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651.
The estimation of recharge through groundwater model calibration is hampered by the nonuniqueness of recharge and aquifer parameter values. It has been shown recently that the estimability of spatially distributed recharge through calibration of steady‐state models for practical situations (i.e., real‐world, field‐scale aquifer settings) is limited by the need for excessive amounts of hydraulic‐parameter and groundwater‐level data. However, the extent to which temporal recharge variability can be informed through transient model calibration, which involves larger water‐level datasets, but requires the additional consideration of storage parameters, is presently unknown for practical situations. In this study, time‐varying recharge estimates, inferred through calibration of a field‐scale highly parameterized groundwater model, are systematically investigated subject to changes in (1) the degree to which hydraulic parameters including hydraulic conductivity (K) and specific yield (Sy) are constrained, (2) the number of water‐level calibration targets, and (3) the temporal resolution (up to monthly time steps) at which recharge is estimated. The analysis involves the use of a synthetic reality (a reference model) based on a groundwater model of Uley South Basin, South Australia. Identifiability statistics are used to evaluate the ability of recharge and hydraulic parameters to be estimated uniquely. Results show that reasonable estimates of monthly recharge (<30% recharge root‐mean‐squared error) require a considerable amount of transient water‐level data, and that the spatial distribution of K is known. Joint estimation of recharge, Sy and K, however, precludes reasonable inference of recharge and hydraulic parameter values. We conclude that the estimation of temporal recharge variability through calibration may be impractical for real‐world settings. 相似文献
652.
Svetlana S. Kostrova Hanno Meyer Francisco Fernandoy Martin Werner Pavel E. Tarasov 《水文研究》2020,34(1):51-67
The paper presents oxygen and hydrogen isotopes of 284 precipitation event samples systematically collected in Irkutsk, in the Baikal region (southeast Siberia), between June 2011 and April 2017. This is the first high-resolution dataset of stable isotopes of precipitation from this poorly studied region of continental Asia, which has a high potential for isotope-based palaeoclimate research. The dataset revealed distinct seasonal variations: relatively high δ18O (up to −4‰) and δD (up to −40‰) values characterize summer air masses, and lighter isotope composition (−41‰ for δ18O and −322‰ for δD) is characteristic of winter precipitation. Our results show that air temperature mainly affects the isotope composition of precipitation, and no significant correlations were obtained for precipitation amount and relative humidity. A new temperature dependence was established for weighted mean monthly precipitation: +0.50‰/°C (r2 = 0.83; p <.01; n = 55) for δ18O and +3.8‰/°C (r2 = 0.83, p < 0.01; n = 55) for δD. Secondary fractionation processes (e.g., contribution of recycled moisture) were identified mainly in summer from low d excess. Backward trajectories assessed with the Hybrid Single-Particle Lagrangian Integrated Trajectory (HYSPLIT) model indicate that precipitation with the lowest mean δ18O and δD values reaches Irkutsk in winter related to moisture transport from the Arctic. Precipitation originating from the west/southwest with the heaviest mean isotope composition reaches Irkutsk in summer, thus representing moisture transport across Eurasia. Generally, moisture transport from the west, that is, the Atlantic Ocean predominates throughout the year. A comparison of our new isotope dataset with simulation results using the European Centre/Hamburg version 5 (ECHAM5)-wiso climate model reveals a good agreement of variations in δ18O (r2 = 0.87; p <.01; n = 55) and air temperature (r2 = 0.99; p <.01; n = 71). However, the ECHAM5-wiso model fails to capture observed variations in d excess (r2 = 0.14; p < 0.01; n = 55). This disagreement can be partly explained by a model deficit of capturing regional hydrological processes associated with secondary moisture supply in summer. 相似文献
653.
Jutta Jahnel Christian Zwiener Thomas J. Gremm Gudrun Abbt‐Braun Fritz H. Frimmel Carola Kussatz Dieter Schudoma Werner Rocker 《洁净——土壤、空气、水》2001,29(4):246-253
Quality Targets for Pesticides and Other Pollutants in Surface Waters Surface waters are not only adversely affected by industrial and municipal wastewaters but also by diffuse sources. For the control of the ecological water quality, so‐called quality targets are set. The quality targets are threshold concentrations for hazardous substances related to the protected goods like water ecosystems, drinking water supply, sediments, or fishing. In this paper, quality targets for the protection of aquatic life in surface waters were derived on the basis of a concept developed by the International Commission for the Protection of the Rhine (Internationale Kommission zum Schutze des Rheins – IKSR). The quality targets for the selected hazardous substances, which mainly belong to the chemical class of pesticides, were calculated using ecotoxicological results for species of bacteria, algae, fish, and small crustaceans, as the four trophic standards of the water ecosystem. In cooperation with the Federal Environmental Agency (Umweltbundesamt – UBA) the effect data were taken from ecotoxicological data bases. According to the concept of the IKSR, the lowest test result for the most sensitive species was multiplied by an assessment factor. This proceeding concerns the difficulty in describing the complex interactions in water ecosystems with toxicity data of single laboratory experiments for a few organisms. For seven pesticides quality targets below 0.1 μg/L were proposed. These results show that the ecotoxicologically based quality targets might be even lower than the limit values for pesticides in drinking water of 0.1 μg/L. But for most of the substances the determined values are significantly higher. The great concentration range of quality targets demonstrates distinctly that one standard concentration for all pesticides could not be given with regard to the different effects on aquatic organisms. 相似文献