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61.
This paper studies the effects of sodium-based alkaline activators and class F fly ash on soil stabilisation. Using the unconfined compressive strength test (UCS), the effectiveness of this binder is compared with that of a common cement-based binder. Influence of the activator/ash ratio, sodium oxide/ash ratio and sodium hydroxide concentration was also analysed. Sodium hydroxide concentrations of 10, 12.5 and 15 molal were used for the alkaline-activated specimens (AA), with activator/ash ratios between 1 and 2.5 and ash percentages of 20, 30 and 40 %, relatively to the total solids (soil + ash). UCS was determined at curing periods of 7, 28, 90 and 365 days, and the most effective mixtures were analysed for mineralogy with XRD. The results showed a clear increase in strength with decreasing activator/ash ratio (up to a maximum of 43.4 MPa), which is a positive result since the activator is the most expensive component in the mixture. Finally, UCS results of the cement and AA samples, at 28 days curing, were very similar. However, AA results proved to be just between 20 and 40 % of the maximum UCS obtained at 1 year curing, while cement results at 28 days are expected to be between 80 and 90 % of its maximum.  相似文献   
62.
The growing search for clean and renewable energy sources has given rise to the studies of exploring sea wave energy. This paper is concerned with the numerical evaluation of the main operational principle of a submerged plate employed for the conversion of wave energy into electrical one. The numerical model used to solve the conservation equations of mass, momentum and transport of volume fraction is based on the finite volume method (FVM). In order to tackle with the flow of mixture of air-water and its interaction with the device, the multiphase model volume of fluid (VOF) is employed. The purpose of this study is the evaluation of a numerical model for improvement of the knowledge about the submerged plate wave energy converter, as well as the investigation of the effect of the distance from the plate to the bottom of the sea (HP) on the performance of the converter. The simulations for several distances of the plate from the seabed show that the optimal efficiency is 64%, which is obtained for HP=0.53 m (88% of the depth). This efficiency is 17% larger than that found in the worst case (HP=0.46 m, 77% of the depth).  相似文献   
63.
Invasive coral species of the genus Tubastraea have been increasingly recorded in Southwestern Atlantic waters since the 1980s. Their invasion and infestation are mainly related to port and oil exploration activities. For the first time the presence of Tubastraea tagusensis colonies is reported in Espírito Santo State, colonizing a port shore area, and incrusting oil/gas platform structures situated in the southern Abrolhos Bank, which is part of the most important coral reef system of the South Atlantic Ocean. Tubastraea colonies exhibit fast growth and high recruitment rates, and colonized 40% of the analyzed structures in just four years. The projection of port and oil/gas industry growth for the Espírito Santo State (more than 300%) highlights an alert to the dispersal of this alien species to natural areas.  相似文献   
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Spectral analysis of data noise is performed in the context of gravity field recovery from inter-satellite ranging measurements acquired by the satellite gravimetry mission GRACE. The motivation of the study is two-fold: (i) to promote a further improvement of GRACE data processing techniques and (ii) to assist designing GRACE follow-on missions. The analyzed noise realizations are produced as the difference between the actual GRACE inter-satellite range measurements and the predictions based on state-of-the-art force models. The exploited functional model is based on the so-called “range combinations,” which can be understood as a finite-difference analog of inter-satellite accelerations projected onto the line-of-sight connecting the satellites. It is shown that low-frequency noise is caused by limited accuracy of the computed GRACE orbits. In the first instance, it leads to an inaccurate estimation of the radial component of the inter-satellite velocities. A large impact of this component stems from the fact that it is directly related to centrifugal accelerations, which have to be taken into account when the measured range-accelerations are linked with inter-satellite accelerations. Another effect of orbit inaccuracies is a miscalculation of forces acting on the satellites (particularly, the one described by the zero-degree term of the Earth’s gravitational field). The major contributors to the noise budget at high frequencies (above 9?mHz) are (i) ranging sensor errors and (ii) limited knowledge of the Earth’s static gravity field at high degrees. Importantly, we show that updating the model of the static field on the basis of the available data must be performed with a caution as the result may not be physical due to a non-unique recovery of high-degree coefficients. The source of noise in the range of intermediate frequencies (1–9?mHz), which is particularly critical for an accurate gravity field recovery, is not fully understood yet. We show, however, that it cannot be explained by inaccuracies in background models of time-varying gravity field. It is stressed that most of the obtained results can be treated as sufficiently general (i.e., applicable in the context of a statistically optimal estimation based on any functional model).  相似文献   
65.
The Marifil Volcanic Complex, exposed in the eastern North Patagonian Massif, Argentina, includes up to 550 m of red conglomerates, sandstones, black siltstones, limestones, and reworked tuff of the Puesto Piris Formation. The basal part of this unit, which was deposited in high-gradient topographic relief, is composed of conglomerates and sandstones with thin layers of reworked tuffs. The lithofacies associations of the basal part indicate that the depositional mechanisms were mantled and gravitational flows.The middle part of the unit consists of fine sandstones, limestones, and black siltstones that were deposited in low-energy fluvial and lacustrine environments. The outcrops are located along the NEe SW direction and the major thickest units represented by limestones and siltstones, occur near the southeastern border of this NEeS W depocenter. Since the rhyolitic and trachytic lava flows and tuffs of the Marifil Volcanic Complex are interbedded with the sedimentary sequences of the Puesto Piris Formation,both units are coeval. Zircon Ue Pb age was obtained for a trachytic lava flow(193.4 ±3.1 Ma) suggesting that sedimentation and volcanism are Sinemurian. This extensional episode was recorded in the eastern,western, and southwestern sectors of the North Patagonian Massif, and is possibly associated with the Gondwana supercontinent breakup.  相似文献   
66.
In Brazil, intense coal exploitation activities have led to environmental deterioration, including soil mortification, water contamination, loss of ecosystem, and atmospheric contamination. In addition,considerable quantities of sulfur-rich residues are left behind in the mining area; these residues pose grave environmental issues as they undergo sulfide oxidation reactions. When sulfur oxides come in contact with water, extreme acid leachate is produced with great proportions of sulfate, and hazardous elements(HEs), which are identified as coal drainage(CMD). CMD is an environmental pollution challenge, particularly in countries with historic or active coal mines. To prevent CMD formation or its migration, the source must be controlled; however, this may not be feasible at many locations. In such scenarios, the mine water should be collected, treated, and discharged. In this study, data from 2005 to2010 was gathered on the geochemistry of 11 CMD discharges from ten different mines. There are several concerns and questions on the formation of nanominerals in mine acid drainage and on their reactions and interfaces. The detailed mineralogical and geochemical data presented in this paper were derived from previous studies on the coal mine areas in Brazil. Oxyhydroxides, sulfates, and nanoparticles in these areas possibly go through structural transformations depending on their size and formation conditions. The geochemistry of Fe-precipitates(such as jarosite, goethite, and hematite) existent in the CMD-generating coal areas and those that could be considered as a potential source of hazardous elements(HEs)(e.g., Cr) were also studied because these precipitates are relatively stable in extremely low pH conditions. To simplify and improve poorly ordered iron, strontium, and aluminum phase characterization, field emission scanning electron microscopy(FE-SEM), high-resolution transmission electron microscopy(HR-TEM), micro-Raman spectroscopy, and X-ray diffraction(XRD) and sequential extraction(SE) studies were executed on a set CMD samples from the Brazilian mines. This study aimed to investigate the role of both nanomineral and amorphous phase distribution throughout the reactive coal cleaning rejects profile and HEs removal from the water mine to provide holistic insights on the ecological risks posed by HEs, nanominerals, amorphous phases, and to assess sediments in complex environments such as estuaries.  相似文献   
67.
Maximum Entropy Spectral Analysis of the annual rainfall series for 1887–1976 (90 years) for Massachusetts (northeastern USA.) shows T = 17.8 (very near the 18.6 year luni-solar signal) as the most prominent periodicity. However, it explains only 12% variance. Also, the next prominent periodicity is T = 2.72 years, i.e. in the QBO (Quasi-Biennial Oscillation, T = 2–3 years) region. Also, regular periodicities account for only 50% variance, leaving 50% as a random component. Hence, predictions are unreliable. Roughly, excess rainfall during 1990–1994 and droughts during 1992–2002 are indicated; but occasional years of opposite behavior cannot be ruled out.  相似文献   
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In the Cubatão region, southern Brazil, sediments are transported by several rivers from the Serra do Mar Ridge into the Santos estuary. Fertilizer plants have been operating along the margins of one of these rivers (Mogi River) producing a large volume of phosphogypsum, which is stockpiled in nearby areas. Surface sediments of the Mogi River were sampled upstream and downstream in relation to the point where the effluents of the phosphogypsum piles flow into the drainage system. In the vicinity of this point one sediment core was collected. Results show that REE, Ba, Zr and Th concentrations in the non-contaminated sediments are of the same order as those present in the upper continental crust. The contaminated samples present a composition affected by that of the phosphogypsum, marked by a higher concentration of these elements and a stronger degree of REE fractionation. These phosphogypsum characteristics are inherited from the Catalão igneous phosphate ore and were moderately modified by the industrial process of phosphoric acid production. The phosphogypsum signal decreases rapidly downstream, pointing to a limited area of influence of the stacks. The deepest sediments of the core are also free of contamination, representing a time interval prior to the deposition of phosphogypsum wastes on the banks of the estuary.  相似文献   
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