Investigation of gas content of organic-rich shale:A case study from Lower Permian shale in southern North China Basin,central China     

Wei Dang  Jin-Chuan Zhang  Xuan Tang  Xiao-Liang Wei  Zhong-Ming Li  Cheng-Hu Wang  Qian Chen  Chong Liu 《地学前缘(英文版)》2018,9(2):559-575

Measuring gas content is an essential step in estimating the commerciality of gas reserves. In this study,eight shale core samples from the Mouye-1 well were measured using a homemade patented gas desorption apparatus to determine their gas contents. Due to the air contamination that is introduced into the desorption canister, a mathematical method was devised to correct the gas quantity and quality.Compared to the chemical compositions of desorbed gas, the chemical compositions of residual gas are somewhat different. In residual gas, carbon dioxide and nitrogen record a slight increase, and propane is first observed. This phenomenon may be related to the exposure time during the transportation of shale samples from the drilling site to the laboratory, as well as the differences in the mass, size and adsorptivity of different gas molecules. In addition to a series of conventional methods, including the USBM direct method and the Amoco Curve Fit(ACF) method, which were used here for lost gas content estimation, a Modified Curve Fit(MCF) method, based on the 'bidisperse' diffusion model, was established to estimate lost gas content. By fitting the ACF and MCF models to gas desorption data, we determined that the MCF method could reasonably describe the gas desorption data over the entire time period, whereas the ACF method failed. The failure of the ACF method to describe the gas desorption process may be related to its restrictive assumption of a single pore size within shale samples. In comparison to the indirect method, this study demonstrates that none of the three methods studied in this investigation(USBM, ACF and MCF) could individually estimate the lost gas contents of all shale samples and that the proportion of free gas relative to total gas has a significant effect on the estimation accuracy of the selected method. When the ratio of free gas to total gas is lower than 45%, the USBM method is the best for estimating the lost gas content, whereas when the ratio ranges from 45% to 75% or is more than 75%, the ACF and MCF methods, are the best options respectively.  相似文献   

Geochemistry of organic matter and elements of black shale during weathering in Northern Guizhou,Southwestern China: Their mobilization and inter-connection     

Xuan Tang  Jinchuan Zhang  Yang Liu  Chao Yang  Qian Chen  Wei Dang  Panwang Zhao 《Chemie der Erde / Geochemistry》2018,78(1):140-151

Different from previous studies on effect of weathering upon geochemical variation along a single weathered profile, this paper provides a new methodology validated by comparing a weathered outcrop samples and their stratigraphic counterpart un-weathered core samples in a nearby shallow borehole. This outcrop and borehole penetrated the Ordovician-Silurian Wufeng–Longmaxi shales, located in the same anticline structure in the northern part of Guizhou Province, Southern China. The mineral composition, major, trace and rare earth elements (REEs) composition and Rock-Eval parameters of outcrop and core samples were analyzed and compared. Organic matter (OM) was observed in the microscope and extracted for elements analysis. The results show that short-term weathering still has significant influence on OM, mineral and elemental composition of black shales. The elements composition shows the outcrop profile was moderately weathered. The REEs compositions do not alter much during weathering process and the REEs composition and their relative ratios still are valid for rock origin determination. The OM, mainly composed by graptolite and bitumen, even entering the highly-over thermal maturity, is still sensitive to the weathering with a systematic loss 30–50% of TOC along the outcrop profile, which suggests that the OM consumption is predominantly controlled by weathering duration and the distance from the weathering surface. In turn, OM has significant influence on the trace elements transportation behavior during weathering. Some trace elements associated with the OM such as V, Cr, Th, U, Ni and Co, change significantly in their absolute concentration during weathering, but their relative ratios do not necessarily change too much and might be still reliable proxies for paleo-environmental determination. The mobility of shale minerals during weathering is in the following order: plagioclase?>?potassium feldspar and dolomite >pyrite and OM. Short-term weathering can also result in considerable transportation of elements and significant variation of minerals content in black shale, which may pose potentially high environmental and engineering risk in the regions rich in black shale.  相似文献   

内蒙古特拜金矿流体包裹体特征与成矿作用     

杨轩 《地质与勘探》2018,54(5):877-889

华北地台北缘西段是我国重要的金矿成矿区,目前为止已发现了浩尧尔忽洞、朱拉扎嘎、赛乌素、碱泉子、卡修他他等多个规模不等、不同成因的的金矿床,显示出较大的成矿潜力。特拜金矿是近年来在华北地台北缘西段新发现的一个中型金矿。为探索该金矿的成矿机制,本文对特拜金矿开展了矿床地质和流体性质研究。结果表明,特拜金矿-赋存于早古生代的碳质板岩、碳质千枚岩中。矿体展布受黑色岩系、NW向F2断裂带和NE向F8断裂带的共同控制。矿区周边出露华力西期特拜石英闪长岩和管材陶鲁盖花岗岩等岩浆岩。该金矿从早期成矿阶段到晚期成矿阶段,流体包裹体的均一温度从300℃~350℃逐渐降低到150℃~200℃,盐度从16wt%NaCleqv~20wt%NaCleqv逐渐降低到1wt%NaCleqv ~4wt%NaCleqv;流体的气相组成以CH4-N2-CO2为特征,δDV-SMOW为-91.6‰~-84.5‰,δ18OH2O为2.8‰~3.5‰之间,流体相对富集Ba、Pb、Sr等元素,相对亏损Rb、Th、Nb、Zr、Y、Yb等元素。成矿流体主要来源于岩浆期后热液,可能混合了少量的大气降水。成矿流体处于一种还原性、低温的环境下,金在流体中以Au(HS) 2- 络合物的形式迁移。流体向上运移过程中,因温度、压力的降低而发生不混溶现象,并导致金的沉淀。  相似文献   

北衙金矿多期热液成矿作用识别:来自地质、岩相学、流体包裹体和H-O-S同位素证据   总被引：2，自引：2，他引：0  

王璇  杨林  邓军  李华健  于华之  董超一 《岩石学报》2018,34(5):1299-1311

北衙超大型金矿床是三江特提斯成矿域中喜山期斑岩-矽卡岩型矿床的典型代表,长期以来大量研究均围绕斑岩-矽卡岩成矿作用开展并取得了丰硕成果,然而对于北衙金矿是否存在多期热液成矿作用尚不明确。本次研究基于详细野外调查、岩相学与矿相学研究,流体包裹体显微测温及成分分析、H-O-S同位素分析等多种手段,识别了北衙金矿成矿晚期存在新一期热液成矿事件。主要证据如下:(1)野外调查发现北衙金矿发育NW向陡倾断裂控制的石英多金属硫化物脉,其切割矽卡岩矿体与矽卡岩晚期石英硫化物矿脉;(2)本次研究矿脉中原生流体包裹体类型主要为富CO_2三相水溶液包裹体、含CO_2三相水溶液包裹体及气液两相水溶液包裹体,而矽卡岩晚期硫化物脉中除上述三种类型外还发育含子晶三相水溶液包裹体;(3)成矿流体均一温度分布范围为204～426℃,盐度为1.0%～14.2%NaCleqv,整体表现为中高温、中低盐度的NaCl-CO_2-H_2O流体体系,而矽卡岩晚期硫化物脉成矿流体体系具有中温、中高盐度的特征;(4)该矿脉中石英的δ~(18)O、δD范围分别为7.5‰～9.4‰与-102.0‰～-75.0‰,指示岩浆水来源,而矽卡岩晚期硫化物脉具有岩浆水和大气水混合来源。本次研究的多金属硫化物矿脉δ~(34)S值范围为-0.97‰～1.40‰,与矽卡岩期和矽卡岩晚期硫化物脉中黄铁矿S同位素一致,表明多期矿化成矿物质均具有幔源贡献。结合北衙矿集区成岩成矿动力学背景,推测始新世大规模地壳拆沉、软流圈上涌导致的强烈的壳幔相互作用可能是北衙金矿多期成矿作用的诱因。  相似文献   

面向矿产资源信息的空间关联性分析   总被引：2，自引：1，他引：1  

常力恒  朱月琴  张戈一  张旋  胡博然 《岩石学报》2018,34(2):314-318

关联性分析是综合多源、多类数据,发现和挖掘数据中潜在的相关关系,提取和挖掘数据之间的关联性。该方法对于充分利用地质大数据、发现地质要素之间的共生组合规律具有重要的意义。本文首先基于数据的空间位置,将不同类型的地质空间数据建立联系,形成空间属性数据库;其次应用统计方法,对不同来源数据中的属性特征进行分析,发现热液型金矿的形成与火山作用存在明显相关性;最后基于Apriori算法提取热液型金矿的伴生矿与侵入岩的频繁项集,发现伴生矿与侵入岩酸碱性二者密切相关。因此,在今后的工作中,有望应用空间关联性的方法对地球物理、地球化学、遥感等多源地质数据开展深入的研究分析。  相似文献   

Intraseasonal oscillation of the rainfall variability over Rwanda and evaluation of its subseasonal forecasting skill          下载免费PDF全文

Xuan Zhou  Lin Chen  Janet Umuhoza  Yifeng Cheng  Lu Wang  Ran Wang 《大气和海洋科学快报》2021,14(6):60-65

非洲中东部地区的经济主要依靠自给农业支撑,该地区农业经济对降水的变化尤为敏感.本文以卢旺达为例,观测分析指出卢旺达的次季节降雨主要集中在10-25天;根据次季节尺度降水变率的单点相关方法,发现卢旺达的次季节降水变率和周围区域变化一致;进一步合成结果显示该地区次季节降水变率与异常西风有关,这可追溯到赤道地区西传的赤道Rossby波.最后,本文评估了当前动力模式ECMWF对 卢旺达地区(即非洲中东部)次季节降水变率的预报能力,发现EC模式在对该区域降水和相关风场指数的预报技巧都在18天左右,且预报技巧表现出一定的年际差异,这可能与热带太平洋的背景海温信号有关.该工作增进了当 前对非洲中东部地区的次季节降水变率和预测水平的认知,并且对该地区国家粮食安全和防灾减灾具有启示性意义.  相似文献   

Intraseasonal oscillation of the southwest monsoon over Sri Lanka and evaluation of its subseasonal forecast skill          下载免费PDF全文

L.A.D.Buddika Bandurathna  Lu Wang  Xuan Zhou  Yifeng Cheng  Lin Chen 《大气和海洋科学快报》2021,14(6):7-13

斯里兰卡的雨季发生于5-9月间,主要受西南季风的控制.本文发现该地区的西南季风降水存在很强的次季节变率,主导周期为10-35天.降水的季节内变化与西传的异常气旋有关.进一步,利用S2S比较计划中欧洲中心的数值预报模式(ECMWF)提供的回报试验数据,评估了当今动力模式对斯里兰卡西南季风次季节变化的预报技巧.结果显示,对季风指数的预测技巧超过30天,而对降水指数的预测技巧大约两周,且模式的预报技巧具有明显的年际差异.分析表明,能否正确模拟出大尺度环流对热带对流的响应是影响斯里兰卡降水预测的重要因子.  相似文献   

基于多尺度特征融合网络的云和云阴影检测试验     

杨昌军  张秀再  张晨  冯绚  刘瑞霞 《大气科学》2021,45(6):1187-1195

基于深度学习的高分辨率光学影像云检测过程中,云和云阴影及其边缘细节丢失较为严重,主要原因在于不同尺度空间语义信息特征融合存在不足。针对该问题,本文构建一种基于深度学习的多尺度特征融合网络（Multi-scale Feature Fusion Network, MFFN）的云和云阴影检测方法,该算法结合防止网络退化的残差神经网络模块（Res.block）、扩大网络感受野的多尺度卷积模块（MCM）和提取并融合不同尺度信息的多尺度特征模块（MFM）。试验表明,本算法能提取丰富的空间信息与语义信息,可取得较为精细的云与云阴影掩模,具有较高检测精度,其中云检测准确率达0.9796,云阴影检测准确率达0.8307。同时,该工作可为深度学习技术应用于业务云检测提供理论支持及技术储备。  相似文献   

An improved ionosphere interpolation algorithm for network RTK in low-latitude regions     

Jianhui Cui  Weiming Tang  Lei Jin  Chenlong Deng  Xuan Zou  Shengfeng Gu 《GPS Solutions》2018,22(4):109

A traditional interpolation algorithm with the linear interpolation method (LIM) using a fixed number of reference stations is widely used in network RTK to obtain the ionospheric delays for the users. In low-latitude regions, where the ionosphere is relatively active, however, large interpolation errors exist, especially for satellites at low elevation angles. Considering the characteristics of “coinciding ionospheric pierce points (CIPPs)” with a similar nature of ionospheric delays, an improved interpolation algorithm is proposed. In this algorithm, all stations with CIPPs are used to establish the interpolation model; thus, more precise interpolation model is achieved. To validate the performance of the proposed algorithm, data from some reference stations in Guangdong Province of China were used, and the results are compared with those with the traditional interpolation algorithm. Numerical analysis shows that the interpolation accuracy of the proposed algorithm increases by 10–30% compared with the traditional one. Since the number of reference stations is flexible, the proposed algorithm can also balance the model accuracy with the computation burdens. In addition, the proposed algorithm is less affected by the selection of master reference station. In terms of network RTK on-the-fly positioning, the time-to-first-fix is reduced when replacing the traditional interpolation algorithm with the proposed one.  相似文献   

宣城地区龙潭组页岩沉积环境与有机质富集     

丁江辉  张金川  石刚  申宝剑  唐玄  杨振恒  李兴起  李楚雄 《沉积学报》2021,39(2):324-340

安徽宣城地区上二叠统龙潭组海陆过渡相页岩不仅是我国下扬子区重要的烃源岩,也是目前我国页岩气勘探的重要层位之一。为研究海陆过渡相页岩沉积环境与有机质富集的关系,以港地1井和两个露头剖面为研究对象,系统开展了有机地球化学测试、有机岩石学研究、氩离子抛光—扫面电镜观察、元素地球化学分析等工作。结果表明:下扬子宣城地区龙潭组页岩沉积时期处于暖湿型气候,沉积水体处于氧化—贫氧状态,具有高的生物生产力和沉积速率。海陆过渡相富有机质页岩的形成,不是由单一因素所决定的,而是由古气候、水体氧化还原性质、古生产力、沉积速率等多个要素相互配置与耦合的结果,这些因素都会直接或者间接地影响有机质的供给或者有机质的埋藏和保存。其中,温湿型气候不仅有利于陆源高等植物的生长,而且会促进生物地球化学作用,使得母岩化学风化程度加大,向水体输入的营养物质增多,有利于菌藻类等低等水生生物勃发,高等植物碎屑和低等水生生物共同为富有机质页岩沉积提供了丰富的有机质来源。宣城地区晚二叠世沉积时期,较高的古生产力为海陆过渡相富有机质页岩的形成提供了良好的物质基础,有机质产生后进一步埋藏和保存,虽然富氧水体环境不利于有机质保存,但高的沉积速率可以缩短有机质在富氧水体中暴露的时间,使得有机质来不及被氧化或分解,也可造成有机质的富集。  相似文献