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111.
This study presents a laboratory study of the following two aspects: (1) the influence of sea laver treatment acid on the
geoenvironmental properties of Ariake Sea tidal mud, and (2) the natural remediation effect on the sea laver treatment acid
contaminated Ariake Sea tidal mud caused by the upward seepage of pore water liquid in the mud. Firstly, the mechanisms of
the transport of sea laver treatment acid in the Ariake Sea tidal mud and the generation mechanisms of the upward seepage
flow in the Ariake Sea tidal mud are discussed. Secondly, a series of one-dimensional laboratory infiltration tests were carried
out to investigate the deterioration of the Ariake Sea tidal mud caused by the sea laver acid treatment practice. Test results
reveal that the acid treatment practice caused considerable change in the geochemical properties of the mud in terms of increase
in sulfide content and decrease in pH value. After the treatment by the sea laver treatment acid, the sulfide content of the
mud even exceeded the safe limit value for the benthos, which represents undesirable living condition for benthos. Thirdly,
series of laboratory fresh seawater infiltration tests for the deteriorated Iida site mud were conducted to illustrate this
natural remediation efficiency. It is found that with the infiltration of the fresh seawater, the sulfide content of the Iida
site mud was considerably reduced and pH value increased to an acceptable range for benthos living in the tidal flat mud.
With the increase in the infiltration time and the hydraulic gradient, the remediation efficiency could be increased. 相似文献
112.
113.
Wenjun Yong E. Dachs A. C. Withers E. J. Essene 《Contributions to Mineralogy and Petrology》2008,155(2):137-146
The low-temperature heat capacity (C
p) of Si-wadeite (K2Si4O9) synthesized with a piston cylinder device was measured over the range of 5–303 K using the heat capacity option of a physical
properties measurement system. The entropy of Si-wadeite at standard temperature and pressure calculated from the measured
heat capacity data is 253.8 ± 0.6 J mol−1 K−1, which is considerably larger than some of the previous estimated values. The calculated phase transition boundaries in the
system K2O–Al2O3–SiO2 are generally consistent with previous experimental results. Together with our calculated phase boundaries, seven multi-anvil
experiments at 1,400 K and 6.0–7.7 GPa suggest that no equilibrium stability field of kalsilite + coesite intervenes between
the stability field of sanidine and that of coesite + kyanite + Si-wadeite, in contrast to previous predictions. First-order
approximations were undertaken to calculate the phase diagram in the system K2Si4O9 at lower pressure and temperature. Large discrepancies were shown between the calculated diagram compared with previously
published versions, suggesting that further experimental or/and calorimetric work is needed to better constrain the low-pressure
phase relations of the K2Si4O9 polymorphs.
Electronic supplementary material The online version of this article (doi:) contains supplementary material, which is available to authorized users. 相似文献
114.
Yuan-Bao Wu Shan Gao Hong-Fei Zhang Sai-Hong Yang Wen-Fang Jiao Yong-Sheng Liu Hong-Lin Yuan 《Contributions to Mineralogy and Petrology》2008,155(1):123-133
The Hong’an area (western Dabie Mountains) is the westernmost terrane in the Qinling-Dabie-Sulu orogen that preserves UHP
eclogites. The ages of the UHP metamorphism have not been well constrained, and thus hinder our understanding of the tectonic
evolution of this area. LA-ICPMS U–Pb age, trace element and Hf isotope compositions of zircons of a granitic gneiss and an
eclogite from the Xinxian UHP unit in the Hong’an area were analyzed to constrain the age of the UHP metamorphism. Most zircons
are unzoned or show sector zoning. They have low trace element concentrations, without significant negative Eu anomalies.
These metamorphic zircons can be further subdivided into two groups according to their U–Pb ages, and trace element and Lu–Hf
isotope compositions. One group with an average age of 239 ± 2 Ma show relatively high and variable HREE contents (527 ≥ LuN ≥ 14) and 176Lu/177Hf ratios (0.00008–0.000931), indicating their growth prior to a great deal of garnet growth in the late stage of continental
subduction. The other group yields an average age of 227 ± 2 Ma, and shows consistent low HREE contents and 176Lu/177Hf ratios, suggesting their growth with concurrent garnet crystallization and/or recrystallization. These two groups of age
are taken as recording the time of prograde HP to UHP and retrograde UHP–HP stages, respectively. A few cores have high Th/U
ratios, high trace element contents, and a clear negative Eu anomaly. These features support a magmatic origin of these zircon
cores. The upper intercept ages of 771 ± 86 and 752 ± 70 Ma for the granitic gneiss and eclogite, respectively, indicate that
their protoliths probably formed as a bimodal suite in rifting zones in the northern margin of the Yangtze Block. Young Hf
model ages (T
DM1) of magmatic cores indicate juvenile (mantle-derived) materials were involved in their protolith formation.
Electronic supplementary material The online version of this article (doi:) contains supplementary material, which is available to authorized users. 相似文献
115.
The alkenone unsaturation index UK′37 has been applied to reconstruct past temperature changes in both marine and lacustrine systems. However, few studies have addressed whether the relative abundance of the C37:4 alkenone to the total C37 production (%C37:4) can reflect surface salinity changes in lacustrine systems. Here we present long-chain C37 alkenone distribution patterns in surface sediments from Lake Qinghai, China. Surface sediments were sampled over a large range of surface salinity changes (1.7-25 g/l) within Lake Qinghai and its surrounding lakes, while temperature differences at these sampling locations should be relatively small. We have found that %C37:4 varies from 15% to 49% as surface salinity decreases. We tentatively describe this %C37:4-salinity link with a general linear regression: %C37:4 = 53.4 (±7.8) − 1.73 (±0.45) × S (n = 28, r2 = 0.62), although step-wise %C37:4 changes in response to salinity variation may exist. UK′37 values vary between 0.10 and 0.16 at these sites and the inferred range of lake water temperature changes is ∼2-3 °C, suggesting that UK′37 largely reflects temperature signal across a large salinity range, consistent with previous findings that UK′37 can indicate temperature changes over a large diversity of environmental settings. We have also found that UK′37 values are correlated with salinity changes (r2 = 0.4), and thus cannot exclude potential temperature effect on %C37:4 and salinity effect on UK′37 in this study. However, even extreme estimates of temperature differences within the lake are still unable to explain the observed %C37:4 changes. We therefore suggest that %C37:4 could be used to infer past lake salinity changes at a regional scale. 相似文献
116.
Understanding of isotopic variations in leaf water is important for reconstruction of paleoclimate and assessment of global biochemical processes. We report here a study of isotopic distributions within a single needle of two pine species, Pinus resinosa Ait and Pinus strobes L., with the objective of understanding how isotopic compositions of leaf water are controlled by environmental and physiological variables. A 2D model was developed to simulate along-leaf isotopic variations and bulk leaf water isotopic compositions. In addition to variables common to all leaf water isotopic models, this 2D model also takes into account the specific geometry and dimensions of pine needles and the isotopic transport in xylem and mesophyll. The model can successfully simulate oxygen isotopic variations along a single needle and averaged over a leaf (bulk leaf water). The simulations suggest that isotopic composition of the bulk leaf water does not always depend only upon the average transpiration rate, which in turn raises questions about using leaf water isotopic values to estimate transpiration rates. An unsuccessful attempt to simulate along-needle hydrogen isotopic variations suggests that certain unknown biological process(es) may not have been incorporated into our 2D model, and if so, it calls for a reevaluation of all other models for hydrogen isotopic simulations of leaf water since they too lack these processes.Existing leaf water isotopic models are reviewed in this work. In particular, we evaluate the most frequently used model, the stomatal boundary layer model (also referred to as the Craig-Gordon model). We point out that discrepancy between the boundary layer model and the measured bulk leaf water seems to depend upon relative humidity. Using our 2D model, we show that this humidity dependency is a result of an interplay between environmental and physiological conditions: if the transpiration rate of plant leaves decreases with increasing relative humidity, our 2D model can reproduce the pattern of isotopic discrepancy between boundary layer model predictions and observations, enabling us to understand better the reason behind this discrepancy. 相似文献
117.
118.
119.
中国滑坡预测预报研究综述 总被引:14,自引:1,他引:13
滑坡预测预报是有效预防滑坡灾害的重要途径之一,这方面的研究不仅受到广泛重视,且硕果累累。将中国滑坡预测预报的研究历史划分为四个阶段:① 经验判断——被动防灾避灾阶段;② 定性——半定量分析预测预报阶段;③ 理论方法探索——检验预测预报阶段;④ 理论方法深化——综合应用预测预报阶段。从监测(观测)方法、预测预报方法,以及研究特点等方面进行简要回顾,总结已有监测方法(手段)、预测预报理论、方法的研究现状,认为尚存在:① 监测方法(手段),包括仪器、设备的精度不足;② 预测预报方法综合性、实用性不强;③ 预测预报专门理论尚待完善等问题。在分析的基础上,提出自己的观点,并进行了发展趋势展望。 相似文献
120.
人工合成烃类包裹体研究进展 总被引:4,自引:0,他引:4
人工合成烃类包裹体不仅可以作为分析仪器校正的标样,还可以增进人们对烃类包裹体形成机制和水—岩作用机理的认识。人工合成包裹体的方法主要有三种:人工晶体生长法、焊封石英管法和金刚石压腔法,其中利用愈合人工石英(水晶)单晶裂隙合成流体包裹体技术已成为标准的合成技术。目前人工合成烃类包裹体主要利用晶体生长法合成,包括高温高压利用石英(或方解石)晶体生长愈合裂缝形成流体包裹体和低温下采用过饱和溶液重结晶形成流体包裹体。由于高温高压条件下烃类可能发生裂解,母液保真是成功实现人工合成烃类包裹体的重要前提条件。国外在人工合成烃类包裹体研究方面已经取得了一些重要的认识,但远不及人工合成无机体系流体包裹体研究那样系统和完善。国内关于人工合成烃类包裹体研究尚处于起步阶段,迫切需要开展这方面的研究工作。 相似文献