Grain-scale iron isotopic distribution of pyrite from Precambrian shallow marine carbonate revealed by a femtosecond laser ablation multicollector ICP-MS technique: Possible proxy for the redox state of ancient seawater     

Manabu Nishizawa  Hiroki Yamamoto  Subaru Tsuruoka  Yusuke Sawaki  Yoshiaki Kon  Tsuyoshi Komiya  Takafumi Hirata 《Geochimica et cosmochimica acta》2010,74(9):2760-8899

The redox state of Precambrian shallow seas has been linked with material cycle and evolution of the photosynthesis-based ecosystem. Iron is a redox-sensitive element and exists as a soluble Fe(II) species or insoluble Fe(III) species on Earth’s surface. Previous studies have shown that the iron isotopic ratio of marine sedimentary minerals is useful for understanding the ocean redox state, although the redox state of the Archean shallow sea is poorly known. This is partly because the conventional bulk isotope analytical technique has often been used, wherein the iron isotopic record may be dampened by the presence of isotopically different iron-bearing minerals within the same sample. Here we report a microscale iron isotopic ratio of individual pyrite grains in shallow marine stromatolitic carbonates over geological time using a newly developed, near-infrared femtosecond laser ablation multicollector ICP-MS technique (NIR-fs-LA-MC-ICP-MS).We have determined that the grain-scale iron isotopic distribution of pyrite from coeval samples shows a bimodal (2.7 and 2.3 Ga) or unimodal pattern (2.9, 2.6, and 0.7 Ga). In particular, pyrite from the 2.7 Ga Fortescue Group shows a unique bimodal distribution with highly positive (+1.0‰ defined as Type 1) and negative δ⁵⁶Fe values (−1.8‰ defined as Type 2). Type 1 and 2 pyrites occasionally occur within different siliceous layers in the same rock specimen. Layer-scale iron isotopic heterogeneity indicates that the iron isotopic ratios of the two types of pyrite are not homogenized by diagenesis after deposition. Some cubic pyrites have a core with a positive δ⁵⁶Fe value (1‰) and a rim with a crustal δ⁵⁶Fe value (0‰). The observed isotopic zoning suggests that the positive δ⁵⁶Fe value is a primary signature at the time of stromatolite formation, while secondary pyrite precipitated during diagenesis.The positive δ⁵⁶Fe value of Type 1 and the large iron isotopic difference between Type 1 and 2 (2.8‰.) suggest partial Fe(II) oxidation in the 2.7-Ga shallow sea, i.e., pyritization of ⁵⁶Fe-enriched ferric oxyhydroxide (Type 1) and ⁵⁶Fe depleted Fe²⁺aq in seawater (Type 2). Type 2 pyrite was probably not produced by microbial iron redox cycling during diagenesis because this scenario requires a higher abundance of pyrite with δ⁵⁶Fe of 0‰ than of −1.8‰. Consequently, the degree of Fe(II) oxidation in the 2.7-Ga shallow sea can be estimated by a Fe²⁺aq steady-state model. The model calculation shows that half the Fe²⁺aq influx was oxidized in the seawater. This implies that O₂ produced by photosynthesis would have been completely consumed by oxidation of the Fe²⁺aq influx. Grain-scale iron isotopic distribution of pyrite could be a useful index for reconstructing the redox state of the Archean shallow sea.  相似文献   

Application of an earthquake early warning system and a real-time strong motion monitoring system in emergency response in a high-rise building   总被引：1，自引：0，他引：1  

Tomohiro Kubo  Yoshiaki Hisada  Masahiro Murakami  Fusako Kosuge  Kohei Hamano 《Soil Dynamics and Earthquake Engineering》2011

We apply a combination of earthquake early warning system (EEWS) and real-time strong motion monitoring system (RSMS) to emergency response for a high-rise building; The Kogakuin University has a 29-story high-rise building in Shinjuku Ward, Tokyo. The proposed strategy is based on the Plan, Do, Check, Action (PDCA) Cycle to brush up the systems and the users: in the “Plan” stage, we apply EEWS and RSMS to the building, where EEWS predicts not only short-period strong ground motions but also long-period ground motions [1]. The system is built into a building announcement system, an emergency elevator control system, and an email message system, which quickly send emails to the emergency response team. Meanwhile, RSMS provides information on seismic intensities at each floor of the building via the web browser in real time using the existing network in the building. In addition, the building response and structural damage can be estimated based on this information. The network system is impervious to the earthquake damage, because the network cable has extra length, there is, however, possible that a network system does not work due to power outage. Thus, we develop the network system that has uninterruptible power-supply system (UPS) and apply it to EEWS and RSMS. The high-rise building has the emergency call units to the security control center in the building on every floor. The emergency call line, however, will be busy promptly, because it is able to use only one line. Therefore, we installed IP telephone which uses the network system on main floors. UPS will work about 30 min after a major earthquake, it is supposed to be enough time for gathering the damage information about the building during initial response. In the “Do” stage, we prepare emergency response instruction manuals and educate the faculty members and students to carry out promptly emergency response. In the “Check” stage, the validity of the proposed systems are verified by carrying out an earthquake drill in an actual high-rise building. The earthquake drill confirmed that our proposed approach is valid. In the final “Action” stage, we improve these systems and emergency response manual and educate people in the building how to use effectively these systems.  相似文献   

Installing single-propeller twin-rudder system with less asymmetric maneuvering motions     

Donghoon Kang  Vishwanath Nagarajan  Yoshiaki Gonno  Kazuhiko Hasegawa 《Ocean Engineering》2011,38(10):1184-1196

The inflow characteristics to each one of the rudders of single-propeller twin-rudder system are investigated. It is shown that this inflow is not parallel to ship's centerline. This may result in asymmetric maneuvering characteristic of the ship thereby reducing ship's maneuvering performance. For this purpose, a method of installing single-propeller twin-rudder system is proposed. This method is called “virtual zero rudder angle” arrangement. Here, each one of the twin-rudder is set at an angle corresponding to the inflow to the rudder. The improvement in ship's maneuvering characteristics with “virtual zero rudder angle” arrangement is investigated using experiments and numerical simulations for different ship types. It is shown that this arrangement may also improve ship's propulsion performance.  相似文献   

Geochemical Characteristics of Apatite in Heavy REE‐rich Deep‐Sea Mud from Minami‐Torishima Area,Southeastern Japan     

Yoshiaki Kon  Mihoko Hoshino  Kenzo Sanematsu  Sayaka Morita  Maiko Tsunematsu  Nobuyuki Okamoto  Nobuhiko Yano  Mikiya Tanaka  Tetsuichi Takagi 《Resource Geology》2014,64(1):47-57

We have conducted geochemical and mineralogical investigations of the rare earth and yttrium (REY)‐rich mud from the Minami‐Torishima area in the Pacific in order to clarify the concentration of REY and their host‐phase in the mud. X‐ray diffraction analysis shows that the mud is mainly composed of phillipsite, fluorapatite, quartz, albite, illite and montmorillonite. Whole‐rock CaO, P₂O₅ and total REY contents of the mud are positively correlated. Relative abundance of apatite is also positively correlated to P₂O₅ and total REY contents. These correlations suggest that apatite is the main host of the P₂O₅ and REY in the mud. We make in situ compositional analyses of constituent minerals in the REY mud. The results show that the apatite is abundant in REY (9300–32,000 ppm) and is characterized by a negative Ce anomaly and enrichment in heavy rare‐earth elements. This abundance and composition of REY of the mud is similar those of fish debris apatites. In contrast, phillipsite is less abundant in REY (60–170 ppm). Therefore we conclude that the main REY host phase of the mud is apatite.  相似文献   

Magnetic-Tower Jet Solution for Launching Astrophysical Jets     

Yoshiaki Kato 《Astrophysics and Space Science》2007,307(1-3):11-15

In spite of the large number of global three-dimensional (3-D) magnetohydrodynamic (MHD) simulations of accretion disks and astrophysical jets, which have been developed since 2000, the launching mechanisms of jets is somewhat controversial. Previous studies of jets have concentrated on the effect of the large-scale magnetic fields permeating accretion disks. However, the existence of such global magnetic fields is not evident in various astrophysical objects, and their origin is not well understood. Thus, we study the effect of small-scale magnetic fields confined within the accretion disk. We review our recent findings on the formation of jets in dynamo-active accretion disks by using 3-D MHD simulations. In our simulations, we found the emergence of accumulated azimuthal magnetic fields from the inner region of the disk (the so-called magnetic tower) and also the formation of a jet accelerated by the magnetic pressure of the tower. Our results indicate that the magnetic tower jet is one of the most promising mechanisms for launching jets from the magnetized accretion disk in various astrophysical objects. We will discuss the formation of cosmic jets in the context of the magnetic tower model.  相似文献   

Incessant excitation of the Earth's free oscillations: global comparison of superconducting gravimeter records     

Kazunari Nawa  Naoki Suda  Yoshio Fukao  Tadahiro Sato  Yoshiaki Tamura  Kazuo Shibuya  Herbert McQueen  Heikki Virtanen  Jussi Kriinen 《Physics of the Earth and Planetary Interiors》2000,120(4):289-297

Records of superconducting gravimeters (SGs) at Canberra (Australia), Esashi (Japan), Metsähovi (Finland) and Syowa Stations (Antarctica) were analyzed to search for further evidence of background free oscillations of the Earth. Spectrograms for 1-year period and averaged power spectra for seismically quiet periods were obtained for each of the stations. Anomalous features of the oscillations observed at Syowa Station, such as an apparent seasonal variation and a high intensity at frequencies between 3 and 4 mHz, were absent at the other SG stations. Among the SG stations used in this study, the background free oscillations were detected most consistently and distinctly at Canberra, where the noise level was comparable to that at the IDA quietest station, while that at Syowa Station was close to the critical limit for detecting the oscillations. The background free oscillations provide a good reference to evaluate the noise level in the milliHertz band.  相似文献   

Zircon U–Pb sensitive high mass-resolution ion microprobe dating of granitoids in the Ryoke metamorphic belt, Kinki District, Southwest Japan     

Teruo Watanabe  Trevor Ireland  Yoshiaki Tainosho and  Yutaka Nakai 《Island Arc》2000,9(1):55-63

Abstract Zircon U–Pb sensitive high mass-resolution ion microprobe dating was carried out on three types of granitic rock (gneissose biotite granodiorite, biotite granite and two-mica granite) from the Cretaceous Ryoke belt of the Kinki district, Southwest Japan. The results give the ages of granitic magmatism in the Shigi-san area of between 87 and 78 Ma and suggest extensive melting of the Cretaceous Ryoke granitic crust to form the two-mica granite, probably at ca 80 Ma. Discrimination into older and younger granites based on development of gneissosity does not appear to represent the sequence of magma generation, although there is some scope in the interpretation of the zircon U–Pb data that would allow all three granites to form at 83 Ma. Compilation of chemical Th-U-total Pb isochron dating method ages, whole rock Rb–Sr isotope ages and U–Pb isotope ages indicates that most Ryoke plutonism occurred from ca 70 Ma to ca 100 Ma. Younger (85 Ma–70 Ma) plutonism with the formation of two-mica granite occurred only in the eastern sector of the Ryoke belt, including the Kinki District.  相似文献   

A fluorescent approach to the identification of grout injected into fissures and pore spaces   总被引：6，自引：0，他引：6  

Youqing Chen  Takashi Nishiyama  Michinao Terada  Yoshiaki Iwamoto 《Engineering Geology》2000,56(3-4):395-401

A new fluorescent approach was developed to visualize grouting processes. The evaluation of the effect of grouting is carried out by methods based mainly on physical measurements such as permeability and porosity characteristics. However, these estimates do not necessarily correlate with practical grouting data. In this paper, the distributions of various grout mixtures containing fluorescent substances were clearly visualized under ultraviolet light, using a borehole television system or a microscope. Since this approach enabled direct observation of grout distribution, it is considered that this approach is useful for analysis of grouting mechanisms, designing grout curtains, etc.  相似文献   

Photometric properties of the Arp 220 super star clusters     

Yasuhiro Shioya  Yoshiaki Taniguchi  Neil Trentham 《Monthly notices of the Royal Astronomical Society》2001,321(1):11-17

We investigate the photometric properties of six super stellar clusters (SSCs) seen in both the optical and near-infrared Hubble Space Telescope images of the local ultraluminous starburst galaxy Arp 220. Three of the SSCs are located in the central 0.5-kpc region. The remaining three are in the circumnuclear region between 0.5 and 2.5 kpc from the centre. Comparing the observed spectral energy distributions (SEDs) of the SSCs with the Starburst99 models of Leitherer et al., we confirm that all three nuclear SSCs are heavily obscured     Considering the results from this comparison in conjunction with measurements of the near-infrared CO absorption index and of millimetre CO linewidths and luminosities, we estimate the ages of the nuclear SSCs to be 10⁷–10⁸ yr. The bolometric luminosity of the three nuclear SSCs is at most one-fifth of the total bolometric luminosity of Arp 220. On the other hand, the circumnuclear SSCs have little internal extinction     These contribute negligibly to the total bolometric luminosity.  相似文献   

Synthetic Silica Glass for Trace Aluminium Determination in Quartz by Electron Microprobe     

Naoya Miyoshi  Hisao Satoh  Yoshiaki Yamaguchi  Harue Masuda 《Geostandards and Geoanalytical Research》2003,27(1):91-98

Five synthetic silica glasses have been prepared for microprobe determination of trace aluminium in quartz. The glasses were synthesized from tetraethoxysilane (TEOS) into which between 0 and 1431 μg g-¹ aluminium had been doped. The aluminium concentrations of the glasses were independently determined by ICP-AES analysis. X-ray wavelength shift in the Al Kα peak was minimised relative to unknown quartz samples when these glasses were used for calibration. A set of these five glasses yielded a linear calibration line, and are available for trace aluminium analysis of quartz in routine microprobe systems.  相似文献