Identification of Pb sources in Yellow Sea sediments using stable Pb isotope ratios   总被引：1，自引：0，他引：1  

Man-Sik Choi  Hi-Il Yi  Shou Ye Yang  Chang-Bok Lee  Hyun-Ju Cha 《Marine Chemistry》2007

Rapid economic developments in East Asian countries have inevitably resulted in environmental degradation in the surrounding seas, and concern for both the environment and protection from pollutants is increasing. Identification of sources of contaminants is essential to environmental pollution management. In this study, the provenance of anthropogenic lead (Pb), a major pollutant of Yellow Sea sediments, was determined for river mouth sediments, including those of the Changjiang, Huanghe, Han, and Geum Rivers, and for age-determined shelf core sediments through the measurement of Pb isotope ratios in the HCl-leached fraction using multi-collector inductively coupled plasma-mass spectrometry (MC ICP/MS). Anthropogenic Pb has accumulated in shelf core sediments since 1910, and its isotope ratios were estimated as 0.863–0.866 and 2.119–2.125 for ²⁰⁷Pb/²⁰⁶Pb and ²⁰⁸Pb/²⁰⁶Pb, respectively, from the mixing relationships of the two endmembers. River mouth sediments exhibited enough distinction in anthropogenic Pb isotope ratios to be discriminated: 0.874 (2.144) in the Huanghe, 0.856 (2.129) in the Han, 0.857 (2.122) in the Geum, and 0.854 (2.101) in the Changjiang for ²⁰⁷Pb/²⁰⁶Pb (²⁰⁸Pb/²⁰⁶Pb), respectively. Although isotope ratios of geogenic Pb in sediments dating before 1910 showed narrow ranges (0.842–0.845 and 2.088–2.100 for ²⁰⁷Pb/²⁰⁶Pb and ²⁰⁸Pb/²⁰⁶Pb, respectively), distinct isotope ratios in each core permitted source identification of sediments in the Yellow Sea based on geographic locations and the geogenic Pb of each river. By comparing the isotope ratios of the estimated anthropogenic Pb to source-related materials, the provenances of anthropogenic Pb in Chinese river sediments were presumed to be Chinese coal or ore, which is also a major source of atmospheric particulate Pb. The anthropogenic Pb in the shelf core sediments in the northern Yellow Sea originated from northern Chinese cities such as Beijing and Tianjin through atmospheric pathways. Pb isotope ratios indicated that Pb in Korean river sediments was characteristic of local Korean ores.  相似文献   

网箱养鱼诱发有机物污染的生物监测     

叶立勋 《中国海洋大学学报(自然科学版)》1990,(3)

介绍三种通过底栖动物群落结构的变化对有机物污染监测和评价的方法,并分别对澳大利亚塔斯马尼亚州Nubeena鳟鱼养殖场内由高密度网箱养鱼诱发的有机物污染进行了检测。结果表明:距网箱垂线0m处为严重污染区域,10m处为中度污染区域,30m为过渡类型,其有机物对该处底栖生物仍具有害影响,60m处为轻度有机物富集区,但该处有机物对底栖生物的总效应是有益的,60m以外为正常区域。本文还对三种方法的适用性进行了讨论。  相似文献   

南海北部海区水团的判别分析   总被引：1，自引：0，他引：1  

李凤岐  苏育嵩  范立群 《中国海洋大学学报(自然科学版)》1989,(Z1)

将判别分析应用于南海北部海区的水团分析。划分为八个水团:沿岸冲淡水团(F),近岸混合水团(M),暖表层水团(WS),表层水团(S),表—次层混合水团(SU),次层水团(U),次—中层混合水团(UI)和中层水团(I)。给出了各水团在四季代表月的Bayes多组判别的系数和参数。用资料检验判别的成效.冬季和春季可达95.90％以上,夏季为94.80％,秋季是全年最低值,为92.72％。讨论了造成错判的原因,并与Fisher判别作了比较。当测值维数较低时,建议选用Bayes判别。对八个水团以及各水团两两之间差异的显著性进行了检验,证实在每个季节中各水团之间的差异,都在高度置信水平(α=0.01)上具有显著性。因而,划分为八个水团是有实际意义的,其判别式的系数和参数,可用于实际的判别和预报。  相似文献   

再创找矿佳绩,为我省经济建设立新功——对我省找矿突破的几点看法     

叶允钧 《福建地质》2008,27(2):125-129

分析了福建省铁、铜、铅锌、钼、金、银、锡、非金属、能源等矿产的成矿地质条件、资源背景、找矿潜力、重点成矿区带、部分含矿层、岩浆-构造-成矿作用等,对我省地质找矿突破的方向提出了看法和建议。  相似文献   

Impact of Montmorillonite and Calcite on Release and Adsorption of Cyanobacterial Fatty Acids at Ambient Temperature   总被引：1，自引：0，他引：1  

刘邓  杨小芬  王红梅  李继红  苏念 《中国地质大学学报(英文版)》2008,19(5):526-533

Minerals might act as important sorbents of sedimentary organic matter and reduce biodegradation, which favors the formation of hydrocarbon source rocks in the earth's history. Since most organic matter is degraded during the sinking process, at ambient temperature, it is important to investigate the adsorption capacity of different minerals during this process, to assess the organic loss from primary productivity to sedimentary organic matter. In this study, montmorillonite and calcite have been selected to study the impact of different minerals on the release, adsorption, and deposition of cyanobacterial (Synechococcus elonpata) fatty acids (FAs) at ambient temperature. Gas chromatography (GC), gas chromatography-mass spectrometry (GC-MS) have been utilized to detect the variation in fatty acids. Primary results suggest that minerals have a different impact on dissolved organic matter. Montmorillonite can specifically enhance the release of fatty acids from cyanobacterial cells by lowering the pH values of the solution. The adsorption of the dissolved organic matter by montmorillonite will also be enhanced under a lower pH value. Conjunction of fatty acids with montmorillonite to form a complex will favor the sinking and preservation of these organics. Selective adsorption is observed among fatty acids with different carbon numbers. In contrast, calcite does not show any impact on the release and adsorption of organic matter even though it is reportedly capable of acting as a catalyst during the transformation of organic matter at high temperature. The primary data bridge a link between primary productivity and sedimentary organic matter, suggesting the relative importance of claystones in the formation of hydrocarbon source rocks in the earth's history.  相似文献   

末次盛冰期以来印度尼西亚穿越流对东印度洋上部水体结构的影响          下载免费PDF全文

叶黎明  翦知湣  金海燕  成鑫荣 《第四纪研究》2008,28(3):458-464

海洋上部水体垂向结构变化对于理解热带海区在全球气候变化中的作用有着重要意义。通过分析印度尼西亚穿越流(ITF)出口处东印度洋帝汶海区SO18480-3孔中的浮游有孔虫表层种Globigerinoides ruber和温跃层种Pulleniatina obliquiloculata壳体氧碳同位素,并借助12个AMS¹⁴C测年数据重建了末次盛冰期(LGM)以来该区温跃层深度和营养盐水平的演化序列。壳体氧同位素(δ¹⁸O)记录表明温跃层古海洋学特征的变化幅度要大于表层海水,其差值(Δδ¹⁸O_(P-G))有效地反映了温跃层深度的变化,即冰消期和晚全新世温跃层较浅,LGM和早中全新世温跃层较深;并揭示出与全新世相比,LGM期间ITF总流量未显著减小,ITF对该区上部水体结构的影响受到了东西太平洋之间不对称性的调节。碳同位素(δ¹³C)记录则表明该区的古海洋学变化在不同程度上受到了南大洋的影响,并受本区上部水体垂向结构的控制,其差值(Δδ¹³_(G-P))在一定程度上反映了该区上部水体营养盐水平的变化。  相似文献   

北京郊区农田土壤中HCH残留调查及评价   总被引：2，自引：0，他引：2  

刘晨  陈家玮  杨忠芳  陶冶 《物探与化探》2008,32(5):567-570

北京郊区农田分析区的土壤样品中,均有不同程度的各种HCH异构体检出.在所测样品中,HCH异构体平均含量由高到低排序为σ-HCH、β-HCH、γ-HCH、α-HCH,而且在各个样品中γ-HCH都没有占据主导地位,说明在土壤中没有新的HCH进入.与商品HCH进行比较,w(α-HCH)和w(γ-HCH)明显下降,w(β-HCH)和w(σ-HCH)却相对上升了,分析得出异构体之间的降解转化速率由大到小排序为α-HCH、γ-HCH、σ-HCH、β-HCH.初步评价近年没有新的HCH来源污染本区,但仍有一定风险.  相似文献   

Chronology and cooling history of the Tianmenshan pluton in South Jiangxi Province and their geological significance     

Qingtao Zeng  Jianren Mao  Qing Hu  Xilin Zhao  Haimin Ye 《中国地球化学学报》2008,27(3):276-284

Geochronological studies on the crust-derived Tianmenshan pluton were undertaken by SHRIMP zircon U-Pb dating and Ar-Ar dating of biotite, muscovite and K-feldspar, giving a petrogenetic age of 167 Ma. Owing to the closure systems in different minerals, the cooling history of the pluton can be determined with an age-temperature diagram. The late hydrothermal event has been recognized, which is related probably with mineralization. In terms of the comparative geochronological and petrologic records, it is concluded that there are some constrains on tectonic evolution and that the formation of the Tianmenshan pluton proceeded in a transition period from Indosinian post-orogeny extension to strong compressive tectonics. And the timing of the hydrothermal event matches the compressive climax of the Yanshanian orogeny. The temporal gap between granite emplacement and wolframite mineralization could last 10-20 Ma owing to the low cooling rate of the pluton.  相似文献   

Simulation experiment on hydrocarbon generating potential of various source rocks on the northern margin of the Qaidam Basin,Qinghai, China     

Xin Li  Dongliang Wang  Baoquan Liu  Chunling Ren  Jianying Guo  Xuefeng Su  Jian Wang 《中国地球化学学报》2008,27(4):412-419

The northern margin of the Qaidam Basin is one of the main oil-gas exploration areas in western China, where source rocks are composed mostly of Middle and Lower Jurassic dark mud shale, carbargillite and coal. A large number of subsurface and outcrop samples differing in lithology with different types of organic matter were selected for resource evaluation, research and calculation. And among them, 13 samples were used for simulation experiment on hydrocarbon generating potential of various source rocks. At first, two kinds of heating modes were compared through simulation experiment, including single temperature-step heating and continual heating. Perhaps, the process of hydrocarbon generation and expulsion occurred naturally between a close system and an open system. In addition, the first heating mode was convenient, and all its reaction products were involved in the whole thermal evolution, and the final simulation experimental results were basically in consistency with the natural evolution trend Therefore, the first heating mode was adopted and the hydrocarbon yield of every sample was worked out. According to the type and lithology of organic matter and the hydrocarbon yield of samples for simulation experiment, hydrocarbon generation and expulsion mode with three kinds of lithology and five types of source rock has been established to provide the basis for hydrocarbon generation evaluation, research and resource calculation.  相似文献   

胶南晚中生代大珠花岗岩岩体的脆性变形机制   总被引：1，自引：0，他引：1  

田野  单业华 《大地构造与成矿学》2008,32(4)

在长期变化的构造应力作用下,胶南大珠山花岗岩岩体自早白垩世冷凝冷却以来发生强烈的脆性破裂变形,形成了多样的破裂类型如岩脉、节理和断层。在该岩体冷凝冷却早期侵入的细晶花岗岩脉和稍后形成的N-S向节理组反映出与同期区域构造应力场协调的N-S向挤压作用,而后伴随着揭顶剥蚀,出现了交替变化的构造应力场形成了岩体内主导的NW-NNW向和NE向节理组。整体上,恢复出的岩体内构造应力场发生顺时针方向旋转,最大水平挤压由早期的N-S向偏转为晚期的近E-W向。构造应力场的长期变化、平行节理作用和节理断层化作用造成了研究区复杂的破裂型式和破裂序列。  相似文献