Automated Extraction of a Five‐Year LA‐ICP‐MS Trace Element Data Set of Ten Common Glass and Carbonate Reference Materials: Long‐Term Data Quality,Optimisation and Laser Cell Homogeneity          下载免费PDF全文

David Evans  Wolfgang Müller 《Geostandards and Geoanalytical Research》2018,42(2):159-188

LA‐ICP‐MS is increasingly applied to obtain quantitative multi‐element data with minimal sample preparation, usually achieved by calibration using reference materials (RMs). However, some ubiquitous RMs, for example the NIST SRM 61× series glasses, suffer from reported value uncertainties for certain elements. Moreover, no long‐term data set of analyses conducted over a range of ablation and tuning conditions exists. Thus, there has been little rigorous examination of the extent to which offsets between measured and reported values are the result of error in these values rather than analytically induced fractionation. We present new software (‘LA‐MINE’), capable of extracting LA‐ICP‐MS data with no user input, and apply this to our system, yielding over 5 years of data (~ 5700 analyses of ten glass and carbonate RMs). We examine the relative importance of systematic analytical bias and possible error in reported values through a mass‐specific breakdown of fourteen of the most commonly determined elements. Furthermore, these data, obtained under a wide range of different ablation conditions, enable specific recommendations of how data quality may be improved, for example the role of diatomic gas, the effect of differential inter‐glass fractionation factors and choice of transport tubing material. Finally, these data demonstrate that the two‐volume Laurin ablation cell is characterised by no discernible spatial heterogeneity in measured trace element ratios.  相似文献   

Satellite estimates and subpixel variability of rainfall in a semi-arid grassland          下载免费PDF全文

Yong Chen  Jing Duan  Junling An  Huizhi Liu  Ulrich G?rsdorf  Franz H.Berger 《大气和海洋科学快报》2021,14(5):24-29

卫星估雨精度的不确定性受到当地降雨类型和像元内降雨非均匀性影响,而结合这两个关键因素开展半干旱草原卫星估雨的研究有限.2009年夏,我们在中国锡林郭勒半干旱草原用多部微雨雷达和雨量计构建了9 km卫星像元降雨观测网,观测了像元内降雨非均匀性(空间变异系数CV),并评估了卫星估雨精度.结果表明:(1)CV值受像元内平均降雨量,降雨类型,降雨云面积及移向等影响,如高Cv值的降雨过程大多为平均降雨量小,对流性降雨过程,降雨云边缘像元CV值较高;(2)TRMM 3B42V7卫星估雨产品适用性较好,CMORPH和PERSIANN次之,但TRMM 3B42V7易在半干旱草原湖泊处高估降雨.  相似文献   

The Austrian node of the natural resources satellite remote sensing cloud service platform:examples of Sino-Austrian cooperation     

Wolfgang Kainz  Xinming Tang  Yucai Xue 《地球空间信息科学学报》2021,24(1):145-151

The Austrian node of the Natural Resources Satellite Remote Sensing Cloud Service Platform was established in 2016 through a cooperation agreement between the Land Satellite Remote Sensing Application Center(LASAC),Ministry of Natural Resources of the Peoples Republic of China and the University of Vienna,Austria.Under this agreement panchromatic and multi-spectral data of the Chinese ZY-3 satellite are pushed to the server at the University of Vienna for use in education and research.So far,nearly 500 GB of data have been uploaded to the server.This technical note briefly introduces the ZY-3 system and illustrates the implementation of the agreement by the first China-Sat Workshop and several case studies.Some of them are already completed,others are still ongoing.They include a geometric accuracy validation of ZY-3 data,an animated visualization of image quick views on a spherical display to demonstrate the time series of the image coverage for Austria and Laos,and the use of ZY-3 data to study the spread of bark beetle in the province of Lower Austria.An accuracy study of DTMs from ZY-3 stereo data,as well as a land cover analysis and comparison of Austria with ZY-3 and other sensors are still ongoing.  相似文献   

FELLNER,WOLF-DIETRICH: Computer-Grafik. Reihe lnformatik Bd. 58, BI-Wissenschafisverlag Mannheim,Wien, Zurich, 1988, 400 Seiten, 184 Abbildungen,Preis: DM 48,- ISBN 3-411-03179-4     

Wolfgang Mai 《Astronomische Nachrichten》1990,311(4):264-264

  相似文献   

Magnetic Helicity as a Predictor of the Solar Cycle     

G. Hawkes  M. A. Berger 《Solar physics》2018,293(7):109

It is well known that the polar magnetic field is at its maximum during solar minima, and that the behaviour during this time acts as a strong predictor of the strength of the following solar cycle. This relationship relies on the action of differential rotation (the Omega effect) on the poloidal field, which generates the toroidal flux observed in sunspots and active regions. We measure the helicity flux into both the northern and the southern hemispheres using a model that takes account of the Omega effect, which we apply to data sets covering a total of 60 years. We find that the helicity flux offers a strong prediction of solar activity up to five years in advance of the next solar cycle. We also hazard an early guess as to the strength of Solar Cycle 25, which we believe will be of similar amplitude and strength to Cycle 24.  相似文献   

Extension of the Paraná Basin to offshore Brazil: Implications for coalbed methane evaluation     

Michael Holz  Wolfgang Kalkreuth  Silvia Beatriz Alves Rolim 《Marine and Petroleum Geology》2010

Coalbed methane (CBM) is a worldwide exploration target of the petroleum industry. In Brazil, the most important coal-bearing succession is associated with the Permian Rio Bonito Formation of the Paraná Basin. The gas-prone areas are located at the southeastern margin of the Paraná Basin and possibly in the offshore region of the northern part of the Pelotas Basin. Coalfields end abruptly at the present day shoreline, a result of rifting of Gondwana and the evolution of the South Atlantic Ocean. All geologic indicators suggest that in pre-rift times the coal seams extended further eastwards, probably now lying deeply buried below the sedimentary succession of the Pelotas Basin. The present paper discusses structural, stratigraphic, seismic and aeromagenetic data that support the preservation of continental crust beneath ocean sediment. If the coal beds had similar lateral extent to known onshore coals, and coal beds extended across the projected extension of the Parana basin, and there was a conservative 5 m of cumulative coal thickness, then a potential methane volume can be estimated for this newly inferred resource. Average onshore coal gas content is 32 scf/ton (1.00 m³/ton). If this is similar in the offshore coal deposits, then the hypothetical methane volume in the offshore area could be in excess of 1.9 × 10¹² scf (56 × 10⁹ m³). Metamorphism from dikes associated with rifting are potential complicating factors in these deposits, and since no borehole reaching the deep-lying strata in the offshore area are available, this is a hypothetical gas resource with a certain level of uncertainty which should be tested in the future by drilling a deep borehole.  相似文献   

Leachable particulate iron in the Columbia River,estuary, and near-field plume     

Sherry M. Lippiatt  Matthew T. Brown  Maeve C. Lohan  Carolyn J.M. Berger  Kenneth W. Bruland 《Estuarine, Coastal and Shelf Science》2010

This study examines the distribution of leachable particulate iron (Fe) in the Columbia River, estuary, and near-field plume. Surface samples were collected during late spring and summer of 2004–2006 as part of four River Influence on Shelf Ecosystems (RISE) cruises. Tidal amplitude and river flow are the primary factors influencing the estuary leachable particulate Fe concentrations, with greater values during high flow and/or spring tides. Near the mouth of the estuary, leachable particulate Fe [defined as the particulate Fe solubilized with a 25% acetic acid (pH 2) leach containing a weak reducing agent to reduce Fe oxyhydroxides and a short heating step to access intracellular Fe] averaged 770 nM during either spring tide or high flow, compared to 320 nM during neap tide, low flow conditions. In the near-field Columbia River plume, elevated leachable particulate Fe concentrations occur during spring tides and/or higher river flow, with resuspended shelf sediment as an additional source to the plume during periods of coastal upwelling and spring tides. Near-field plume concentrations of leachable particulate Fe (at a salinity of 20) averaged 660 nM during either spring tide or high flow, compared to 300 nM during neap tide, low flow conditions. Regardless of tidal amplitude and river flow, leachable particulate Fe concentrations in both the river/estuary and near-field plume are consistently one to two orders of magnitude greater than dissolved Fe concentrations. The Columbia River is an important source of reactive Fe to the productive coastal waters off Oregon and Washington, and leachable particulate Fe is available for solubilization following biological drawdown of the dissolved phase. Elevated leachable Fe concentrations allow coastal waters influenced by the Columbia River plume to remain Fe-replete and support phytoplankton production during the spring and summer seasons.  相似文献   

Final Stages of Stellar Evolution and Nucleosynthesis: What do We Know and What Would We Like to Know?     

Wolfgang Hillebrandt 《Astrophysics and Space Science》2002,281(1-2):173-182

Recent developments in theoretical model-calculations for the synthesis of the chemical elements during late stages of stellar evolution are reviewed. Special emphasis is put on a discussion of various astrophysical sites, including core-collapse and thermonuclear supernovae, and the physics of turbulent reactive fluids. Results of numerical simulations are presented and discussed, together with new results concerning solar-system abundances as well as abundances observed in very metal-poor stars, in the context of searches for constraints on the still rather uncertain nuclear physics data and astrophysical models. This revised version was published online in September 2006 with corrections to the Cover Date.  相似文献   

Mineralogy,petrology, chronology,and exposure history of the Chelyabinsk meteorite and parent body          下载免费PDF全文

K. Righter  P. Abell  D. Agresti  E. L. Berger  A. S. Burton  J. S. Delaney  M. D. Fries  E. K. Gibson  M. K. Haba  R. Harrington  G. F. Herzog  L. P. Keller  D. Locke  F. N. Lindsay  T. J. McCoy  R. V. Morris  K. Nagao  K. Nakamura‐Messenger  P. B. Niles  L. E. Nyquist  J. Park  Z. X. Peng  C.‐Y. Shih  J. I. Simon  C. C. Swisher III  M. J. Tappa  B. D. Turrin  R. A. Zeigler 《Meteoritics & planetary science》2015,50(10):1790-1819

Three masses of the Chelyabinsk meteorite have been studied with a wide range of analytical techniques to understand the mineralogical variation and thermal history of the Chelyabinsk parent body. The samples exhibit little to no postentry oxidation via Mössbauer and Raman spectroscopy indicating their fresh character, but despite the rapid collection and care of handling some low levels of terrestrial contamination did nonetheless result. Detailed studies show three distinct lithologies, indicative of a genomict breccia. A light‐colored lithology is LL5 material that has experienced thermal metamorphism and subsequent shock at levels near S4. The second lithology is a shock‐darkened LL5 material in which the darkening is caused by melt and metal‐troilite veins along grain boundaries. The third lithology is an impact melt breccia that formed at high temperatures (~1600 °C), and it experienced rapid cooling and degassing of S₂ gas. Portions of light and dark lithologies from Chel‐101, and the impact melt breccias (Chel‐102 and Chel‐103) were prepared and analyzed for Rb‐Sr, Sm‐Nd, and Ar‐Ar dating. When combined with results from other studies and chronometers, at least eight impact events (e.g., ~4.53 Ga, ~4.45 Ga, ~3.73 Ga, ~2.81 Ga, ~1.46 Ga, ~852 Ma, ~312 Ma, and ~27 Ma) are clearly identified for Chelyabinsk, indicating a complex history of impacts and heating events. Finally, noble gases yield young cosmic ray exposure ages, near 1 Ma. These young ages, together with the absence of measurable cosmogenic derived Sm and Cr, indicate that Chelyabinsk may have been derived from a recent breakup event on an NEO of LL chondrite composition.  相似文献   

One‐dimensional dynamics of saturated incompressible porous media: analytical solutions and influence of inertia terms          下载免费PDF全文

Yunpeng Zhang  Dorival M. Pedroso  Wolfgang Ehlers 《国际地质力学数值与分析法杂志》2016,40(18):2489-2513

The complexity of formulations for the hydromechanical coupled mechanics of porous media is typically minimised by simplifying assumptions such as neglecting the effect of inertia terms. For example, three formulations commonly employed to model practical problems are classified as fully dynamic, simplified dynamic and quasi‐static. Thus, depending on the porous media conditions, each formulation will have advantages and limitations. This paper presents a comprehensive analysis of these limitations when solving one‐dimensional fully saturated porous media problems in addition to a new solution that considers a more general loading situation. A phase diagram is developed to assist on the selection of which formulation is more appropriate and convenient regarding particular cases of porosity and hydraulic conductivity values. Non‐dimensional formulations are proposed to achieve this goal. Results using the analytical solutions are compared against numerical values obtained with the finite element method, and the effect of porosity is investigated. Copyright © 2016 John Wiley & Sons, Ltd.  相似文献