Ablation Characteristic of Ilmenite using UV Nanosecond and Femtosecond Lasers: Implications for Non‐Matrix‐Matched Quantification          下载免费PDF全文

Zhen Li  Zhaochu Hu  Detlef Günther  Keqing Zong  Yongsheng Liu  Tao Luo  Wen Zhang  Shan Gao  Shenghong Hu 《Geostandards and Geoanalytical Research》2016,40(4):477-491

Ilmenite (FeTiO₃) is a common accessory mineral and has been used as a powerful petrogenetic indicator in many geological settings. Elemental fractionation and matrix effects in ilmenite (CRN63E‐K) and silicate glass (NIST SRM 610) were investigated using 193 nm ArF excimer nanosecond (ns) laser and 257 nm femtosecond (fs) laser ablation systems coupled to an inductively coupled plasma‐mass spectrometer. The concentration‐normalised ⁵⁷Fe and ⁴⁹Ti responses in ilmenite were higher than those in NIST SRM 610 by a factor of 1.8 using fs‐LA. Compared with the 193 nm excimer laser, smaller elemental fractionation was observed using the 257 nm fs laser. When using 193 nm excimer laser ablation, the selected range of the laser energy density had a significant effect on the elemental fractionation in ilmenite. Scanning electron microscopy images of ablation craters and the morphologies of the deposited aerosol materials showed more melting effects and an enlarged particle deposition area around the ablation site of the ns‐LA‐generated crater when compared with those using fs‐LA. The ejected material around the ns crater predominantly consisted of large droplets of resolidified molten material; however, the ejected material around the fs crater consisted of agglomerates of fine particles with ‘rough' shapes. These observations are a result of the different ablation mechanisms for ns‐ and fs‐LAs. Non‐matrix‐matched calibration was applied for the analysis of ilmenite samples using NIST SRM 610 as a reference material for both 193 nm excimer LA‐ICP‐MS and fs‐LA‐ICP‐MS. Similar analytical results for most elements in ilmenite samples were obtained using both 193 nm excimer LA‐ICP‐MS at a high laser energy density of 12.7 J cm^?2 and fs‐LA‐ICP‐MS.  相似文献   

Self-organized criticality of significant fording landslides in Three Gorges Reservoir area,China     

Fei Guo  Zujiang Luo  Huizhong Li  Shimei Wang 《Environmental Earth Sciences》2016,75(7):607

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Impacts of anthropogenic activities on weathering and carbon fluxes: a case study in the Xijiang River basin,southwest China   总被引：1，自引：0，他引：1  

Shi Yu  Shiyi He  Ping’an Sun  Junbing Pu  Jie Huang  Huixian Luo  Yongshan Li  Rui Li  Yaqiong Yuan 《Environmental Earth Sciences》2016,75(7):589

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Identifying structure and function of karst aquifer system using multiple field methods in karst trough valley area,South China   总被引：1，自引：0，他引：1  

Mingming Luo  Zhihua Chen  Hong Zhou  Hamza Jakada  Liang Zhang  Zhaofeng Han  Tingting Shi 《Environmental Earth Sciences》2016,75(9):824

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Study on biological degradation and transform characteristics of different components in petroleum hydrocarbon used by bacterial consortium     

Lihua Chen  Chaohu Xiao  Xiaofang Luo  Wanhong Sun 《Environmental Earth Sciences》2016,75(9):816

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Geochemistry of geothermal waters from the Gonghe region,Northwestern China: implications for identification of the heat source     

Mingliang Liu  Qinghai Guo  Xiaobo Zhang  Jin Luo  Jiexiang Li  Chao Zhou  Wei Guo  Canhai Zhang  Mingcheng Zhu 《Environmental Earth Sciences》2016,75(8):682

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Theoretical calculation of equilibrium Mg isotope fractionation between silicate melt and its vapor     

Haiyang Luo  Huiming Bao  Yuhong Yang  Yun Liu 《中国地球化学学报》2018,37(5):655-662

Isotope fractionation during the evaporation of silicate melt and condensation of vapor has been widely used to explain various isotope signals observed in lunar soils, cosmic spherules, calcium–aluminum-rich inclusions, and bulk compositions of planetary materials. During evaporation and condensation, the equilibrium isotope fractionation factor (α) between high-temperature silicate melt and vapor is a fundamental parameter that can constrain the melt’s isotopic compositions. However, equilibrium α is difficult to calibrate experimentally. Here we used Mg as an example and calculated equilibrium Mg isotope fractionation in MgSiO₃ and Mg₂SiO₄ melt–vapor systems based on first-principles molecular dynamics and the high-temperature approximation of the Bigeleisen–Mayer equation. We found that, at 2500 K, δ²⁵Mg values in the MgSiO₃ and Mg₂SiO₄ melts were 0.141?±?0.004 and 0.143?±?0.003‰ more positive than in their respective vapors. The corresponding δ²⁶Mg values were 0.270?±?0.008 and 0.274?±?0.006‰ more positive than in vapors, respectively. The general \(\alpha - T\) equations describing the equilibrium Mg α in MgSiO₃ and Mg₂SiO₄ melt–vapor systems were: \(\alpha_{{{\text{Mg}}\left( {\text{l}} \right) - {\text{Mg}}\left( {\text{g}} \right)}} = 1 + \frac{{5.264 \times 10^{5} }}{{T^{2} }}\left( {\frac{1}{m} - \frac{1}{{m^{\prime}}}} \right)\) and \(\alpha_{{{\text{Mg}}\left( {\text{l}} \right) - {\text{Mg}}\left( {\text{g}} \right)}} = 1 + \frac{{5.340 \times 10^{5} }}{{T^{2} }}\left( {\frac{1}{m} - \frac{1}{{m^{\prime}}}} \right)\), respectively, where m is the mass of light isotope ²⁴Mg and m′ is the mass of the heavier isotope, ²⁵Mg or ²⁶Mg. These results offer a necessary parameter for mechanistic understanding of Mg isotope fractionation during evaporation and condensation that commonly occurs during the early stages of planetary formation and evolution.  相似文献   

U–Pb zircon age of the base of the Ediacaran System at the southern margin of the Qinling Orogen     

Lecai Xing  Taiyi Luo  Zhilong Huang  Zhikuan Qian  Mingzhong Zhou  Hongtao He 《中国地球化学学报》2018,37(3):414-421

Global abrupt climate change from Marinoan snowball Earth to greenhouse Earth, recorded as cap carbonate overlain on diamictite, had shed the first light on Cambrian bio-radiation. The most documented cap carbonate sections are typical with comprehensive δ¹³C negative values and ubiquitous sedimentary structures, such as tepee-like, sheet-crack etc., which are associated with successive glacial eustatic variation caused by isostatic rebound in shallow-water facies. Here we report a deep-water basinal cap carbonate section with strong negative δ¹³C values in the southern margin of the Qinling Orogen, Heyu, Chengkou County, Chongqing in China, which consists of massive dolostone with abundant carbonaceous laminae. However, it lacks the sedimentary structure as mentioned above and is overlain by thin-bedded silicious shales and cherts. A K-bentonite bed was discovered within the base of cap carbonates, about 0.7 m above the top of the Marinoan diamictite. Magmatic zircons that were separated from the K-bentonite bed yield a SIMS concordia U–Pb age of 634.1 ± 1.9 Ma (1σ, MSWD_CE = 0.31, Probability_CE = 1.000, n = 20). The age is in good agreement with previously reported TIMS U–Pb ages for the termination of Marinoan glaciation and provides a geochronological constraint for the Ediacaran successions in the Qinling Orogen.  相似文献   

Effects of a proline solution cover on the geochemical and mineralogical characteristics of high-sulfur coal gangue     

Youfa Luo  Yonggui Wu  Tianling Fu  Hu Wang  Rongrong Xing  Zhilin Zheng 《中国地球化学学报》2018,37(5):701-714

Batch experiments were conducted to comparatively evaluate the inhibition effects and mechanisms of a low-concentration (1%) proline solution cover on the release of pollutants from high-sulfur coal gangue. High-sulfur coal gangue was continuously immersed in a proline solution and in deionized water (as a control treatment) for 540 days. The results showed that the coal gangue in the control treatment was oxidized and generated leachate with poor water qualities, i.e., the leachate exhibited lower pH values, higher redox potential values, higher pollutant concentrations (SO₄^2?, Fe, Mn, Cu, and Zn), and high levels of acidophilic sulfur-oxidizing bacteria. However, compared to the control treatment, the addition of the proline solution (1%) significantly improved the water quality of the leachate by significantly reducing the Eh values, the pollutant concentrations (SO₄^2?, Fe²⁺, Fe, Mn, Cu, and Zn), and the activity of acidophilic sulfur-oxidizing bacteria and by significantly increasing the pH value to neutral. The proline treatment significantly inhibited the oxidation of coal gangue and the release of pollutants, mainly by inhibiting the activity of acidophilic sulfur-oxidizing bacteria and by altering the heavy metal fractions and the mineralogical characteristics. Therefore, in engineering practice, workers should consider using an environmental friendly aqueous proline solution cover to achieve the in-situ control of pollutant releases from coal gangue dumps.  相似文献   

Identification and determination of the boundary between the Cathaysian and Yangtze blocks: a preliminary understanding of gravity and magnetic fields     

Jiayong Yan  Kun Zhang  Guangming Fu  Fan Luo  Hao Wang  Guang Qi 《《地质学报》英文版》2018,92(Z1):222-225

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