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51.
The Obiro deposit is located in the Tagawa Acidic Rocks (AR), Uetsu region, NE Japan. The Tagawa AR is composed of a volcanic phase of dacitic welded tuff and a plutonic phase of porphyritic granodiorite. Drill core and ore samples were collected from the deposit and examined by XRD, EPMA, and microthermometry. The drill core samples have suffered pervasively from sericite (illite) alteration, whereas pinkish K‐feldspar alteration halo occur close to veins. The results of EPMA and microthermometry is interpreted as that the magnatic‐hydrothermal fluids has changed as follows; the granodioritic magma intruded at about 1.0 kb and 700°C near the water‐saturated granite solidus; after cooling to about 500°C the fluids boiled according to a change in the pressure regime from lithostatic to hydrostatic; mixing with meteoric water led to sulfide mineralization at around 400°C or less. The main reasons for the mineralization in the Obiro deposit are as follows; the oxidized magma intruded at a shallower level, and thereafter hydrothermal fluids were boiled, resulting in a saline fluid. The saline fluid then dissolved metals such as Pb, Zn, Cu, and Bi, and these metals precipitated during cooling accompanied by dilution of the meteoric water and increasing pH, resulting in decreasing solubility.  相似文献   
52.
Flow fields in Shizugawa Bay on the Sanriku ria coast, which faces the Pacific Ocean, were investigated using hydrographic observations for the purpose of understanding oceanographic conditions and the process of water exchanges in the bay after the 2011 earthquake off the Pacific coast of Tohoku. In spring to summer, density-driven surface outflow is part of estuarine circulation and is induced by a pressure gradient force under larger longitudinal gradients in density along with lower salinity water in the innermost part of the bay, regardless of wind forcing. In winter to summer, another density-driven current with a thermal structure is induced by a pressure gradient force under the smaller longitudinal density gradients in calm wind conditions. Particularly in winter, Tsugaru Warm Current water can be transported in the surface layer inside the bay. Wind-driven bay-scale circulation with downwind and upwind currents in the surface and deeper layers, respectively, is induced by strong longitudinal wind forcing under the smaller longitudinal density gradients, irrespective of season. Particularly in fall to spring, this circulation can cause the intrusions of oceanic water associated with Oyashio water and Tsugaru Warm Current water in the deeper layer. These results suggest that wind- and density-driven currents can produce the active exchange of water from inside and outside the bay throughout the year.  相似文献   
53.
Shear bands with characteristic spatial patterns observed in an experiment for a cubic or parallelepiped specimen of dry dense sand were simulated by numerical bifurcation analysis using the Cam‐clay plasticity model. By incorporating the subloading surface concept into the plasticity model, the model became capable of reproducing hardening/softening and contractive/dilative behavior observed in the experiment. The model was reformulated to be compatible with the multiplicative hyperelasto‐plasticity for finite strains. This enhanced constitutive model was implemented into a finite‐element code reinforced by a stress updating algorithm based on the return‐mapping scheme, and by an efficient numerical procedure to compute critical eigenvectors of elastoplastic tangent stiffness matrix at bifurcation points. The emergence of diamond‐ and column‐like diffuse bifurcation modes breaking uniformity of the materials, followed by the evolution of shear bands through strain localization, was observed in the analysis. In the bifurcation analysis of plane strain compression test, unexpected bifurcation modes, which broke out‐of‐plane uniformity and led to 3‐dimensional diamond‐like patterns, were detected. Diffuse bifurcations, which were difficult to observe by experiments, have thus been found as a catalyst creating diverse shear band patterns.  相似文献   
54.
Abstract– Exothermic reactions during the annealing of laboratory synthesized amorphous magnesium‐bearing silicate particles used as grain analogs of cosmic dust were detected by differential scanning calorimetry (DSC) in air. With infrared spectroscopy and transmission electron microscopy, we show that cosmic dust could possibly undergo fusion to larger particles, with oxidation of magnesium silicide and crystallization of forsterite as exothermic reactions in the early solar system. The reactions begin at approximately 425, approximately 625, and approximately 1000 K, respectively, and the reaction energies (enthalpies) are at least 727, 4151, and 160.22 J g−1, respectively. During the crystallization of forsterite particles, the spectral evolution of the 10 μm feature from amorphous to crystalline was observed to begin at lower temperature than the crystallization temperature of 1003 K. During spectral evolution at lower temperature, nucleation and/or the formation of nanocrystallites of forsterite at the surface of the grain analogs was observed.  相似文献   
55.
The phase and melting relations of the C-saturated C–Mg–Fe–Si–O system were investigated at high pressure and temperature to understand the role of carbon in the structure of the Earth, terrestrial planets, and carbon-enriched extraterrestrial planets. The phase relations were studied using two types of experiments at 4 GPa: analyses of recovered samples and in situ X-ray diffractions. Our experiments revealed that the composition of metallic iron melts changes from a C-rich composition with up to about 5 wt.% C under oxidizing conditions (ΔIW = ?1.7 to ?1.2, where ΔIW is the deviation of the oxygen fugacity (fO2) from an iron-wüstite (IW) buffer) to a C-depleted composition with 21 wt.% Si under reducing conditions (ΔIW < ?3.3) at 4 GPa and 1,873 K. SiC grains also coexisted with the Fe–Si melt under the most reducing conditions. The solubility of C in liquid Fe increased with increasing fO2, whereas the solubility of Si decreased with increasing fO2. The carbon-bearing phases were graphite, Fe3C, SiC, and Fe alloy melt (Fe–C or Fe–Si–C melts) under the redox conditions applied at 4 GPa, but carbonate was not observed under our experimental conditions. The phase relations observed in this study can be applicable to the Earth and other planets. In hypothetical reducing carbon planets (ΔIW < ?6.2), graphite/diamond and/or SiC exist in the mantle, whereas the core would be an Fe–Si alloy containing very small amount of C even in the carbon-enriched planets. The mutually exclusive nature of C and Si may be important also for considering the light elements of the Earth’s core.  相似文献   
56.
We describe the mode of occurrence and geochemical characteristics of basalts, in the Khangai–Khentei belt in Mongolia, overlain by Middle Paleozoic radiolarian chert in an extensive accretionary complex. These basalts are greatly enriched in K, Ti, Fe, P, Rb, Ba, Th, and Nb in comparison to the composition of the mid‐ocean ridge basalts, indicative of within‐plate alkaline type. Ti/Y vs Nb/Y and MnO/TiO2/P2O5 ratios of the basalts also suggest within‐plate affinities. Considering the geochemical characteristics as well as the conformable relationship with the overlying radiolarian chert, the alkaline basalts were clearly not continental but formed a pelagic oceanic island. The mode of occurrence and geochemistry of the basalts show that the alkaline basaltic volcanic activity had taken place to form an oceanic island in the Paleozoic pelagic region sufficiently far from continents to allow radiolarian ooze accumulation.  相似文献   
57.
We present observations of the extended dust structures near the orbits of three short-period comets: 2P/Encke, 22P/Kopff, and 65P/Gunn. The dust trails were originally discovered by the Infrared Astronomical Satellite (IRAS). Our observations were made using wide-field optical CCD cameras on the University of Hawaii 2.24-m telescope, the Canada-France-Hawaii 3.6-m telescope, and the Kiso 1.05-m Schmidt telescope. We compared the observed images with models and found that the extended structures seen around 2P/Encke and 22P/Kopff before perihelion passage were most likely “dust trails,” whereas images taken after perihelion passage show a high contamination by recently released particles (i.e., particles in Neck-Line structures are visible). We could not confirm the existence of a dust trail from 65P/Gunn within the field of view of the camera used. The effective sizes of the particles responsible for the scattered light were estimated at 1-100 mm (2P/Encke), 1-10 mm (22P/Kopff), and 100 μm-1 mm (65P/Gunn), respectively, which is consistent with previous studies of dust trails made with infrared space telescopes and optical telescopes. We evaluated the mass loss rates of these comets, averaged over their orbits, as reaching (2P/Encke), (22P/Kopff), and (65P/Gunn). These values are consistent with previous work. Therefore, the total amount of material ejected from these three comets is , which would contribute a considerable fraction of the lost within 1 AU that needs to be replaced if the zodiacal cloud is to be maintained in a steady state. We also found that the particles in the dust structures are significantly redder than the Sun and the zodiacal light, and might be redder than the average short-period comet nuclei. Specifically, the reflectivity gradients of 2P/Encke, 22P/Kopff, and 65P/Gunn are 13±7 (% 103 Å−1), 20±5 (% 103 Å−1), and 15±4 (% 103 Å−1), respectively. We examined the change in color with distance from the nucleus. No clear correlation was detected for 2P/Encke or 22P/Kopff to an accuracy of 3-11%, while the 65P/Gunn tail did show color variation, becoming redder with increasing distance from the nucleus. This dark red material, consisting of particles of sand-cobble size, has marginally escaped from the nuclei and will evolve into finer-grained interplanetary dust particles after subsequent collisions.  相似文献   
58.
A model of core formation is presented that involves the Earth accreting heterogeneously through a series of impacts with smaller differentiated bodies. Each collision results in the impactor's metallic core reacting with a magma ocean before merging with the Earth's proto-core. The bulk compositions of accreting planetesimals are represented by average solar system abundances of non-volatile elements (i.e. CI-chondritic), with 22% enhancement of refractory elements and oxygen contents that are defined mainly by the Fe metal/FeO silicate ratio. Based on an anhydrous bulk chemistry, the compositions of coexisting core-forming metallic liquid and peridotitic silicate liquid are calculated by mass balance using experimentally-determined metal/silicate partition coefficients for the elements Fe, Si, O, Ni, Co, W, Nb, V, Ta and Cr. Oxygen fugacity is fixed by the partitioning of Fe between metal and silicate and depends on temperature, pressure and the oxygen content of the starting composition. Model parameters are determined by fitting the calculated mantle composition to the primitive mantle composition using least squares minimization. Models that involve homogeneous accretion or single-stage core formation do not provide acceptable fits. In the most successful models, involving 24 impacting bodies, the initial 60–70% (by mass) of the Earth accretes from highly-reduced material with the final 30–40% of accreted mass being more oxidised, which is consistent with results of dynamical accretion simulations. In order to obtain satisfactory fits for Ni, Co and W, it is required that the larger (and later) impactor cores fail to equilibrate completely before merging with the Earth's proto-core, as proposed previously on the basis of Hf-W isotopic studies. Estimated equilibration conditions may be consistent with magma oceans extending to the core–mantle boundary, thus making core formation extremely efficient. The model enables the compositional evolution of the Earth's mantle and core to be predicted throughout the course of accretion. The results are consistent with the late accretion of the Earth's water inventory, possibly with a late veneer after core formation was complete. Finally, the core is predicted to contain ~ 5 wt.% Ni, ~ 8 wt.% Si, ~ 2 wt.% S and ~ 0.5 wt.% O.  相似文献   
59.
Gold‐mineralized quartz veins at the Trenggalek district of the Southern Mountains Range in East Java, Indonesia, are hosted by Oligo‐Miocene volcaniclastic and volcanic rocks, and are distributed close to andesitic plugs in the northern prospects (Dalangturu, Suruh, Jati, Gregah, Jombok, Salak, and Kojan) and the southern prospects (Sentul and Buluroto). The plugs are subalkaline tholeiitic basaltic‐andesite to calc‐alkaline andesite in composition. 40Ar–39Ar dating of a quartz‐adularia vein at the Dalangturu prospect yielded an age of 16.29 ± 0.56 Ma (2σ), and a crystal tuff of a limestone‐pyroclastic rock sequence at the southwest of the Dalangturu prospect was determined as 15.6 ± 0.5 Ma (2σ). Statistic overlap of ages suggests that the gold mineralization in the northern prospects took place in a shallow marine to subaerial transitional environment. Hydrothermal alteration of the host rocks is characterized by the replacement of quartz, illite and adularia. Quartz veins in surface outcrops are up to 50 cm wide in the northern prospects and up to 3 m wide in the southern prospects, showing a banded or brecciated texture, and are composed of quartz, adularia, carbonates with pyrite, electrum, sphalerite, galena, and polybasite. Gold contents of quartz veins are positively correlated with Ag, Zn, Pb, and Cu contents in both the northern and southern prospects. The quartz veins at the Jati, Gregah, and Sentul prospects have relatively lower gold‐silver ratios (Ag/Au = 23.2) compared to those at the Kojan, Dalangturu, Salak, and Suruh prospects (Ag/Au = 66.8). The quartz veins at the Dalangturu prospect are relatively rich in base metal sulfides. Ag/(Au+Ag) ratios of electrum in the Dalangturu prospect range from 45.2 to 65.0 at%, and FeS contents of sphalerite range from 1.2 to 6.4 mol%. Fluid inclusion microthermometry indicates ore‐forming temperatures of 190–200°C and 220–230°C at the Sentul and Kojan prospects, respectively. Widely variable vapor/liquid ratio of fluid inclusions indicates that fluid boiling took place within the hydrothermal system at the Sentul prospect. Salinities of ore‐fluids range from 0 to 0.7 wt% (av. 0.4 wt% NaCl equiv.) and from 0.5 to 1.4 wt% (av. 0.9 wt%) for the Sentul and Kojan prospects, respectively. The boiling of hydrothermal fluid was one of the gold deposition mechanisms in the Sentul prospect.  相似文献   
60.
Thermal waters in hydrothermal ponds, bathing pools and the brines of geothermal electric power plants commonly have a characteristic blue color. Although many researchers have assumed that the blue color is due to a colloidal suspension and/or absorption by dissolved ferrous iron or by water itself, there has been no specific effort to identify the physical nature of this phenomenon. We have tested, in synthetic and natural solutions, whether aqueous colloidal silica is responsible for the blue color. Aqueous colloidal silica is formed by silica polymerization in thermal waters of the neutral-chloride type which contain initially monomeric silica in concentrations up to three times above the solubilities of amorphous silica. The hue of the blue thermal waters in the pools tested agrees with that of a synthesized colloidal silica solution. Grain-size analyses of aqueous colloidal silica in the blue-colored thermal waters demonstrate that the color is caused by Rayleigh scattering from aqueous colloidal silica particles with diameters (0.1–0.45 μm) smaller than the wavelengths of visible radiation.  相似文献   
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