Zinc contamination in river water and sediments at Taisyu Zn–Pb mine area,Tsushima Island,Japan     

Naotatsu Shikazono  H.M. Zakir  Yuki Sudo 《Journal of Geochemical Exploration》2008

Tsushima Island is one of the oldest zinc-lead mining areas in Japan. River water and sediment samples were collected mainly from Taishu area to determine the contamination level of Zn and to clarify its behaviour in the natural system. Among the water samples analysed, 64% exceeded the standard environmental limit of 0.03 µg ml^− 1 for Zn. In most cases, Zn concentration in sediment samples also exceeded the standard value, and the concentration varied from 86.75–7490.07 µg g^− 1. The mineralogical constituents in sediments were almost similar and quartz had the strongest peak, but the interior part of the ores had many minerals, with galena having the highest proportion. Considering the enrichment factor values (EFc), 12 samples have values of more than 50, indicating a high pollution load for Zn. This study revealed that the sulphide ores, and contaminated sediments, are the possible contamination sources of Shiine River, and Zn dissolution occurred by reactions, such as desorption and ion exchange.  相似文献   

The roles of fluid transport and surface reaction in reaction-induced fracturing,with implications for the development of mesh textures in serpentinites     

Hiroyuki Shimizu  Atsushi Okamoto 《Contributions to Mineralogy and Petrology》2016,171(8-9):73

  相似文献   

Characterization of serpentinization in olivine-orthopyroxene-H2O system revealed by thermogravimetric and multivariate statistical analyses     

Atsushi Okamoto  Shuhei Tanaka  Masaoki Uno  Otgonbayar Dandar  Kazuki Yoshida 《Island Arc》2024,33(1):e12519

Thermogravimetric (TG) analyses were used to characterize the products and quantify the extent of serpentinization as a stepwise weight loss during heating (TG loss) or its derivative (DTG). Multivariate analyses are powerful tools for extracting information from complicated spectrum data; however, no studies have applied them to characterize serpentinites. In this study, hydrothermal experiments of olivine-H₂O, olivine–orthopyroxene-H₂O and orthopyroxene-H₂O were conducted at 250–400°C and under vapor-saturated pressure. The product minerals observed were serpentine+brucite+magnetite in the olivine-H₂O experiments and serpentine±talc in the orthoyroxene-H₂O and olivine-orthopyroxene-H₂O experiments. These results are consistent with those of previous studies; however, the positions and width of DTG peaks for individual minerals were varied depending on the experimental conditions. To extract systematics from the TG spectra, non-negative matrix factorization (NMF), an unsupervised machine learning technique, was applied to the DTG spectra of the experimental products. NMF revealed that the DTG profiles were explained by a linear combination of six basis spectra, which corresponded to the characteristic products, including three types of serpentine minerals (low-, medium-, and high-T), two types of brucite (low-and high-T), two type of talc (talc+serpentine mixture, well-crystallized talc) with different crystallinity, and noise during the TG measurement. Systematic changes in the factor loading revealed that, in the olivine-H₂O systems, the products changed from medium-T serpentine+low-T brucite to high-T serpentine+high-T brucite as serpentinization progressed. In the olivine-orthopyroxene system, low-T serpentine or poorly crystallized talc+serpentine mixture was initially formed, followed by the formation of well-crystallized talc, resulting in dehydration. Applying NMF to DTG showed the mineralogical differences between olivine and orthopyroxene systems and increases of the crystallinity during the progress of serpentinization, suggesting its potential for characterizing various serpentinites within oceanic lithospheres that suffer from several stages of alteration and weathering at different temperatures.  相似文献   

Hydrothermal activity in the Obiro deposit embedded in the Tagawa acidic rocks,Uetsu region,NE Japan     

Yuki Nakajima  Yuya Izumino  Shin‐ichi Kagashima  Kazuo Nakashima 《Resource Geology》2020,70(4):348-361

The Obiro deposit is located in the Tagawa Acidic Rocks (AR), Uetsu region, NE Japan. The Tagawa AR is composed of a volcanic phase of dacitic welded tuff and a plutonic phase of porphyritic granodiorite. Drill core and ore samples were collected from the deposit and examined by XRD, EPMA, and microthermometry. The drill core samples have suffered pervasively from sericite (illite) alteration, whereas pinkish K‐feldspar alteration halo occur close to veins. The results of EPMA and microthermometry is interpreted as that the magnatic‐hydrothermal fluids has changed as follows; the granodioritic magma intruded at about 1.0 kb and 700°C near the water‐saturated granite solidus; after cooling to about 500°C the fluids boiled according to a change in the pressure regime from lithostatic to hydrostatic; mixing with meteoric water led to sulfide mineralization at around 400°C or less. The main reasons for the mineralization in the Obiro deposit are as follows; the oxidized magma intruded at a shallower level, and thereafter hydrothermal fluids were boiled, resulting in a saline fluid. The saline fluid then dissolved metals such as Pb, Zn, Cu, and Bi, and these metals precipitated during cooling accompanied by dilution of the meteoric water and increasing pH, resulting in decreasing solubility.  相似文献   

Fluctuations in isothermal spheres     

Joseph Katz  Isao Okamoto 《Monthly notices of the Royal Astronomical Society》2000,317(1):163-169

Isolated isothermal spheres of N gravitationally interacting points with equal mass are believed to be stable when density contrasts do not exceed 709. That stability limit does not, however, take into consideration fluctuations of temperature near the onset of instability. These are important when N is finite.
Here we correlate global mean quadratic temperature fluctuations with the onset of instability. We show that such fluctuations trigger instability when the density contrast reaches a value near 709×exp(−3.3 N ^−1/3). These lower values of limiting density contrasts are significantly smaller than 709 when N is not very large, and this suggests (i) that numerical calculations with small N may not reflect correctly the onset of core collapse in clusters with large N , and (ii) that a greater number of globular clusters than is normally believed may already be in an advanced stage of core collapse, because most of the observed globular clusters with parameters that fit quasi-isothermal configurations are close to marginal stability.  相似文献   

Acceleration and collimation of magnetized winds     

Isao Okamoto 《Monthly notices of the Royal Astronomical Society》2000,318(1):250-262

  相似文献   

Reply to Comment on ‘Metamorphic olivine after dehydration embrittlement in Serpentinite: Case study from the Shiraga Serpentinite mass in the Sanbagawa high P/T metamorphic belt,central Shikoku,Japan’ by Wallis and Endo,https://doi.org/10.1111/iar.12328     

Seiya Fukumura  Kazuaki Okamoto  Masaru Terabayashi 《Island Arc》2020,29(1)

  相似文献   

Diffuse bifurcations engraving diverse shear bands in granular materials          下载免费PDF全文

Yuki Yamakawa  Kiyohiro Ikeda  Isao Saiki  Jacques Desrues  Reiko J. Tanaka 《国际地质力学数值与分析法杂志》2018,42(1):3-33

Shear bands with characteristic spatial patterns observed in an experiment for a cubic or parallelepiped specimen of dry dense sand were simulated by numerical bifurcation analysis using the Cam‐clay plasticity model. By incorporating the subloading surface concept into the plasticity model, the model became capable of reproducing hardening/softening and contractive/dilative behavior observed in the experiment. The model was reformulated to be compatible with the multiplicative hyperelasto‐plasticity for finite strains. This enhanced constitutive model was implemented into a finite‐element code reinforced by a stress updating algorithm based on the return‐mapping scheme, and by an efficient numerical procedure to compute critical eigenvectors of elastoplastic tangent stiffness matrix at bifurcation points. The emergence of diamond‐ and column‐like diffuse bifurcation modes breaking uniformity of the materials, followed by the evolution of shear bands through strain localization, was observed in the analysis. In the bifurcation analysis of plane strain compression test, unexpected bifurcation modes, which broke out‐of‐plane uniformity and led to 3‐dimensional diamond‐like patterns, were detected. Diffuse bifurcations, which were difficult to observe by experiments, have thus been found as a catalyst creating diverse shear band patterns.  相似文献   

Dark red debris from three short-period comets: 2P/Encke, 22P/Kopff, and 65P/Gunn     

Masateru Ishiguro  Yuki Sarugaku  Munetaka Ueno  Fumihiko Usui  Suk Minn Kwon 《Icarus》2007,189(1):169-183

We present observations of the extended dust structures near the orbits of three short-period comets: 2P/Encke, 22P/Kopff, and 65P/Gunn. The dust trails were originally discovered by the Infrared Astronomical Satellite (IRAS). Our observations were made using wide-field optical CCD cameras on the University of Hawaii 2.24-m telescope, the Canada-France-Hawaii 3.6-m telescope, and the Kiso 1.05-m Schmidt telescope. We compared the observed images with models and found that the extended structures seen around 2P/Encke and 22P/Kopff before perihelion passage were most likely “dust trails,” whereas images taken after perihelion passage show a high contamination by recently released particles (i.e., particles in Neck-Line structures are visible). We could not confirm the existence of a dust trail from 65P/Gunn within the field of view of the camera used. The effective sizes of the particles responsible for the scattered light were estimated at 1-100 mm (2P/Encke), 1-10 mm (22P/Kopff), and 100 μm-1 mm (65P/Gunn), respectively, which is consistent with previous studies of dust trails made with infrared space telescopes and optical telescopes. We evaluated the mass loss rates of these comets, averaged over their orbits, as reaching (2P/Encke), (22P/Kopff), and (65P/Gunn). These values are consistent with previous work. Therefore, the total amount of material ejected from these three comets is , which would contribute a considerable fraction of the lost within 1 AU that needs to be replaced if the zodiacal cloud is to be maintained in a steady state. We also found that the particles in the dust structures are significantly redder than the Sun and the zodiacal light, and might be redder than the average short-period comet nuclei. Specifically, the reflectivity gradients of 2P/Encke, 22P/Kopff, and 65P/Gunn are 13±7 (% ¹⁰³ Å⁻¹), 20±5 (% ¹⁰³ Å⁻¹), and 15±4 (% ¹⁰³ Å⁻¹), respectively. We examined the change in color with distance from the nucleus. No clear correlation was detected for 2P/Encke or 22P/Kopff to an accuracy of 3-11%, while the 65P/Gunn tail did show color variation, becoming redder with increasing distance from the nucleus. This dark red material, consisting of particles of sand-cobble size, has marginally escaped from the nuclei and will evolve into finer-grained interplanetary dust particles after subsequent collisions.  相似文献   

Microbial carbon cycling in oligotrophic regional aquifers near the Tono Uranium Mine, Japan as inferred from δC and ΔC values of in situ phospholipid fatty acids and carbon sources     

Christopher T. Mills  Yuki Amano  Gregory F. Slater  Teruki Iwatsuki  Kevin W. Mandernack 《Geochimica et cosmochimica acta》2010,74(13):3785-3805

Microorganisms are ubiquitous in deep subsurface environments, but their role in the global carbon cycle is not well-understood. The natural abundance δ¹³C and Δ¹⁴C values of microbial membrane phospholipid fatty acids (PLFAs) were measured and used to assess the carbon sources of bacteria in sedimentary and granitic groundwaters sampled from three boreholes in the vicinity of the Tono Uranium Mine, Gifu, Japan. Sample storage experiments were performed and drill waters analyzed to characterize potential sources of microbial contamination. The most abundant PLFA structures in all waters sampled were 16:0, 16:1ω7c, cy17:0, and 18:1ω7c. A PLFA biomarker for type II methanotrophs, 18:1ω8c, comprised 3% and 18% of total PLFAs in anoxic sedimentary and granitic waters, respectively, sampled from the KNA-6 borehole. The presence of this biomarker was unexpected given that type II methanotrophs are considered obligate aerobes. However, a bacterium that grows aerobically with CH₄ as the sole energy source and which also produces 56% of its total PLFAs as 18:1ω8c was isolated from both waters, providing additional evidence for the presence of type II methanotrophs. The Δ¹⁴C values determined for type II methanotroph PLFAs in the sedimentary (−861‰) and granite (−867‰) waters were very similar to the Δ¹⁴C values of dissolved inorganic carbon (DIC) in each water (∼−850‰). This suggests that type II methanotrophs ultimately derive all their carbon from inorganic sources, whether directly from DIC and/or from CH₄ produced by the reduction of DIC. In contrast, δ¹³C values of type II PLFAs in the sedimentary (−93‰) and granite (−60‰) waters indicate that these organisms use different carbon assimilation schemes in each environment despite very similar δ¹³C_CH4 values (∼−95‰) for each water. The δ¹³C_PLFA values (−28‰ to −45‰) of non-methanotrophic bacteria in the KNA-6 LTL water do not clearly distinguish between heterotrophic and autotrophic metabolisms, but Δ¹⁴C_PLFA values indicate that >65% of total bacteria filtered from the KNA-6 LTL water are heterotrophs. Ancient Δ¹⁴C values (∼−1000‰) of some PLFAs suggest that many heterotrophs utilize ancient organic matter, perhaps from lignite seams within the sedimentary rocks. The more negative range of δ¹³C_PLFA values determined for the KNA-6 granitic water (−42‰ to −66‰) are likely the result of a microbial ecosystem dominated by chemolithoautotrophy, perhaps fuelled by abiogenic H₂. Results of sample storage experiments showed substantial shifts in microbial community composition and δ¹³C_PLFA values (as much as 5‰) during 2-4 days of dark, refrigerated, aseptic storage. However, water samples collected and immediately filtered back in the lab from freshly drilled MSB-2 borehole appeared to maintain the same relative relationships between δ¹³C_PLFA values for sedimentary and granitic host rocks as observed for samples directly filtered under artesian flow from the KNA-6 borehole of the Tono Uranium Mine.  相似文献