic or subharmonic frequency partials are generated in addition to the vibroseis sweep's desired fundamental frequencies. These harmonics produce strong ‘ghost events’ during correlation of the geophone trace with the pilot‐sweep, originating from additional correlations between the fundamental and harmonic frequencies. Especially subharmonic ‘ghosts’ will overlap with ‘good’ fundamental signals, since for typically used up‐sweeps they are folded to later traveltimes, where the signal/noise‐ratio is already lower, thus aggravating or preventing a reliable interpretation of possible later reflections. Here, a method is introduced to remove these unwanted noise trains (with only negligible impact on the fundamental signal) by transforming the seismogram traces into a so‐called ‘(sub)harmonic domain’. In this domain, the respective harmonic noise portions are focused and separated from the fundamental signals, enabling easier detection and appropriate suppression. After back‐transformation to the x‐T domain, the records are free from the corresponding harmonic contamination and can then be processed as usual. The method operates in a data‐driven fashion, i.e., the traces are not uniformly processed but are processed depending upon their actual (sub)harmonic content. The decontamination procedure can be applied universally, i.e., to uncorrelated/correlated and/or vertically unstacked/stacked data either in a manual, semiautomated or fully automated manner. The method works perfectly for synthetic vibroseis traces with or without harmonic/subharmonic portions. The application to real, crustal‐scale vibroseis records that were acquired in 2006 in the Dead Sea region, Israel and that were severely contaminated by subharmonic ground‐roll ghosts covering reflectivity from the basement to the Moho, shows the robustness and success of the presented method.  相似文献   

Applied focused ion beam techniques for sample preparation of astromaterials for integrated nanoanalysis     

Giles A. Graham  Nick E. Teslich  Anton T. Kearsley  Frank J. Stadermann  Rhonda M. Stroud  Zurong Dai  Hope A. Ishii  Ian D. Hutcheon  Saša Bajt  Christopher J. Snead  Peter K. Weber  John P. Bradley 《Meteoritics & planetary science》2008,43(3):561-569

Abstract— Sample preparation is always a critical step in the study of micrometer‐sized astromaterials available for study in the laboratory, whether their subsequent analysis is by electron microscopy or secondary ion mass spectrometry. A focused beam of gallium ions has been used to prepare electron transparent sections from an interplanetary dust particle (IDP), as part of an integrated analysis protocol to maximize the mineralogical, elemental, isotopic, and spectroscopic information extracted from one individual particle. In addition, focused ion beam (FIB) techniques have been employed to extract cometary residue preserved on the rims and walls of microcraters in 1100 series aluminum foils that were wrapped around the sample tray assembly on the Stardust cometary sample collector. Non‐ideal surface geometries and inconveniently located regions of interest required creative solutions. These include support pillar construction and relocation of a significant portion of sample to access a region of interest. Serial sectioning, in a manner similar to ultramicrotomy, is a significant development and further demonstrates the unique capabilities of focused ion beam microscopy for sample preparation of astromaterials.  相似文献   

Mulit-ion plasmas in astrophysics     

E. J. Weber 《Astrophysics and Space Science》1973,20(2):401-415

An isothermal hydrodynamic model of the motions of a multi-ion plasma in a gravitational field is developed and the properties of the flow are discussed for the case of major astrophysical interest in which the gas undergoes a subsonic-supersonic transition. It is shown that the existence of critical points thorough which the plasma has to pass will determine a large number of the plasma parameters, especially the temperature of the minor ions. The equation of motion of a two ion gas (hydrogen-helium) are solved numerically and yield the interesting result that the bulk velocity of the plasma constituents are not equal at 1 AU.Operated by the Association of Universities for Research in Astronomy, under contract with the National Science Foundation.  相似文献   

Interplanetary baseline observations of type III solar radio bursts     

R. R. Weber  R. J. Fitzenreiter  J. C. Novaco  J. Fainberg 《Solar physics》1977,54(2):431-439

Simultaneous observations of type III radio bursts from spacecraft separated by 0.43 AU have been made using the solar orbiters HELIOS-A and HELIOS-B. The burst beginning at 19:22 UT on March 28, 1976 has been located from the intersection of the source directions measured at each spacecraft, and from burst arrival time differences. The source positions range from 0.03 AU from the Sun at 3000 kHz to 0.08 AU at 585 kHz. The electron density along the burst trajectory, and the exciter velocity (=0.13c) were determined directly, without the need to assume a density model as has been done with single-spacecraft observations. The separation of HELIOS-A and -B has also provided the first measurements of burst directivity at low frequencies. For the March 28 burst the intensity observed from near the source longitude (HELIOS-B) was 3–10 dB greater than that from 60° west of the source (HELIOS-A).  相似文献   

Mantle diversity beneath the Colombian Andes, Northern Volcanic Zone: Constraints from Sr and Nd isotopes     

A. Rodriguez-Vargas  E. Koester  G. Mallmann  R.V. Conceio  K. Kawashita  M.B.I. Weber 《Lithos》2005,82(3-4):471-484

In order to provide mantle and crustal constraints during the evolution of the Colombian Andes, Sr and Nd isotopic studies were performed in xenoliths from the Mercaderes region, Northern Volcanic Zone, Colombia. Xenoliths are found in the Granatifera Tuff, a deposit of Cenozoic age, in which mantle- and crustal-derived xenoliths are present in bombs and fragments of andesites and lamprophyres compositions. Garnet-bearing xenoliths are the most abundant mantle-derived rocks, but websterites (garnet-free xenoliths) and spinel-bearing peridotites are also present in minor amounts. Amphibolites, pyroxenites, granulites, and gneisses represent the lower crustal xenolith assemblage. Isotopic signatures for the mantle xenoliths, together with field, petrographic, mineral, and whole-rock chemistry and pressure–temperature estimates, suggest three main sources for these mantle xenoliths: garnet-free websterite xenoliths derived from a source region with low P and T (16 kbar, 1065 °C) and MORB isotopic signature, ⁸⁷Sr/⁸⁶Sr ratio of 0.7030, and ¹⁴³Nd/¹⁴⁴Nd ratio of 0.5129. Garnet-bearing peridotite and websterite xenoliths derived from two different sources in the mantle: i) a source with intermediate P and T (29–35 kbar, 1250–1295 °C) conditions, similar to that of sub-oceanic geotherm, with an OIB isotopic signature (⁸⁷Sr/⁸⁶Sr ratio of 0.7043 and ¹⁴³Nd/¹⁴⁴Nd ratio of 0.5129); and ii) another source with P and T conditions similar to those of a sub-continental geotherm (>38 kbar, 1140–1175 °C) and OIB isotopic characteristics (⁸⁷Sr/⁸⁶Sr ratio=0.7041 and ¹⁴³Nd/¹⁴⁴Nd ratio=0.5135).  相似文献