Geochemistry of Late Permian to Early Triassic pelagic cherts from southwest Japan: implications for an oceanic redox change   总被引：4，自引：0，他引：4  

Yasuhiro Kato  Kyoko NakaoYukio Isozaki 《Chemical Geology》2002,182(1):15-34

Major, trace, and rare earth element abundances were determined for the southwestern Japanese pelagic chert sequence from the early Late Permian to early Early Triassic to investigate a redox change in deep-sea pelagic environments before and at the Permo-Triassic boundary (PTB) (251 Ma). The sequence was primarily deposited in the deep-sea of the superocean Panthalassa, and then was accreted to Japan in the Middle Jurassic. A remarkable lithostratigraphic change from red chert to siliceous∼carbonaceous claystone through gray chert is observed in this sequence. Constituent elements for these sedimentary rocks are essentially derived from two sources: (1) an ancient seawater via biogenic (mainly radiolarian), hydrothermal, and authigenic materials and (2) an average shale-like terrigenous material. The present measurement demonstrates significant stratigraphic changes of the Ce/Ce_non-ter* value (estimated Ce anomaly value of non-terrigenous component, recalculated by subtraction of terrigenous REEs from bulk REEs) and the (Mn/TE)_sample/(Mn/TE)_PAAS value (excess Mn component other than terrigenous one; TE=terrigenous elements including Ti, Al, Nb, Hf, Th; PAAS=Post-Archean Average Australian Shale) in the Permian chert. The Ce/Ce_non-ter* values increase from <0.2 to 1 and the (Mn/TE)_sample/(Mn/TE)_PAAS values decrease up-section, suggesting that the redox condition of deep-sea open-ocean changed from oxic to suboxic in an interval of approximately 10 Myr. The (∑Fe/TE)_sample/(∑Fe/TE)_PAAS and (Mn/TE)_sample/(Mn/TE)_PAAS values of carbonaceous claystone near or at the PTB are less than unity, suggesting that reductive dissolution of iron and manganese occurred under an anoxic condition. This supports the idea of the PTB oceanic anoxia in the superocean Panthalassa. The present data suggest that the anoxic condition prevailed in the deep-sea pelagic regions for an extremely long period, much more than 10 Myr, from the middle Late Permian to early Early Triassic. This long-term development of widespread oceanic anoxia may have been linked to the greatest mass extinction of the Phanerozoic.  相似文献   

Slake durability and mineralogical properties of some pyroclastic and sedimentary rocks   总被引：1，自引：0，他引：1  

Ganesh Dhakal  Tetsuro YonedaMasaji Kato  Katsuhiko Kaneko 《Engineering Geology》2002,65(1):31-45

Slake durability of rocks is an important property of rock-mass and rock-materials in geotechnical practice. The slake durability of rocks is closely related to their mineralogical composition. In this paper, mineralogical examinations and slake durability tests for argillaceous clastic rocks, especially pyroclastic rocks, sandstones and mudstones of Neogene Tertiary age from Japan, were performed in order to assess the slake durability and rock alteration process of these rocks as well as to understand the relationship between mineralogy and durability.The mineral composition and textural features of the rocks were studied by means of optical microscopy (OM), X-ray diffractometry (XRD), electron microprobe analysis (EPMA), and scanning electron microscopy (SEM). In addition, the slake durability test was carried out by using the standard testing method of ISRM [Int. J. Rock Mech. Min. Sci. 16 (1979) 148] in distilled water and in the aqueous solutions with dissolved electrolytes of NaCl and CaCl₂.The pyroclastic rocks and tuffaceous sandstone, rich in di-octahedral and tri-octahedral Fe smectite, respectively, show distinctively different slaking behaviors. The pyroclastic rocks show relatively high slaking (Id₂=55.5% and Id₁₀=10.5%) than the tuffaceous sandstone (Id₂=94.1% and Id₁₀=87.8%, refer to text for Id₂ and Id₁₀). This difference in the slake durability observed in these rocks is due to the microscopic occurrences of smectite present in the interspaces between the particles (pyroclastic rocks) and zeolite cementing the interspaces (tuffaceous sandstone) as alteration minerals. In addition, the durability results of tuffaceous sandstone show that the slake durability decreases as the degree of weathering increases (weathered material Id₂=88.7% and Id₁₀=65.3%). Furthermore, two mudstones of Miocene and Pliocene ages, having different clay mineral compositions (smectite vs. illite+chlorite), show the lowest and the highest slake durability among the tested clastic rocks. Hard mudstone shows the highest (Id₂=98.1% and Id₁₀=95.5%) while the soft mudstone shows the lowest (Id₂=33.9% and Id₆=0.4%.) slake durability. Thus, the slake durability of pyroclastic and sedimentary rocks is greatly affected by their mineral composition and texture, and is closely related to their alteration history. Slake durability is also affected by the kind of dissolved electrolyte and its concentration in the aqueous solution, providing some useful information for geotechnical practice.  相似文献   

Sea-floor fissures, biological communities and sediment fatty acids of the Northern Okushiri Ridge, Japan Sea: Implications for possible methane seepage   总被引：1，自引：0，他引：1  

Takeshi Naganuma  C. Julius Meisel  Hideki Wada  Yukihiro Kato  Akira Takeuchi  Katsunori Fujikura  Jiro Naka  & Kantaro Fujioka 《Island Arc》1999,8(2):232-244

A biological community was discovered in the Northern Okushiri Ridge, northeastern Japan Sea. The community was closely associated with sea-floor fissures, and presumed to be supported by methanotrophic and/or thiotrophic bacterial production. Sediments inside of and in the vicinity of the fissures were collected, and the short-chain (C_9–20) sediment fatty acids were analyzed for amounts and compositions. The fatty acid compositions were compared with those from a known methane seep and a submarine volcano in the Sagami Bay, central Japan, and from a whale skeleton at the Torishima Seamount, northwestern Pacific Ocean. As a result, a close relationship between the sediments from the Northern Okushiri Ridge, the known methane-seep, and the whale skeleton was found. This finding represents the first discovery of methane seepage and associated biological communities in the Japan Sea. This also supports the hypothesis that the eastern margin of the northern Japan Sea is at the early stage of new subduction.  相似文献   

Effect of canopy openness and meteorological factors on spatial variability of throughfall isotopic composition in a Japanese cypress plantation   总被引：1，自引：0，他引：1       下载免费PDF全文

Xinchao Sun  Yuichi Onda  Akiko Hirata  Hiroaki Kato  Takashi Gomi  Xueyan Liu 《水文研究》2018,32(8):1038-1049

Spatial variability of throughfall (TF) isotopic composition, used as tracer input, influences isotope hydrological applications in forested watersheds. Notwithstanding, identification of the dominant canopy factors and processes that affect the patterns of TF isotopic variability remains ambiguous. Here, we examined the spatio‐temporal variability of TF isotopic composition in a Japanese cypress plantation, in which intensive strip thinning was performed and investigated whether canopy structure at a fine resolution of canopy effect analysis is related to TF isotopic composition and how this is affected by meteorological factors. Canopy openness, as an index of canopy structure, was calculated from hemispherical photographs at different zenith angles. TF samples were collected in a 10 × 10 m experimental plot in both pre‐thinning (from July to November 2010) and post‐thinning (from May 2012 to March 2013) periods. Our results show that thinning resulted in a smaller alteration of input δ¹⁸O of gross precipitation, whereas the changes in deuterium excess varied in both directions. Despite the temporal stability of spatial patterns in TF amount, the spatial variability of TF isotopic composition was not temporally stable in both pre‐ and post‐thinning periods. Additionally, after thinning, the isotopic composition of TF was best related to canopy openness calculated at the zenith angle of 7°, exhibiting three different relationships, that is, significantly negative, significantly positive, and nonsignificant. Changes in meteorological factors (wind speed, rainfall intensity, and temperature) were found to affect the relationships between TF δ¹⁸O and canopy openness. The observed shifts in the relationships reveal different dominant factors (partial evaporation and the selection), and canopy water flowpaths control such differences. This study provides useful insights into the spatial variability of TF isotopic composition and improves our understanding of the physical processes of interception through canopy passage.  相似文献   

Probabilistic description of the first-order Fermi acceleration in shock waves: time-dependent solution by the single-particle approach     

Tsunehiko N. Kato †  Fumio Takahara 《Monthly notices of the Royal Astronomical Society》2003,342(2):639-650

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A synthetic seismicity model for the Xianshuihe fault, southwestern China: simulation using a rate- and state-dependent friction law   总被引：1，自引：0，他引：1  

Naoyuki Kato  Xinglin Lei  Xueze Wen 《Geophysical Journal International》2007,169(1):286-300

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Estimating groundwater storage changes in the Mississippi River basin (USA) using GRACE   总被引：7，自引：0，他引：7  

Matthew Rodell  Jianli Chen  Hiroko Kato  James S. Famiglietti  Joe Nigro  Clark R. Wilson 《Hydrogeology Journal》2007,15(1):159-166

Based on satellite observations of Earth’s time variable gravity field from the Gravity Recovery and Climate Experiment (GRACE), it is possible to derive variations in terrestrial water storage, which includes groundwater, soil moisture, and snow. Given auxiliary information on the latter two, one can estimate groundwater storage variations. GRACE may be the only hope for groundwater depletion assessments in data-poor regions of the world. In this study, soil moisture and snow were simulated by the Global Land Data Assimilation System (GLDAS) and used to isolate groundwater storage anomalies from GRACE water storage data for the Mississippi River basin and its four major sub-basins. Results were evaluated using water level records from 58 wells set in the unconfined aquifers of the basin. Uncertainty in the technique was also assessed. The GRACE-GLDAS estimates compared favorably with the well based time series for the Mississippi River basin and the two sub-basins that are larger than 900,000 km². The technique performed poorly for the two sub-basins that have areas of approximately 500,000 km². Continuing enhancement of the GRACE processing methods is likely to improve the skill of the technique in the future, while also increasing the temporal resolution.  相似文献   

Application of random walk theory to the first-order Fermi acceleration in shock waves     

T. N. Kato  F. Takahara 《Monthly notices of the Royal Astronomical Society》2001,321(4):642-660

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A deep near-infrared survey around the giant radio galaxy PKS 1343–601     

T. Nagayama  P. A. Woudt  C. Nagashima  Y. Nakajima  D. Kato  M. Kurita  T. Nagata  H. Nakaya  M. Tamura  K. Sugitani  K. Wakamatsu  S. Sato 《Monthly notices of the Royal Astronomical Society》2004,354(4):980-990

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Infall of gas from intergalactic space and soft x-ray background     

Makoto Tosa  Takako Kato 《Astrophysics and Space Science》1972,18(2):504-513

As the origin of the soft X-ray background, emission of soft X-rays from shocks occurred in the accretion of intergalactic gas onto the Galaxy is studied. Infall of discrete gas clouds cannot explain the diffuse component of soft X-rays. If intergalactic gas rich in heavy elements as the cosmic abundance continously flows into the Galaxy and forms a standing shock surrounding the Galaxy, the line emissions by heavy elements from the shocked gas explain the soft X-ray background. Formation of the high velocity cloud by thermal instability in the shocked gas is also discussed briefly.  相似文献