An infinity of conservation laws of fKdV equation is derived in terms of the Miura and Gardner''s transform.The pseudo-mass and energy theorems are studied by the first two conservation laws.As a typical example,the theoretical mean wave resistance and the regional distribution of energy of the precursor soliton generation are determined by means of the first and the second conservation laws. 相似文献
Details are given of the refinement and application of a thee-dimensional (3-D) layer-integrated numerical model of tidal circulation, with the aim of simulating severe tidal conditions for practical engineering applications. The mode splitting strategy has been used in the model. A set of depth-integrated 2-D equations are first solved to give the pressure gradient, and the layer-integrated 3-D equations are then solved to obtain the vertical distributions of the flow velocities. Attention has been given to maintaining consistency of the physical quantities derived from the 2-D and 3-D equations. A TWO=layer mixing length turbulence model for the vertical shear stress distribution has been included in the model. Emphasis has been focused on applying the model to a real estuary, which is geometrically complicated and has large tidal ranges giving rise to extensive flooding and drying. The model has been applied to three examples, including: wind-driven flow in a rectangular lake, tidal circulation in a model rectangular harbour, and tidal circulation in a large estuary. Favourable results have been obtained for both the simple and complex flow beds. 相似文献
Ancient sea conditions can be estimated from the grain size, spacing and steepness of preserved ripple-marks. The element of greatest uncertainty in such reconstructions is the relationship between near-bed orbital diameter of water particles and the ripple spacing. This relationship is simple for vortex ripples of high steepness but is problematical for the low-steepness forms known as post-vortex, rolling-grain or anorbital ripples.
The existence field for wave ripples is between the threshold velocity for sediment movement and the onset of sheet flow, most low-steepness forms occurring close to the bed planation threshold. A range of maximum period of formative waves can be obtained using combinations of orbital diameter and orbital velocity, assuming linear wave theory to be a reasonable approximation.
Probable wave heights, wave lengths and water depths can be investigated using the transformation of wave parameters in shallowing waters and the constraints on wave dimensions provided by the wave-breaking condition. Given reasonable estimates of wave height, crude estimates of wave power allow a comparison of ancient wave-influenced sequences with modern counterparts.
Wave ripple-marks preserved in the Upper Marine Molasse of western Switzerland have been investigated. Results, which are in agreement with regional geology, suggest deposition in a seaway of approximately 100 km width, where moderate period waves (T = 3–6 s) were generated. The depositional facies belts were adjusted to the prevailing waves, tides and fluvial outflows. 相似文献
Determinations of copper consumption capacity (CuCs.C) and labile copper concentrations in surface coastal seawater, using a copper ion selective electrode (Cu-ISE) potentiometric method under predominantly diffusive conditions, are reported. For evaluation of the copper concentrations, the points of the endpoint contiguity zone of the CuCs.C titration curve were treated by an ISE multiple standard addition technique. The results were compared with those obtained by means of a Chelex-100 (calcic form) ‘batch’ procedure-potentiometric stripping analysis.The labile copper of the sample was determined at concentrations down to 10.70 nM with an average RSD of 12%, independent of the Cu-ISE employed. For adjacent subsamples, the mean CuCs.C values obtained for El Way seawater were equivalent to 81.05 and 48.00 nM copper, with an RSD of 4 and 7%, and for Isla Santa Maria seawater the value was equivalent to 70.27 nM copper, with an RSD of 7%. The theoretical approach of the electrode diffusive mechanism proposed, which would depend, fundamentally, on the adsorptive, complexing and reducing properties of the dissolved organic matter in the seawater sample, allows simultaneous analytical determination of CuCs.C and labile copper concentration in seawater. 相似文献
Trace element concentrations (Pb, Cd, Mn, Fe, and Zn) were measured along four surface water transects across the continental shelf off Baja California, to evaluate the magnitude of heavy metal contamination in the coastal waters along the US-Mexican boundary. These initial measurements of trace elements in Mexican neritic waters revealed offshore concentration gradients, with the highest levels in coastal waters with high salinities and nutrient concentrations. There were also longshore gradients, with lower concentrations in the southern locations. Although the relative enrichment of metals detected at nearshore stations along the US-Mexican border appeared to correspond to wastewater discharges in that area, these trace metal enhancements were found to be primarily associated with physical oceanographic processes (upwelling and advection), rather than anthropogenic inputs. This was demonstrated both by metal-nutrient correlations and multivariate statistical analyses. Mass balance calculations also indicated that about 1% of Cd, 9% of Zn, and 29% of Pb were from urban discharges within the area. 相似文献
Estimates of the characteristics of the horizontal turbulent exchange (coefficients of horizontal exchange, scales of deviations of the velocity of geostrophic currents from the background flows, and horizontal scales of perturbations) in the upper ocean layer were obtained on the basis of the data of expeditions held in 1978 and 1980 in the northwestern part of the Pacific Ocean. It is shown that the characteristics of the horizontal turbulent exchange strongly depend on the structure of the background flows, and one of the causes of their variability is related to tropical cyclones. A tendency to a decrease (to different degrees) of the turbulent coefficients in the wake of a tropical cyclone is noted. 相似文献
Iron chemistry in seawater has been extensively studied in the laboratory, mostly in small-volume sample bottles. However, little has been reported about iron wall sorption in these bottles. In this paper, radio-iron 55Fe was used to assess iron wall adsorption, both in terms of capacity, affinity and kinetics. Various bottle materials were tested. Iron sorption increased from polyethylene/polycarbonate to polymethylmetacrylate (PMMA)/high-density polyethylene/polytetrafluoroethylene to glass/quartz, reaching equilibrium in a 25–70 h period. PMMA was studied in more detail: ferric iron (Fe(III)) adsorbed on the walls of the bottles, whereas ferrous iron (Fe(II)) did not. Considering that in seawater the inorganic iron pool mostly consists of ferric iron, the wall will be a factor that needs to be considered in bottle experiments.The present data indicate that for PMMA with specific surface (S)-to-volume (V) ratio S/V, both iron capacity (42 ± 16 × 10− 9 mol/m2 or 1.7 × 10− 9 mol/L recalculated for the S/V-specific PMMA bottles used) and affinity (log KFe'W = 11.0 ± 0.3 m2/mol or 12.4 ± 0.3 L/mol, recalculated for the S/V-specific PMMA bottles used) are of similar magnitude as the iron capacity and -affinity of the natural ligands in the presently used seawater and thus cannot be ignored.Calculation of rate constants for association and dissociation of both Fe'L (iron bound to natural occurring organic ligands) and Fe'W (iron adsorbed on the wall of vessels) suggests that the two iron complexes are also of rather similar kinetics, with rate constants for dissociation in the order of 10 −4–10− 5 L/s and rate constants for association in the order of 108 L/(mol s). This makes that iron wall sorption should be seriously considered in small-volume experiments, both in assessments of shorter-term dynamics and in end-point observations in equilibrium conditions. Therefore, the present data strongly advocate making use of iron mass balances throughout in experiments in smaller volume set-ups on marine iron (bio) chemistry. 相似文献