Tectonic evolution of the Brian?onnais units along a transect (ECORS-CROP) through the Italian-French Western Alps     

Stefan Bucher  Christina Ulardic  Romain Bousquet  Stefano Ceriani  Bernhard Fügenschuh  Yves Gouffon  Stefan M. Schmid 《Eclogae Geologicae Helvetiae》2004,97(3):321-345

  相似文献   

Heliocentric evolution of the degradation of polyoxymethylene: Application to the origin of the formaldehyde (H₂CO) extended source in Comet C/1995 O1 (Hale-Bopp)     

Nicolas Fray  Yves Bénilan  Dominique Bockelée-Morvan  Jacques Crovisier 《Icarus》2006,184(1):239-254

The H₂CO production rates measured in Comet C/1995 O1 (Hale-Bopp) from radio wavelength observations [Biver, N., and 22 colleagues, 2002a. Earth Moon Planets 90, 5-14] showed a steep increase with decreasing heliocentric distance. We studied the heliocentric evolution of the degradation of polyoxymethylene (formaldehyde polymers: (CH₂O)_n, also called POM) into gaseous H₂CO. POM decomposition can indeed explain the H₂CO density profile measured in situ by Giotto spacecraft in the coma of Comet 1P/Halley, which is not compatible with direct release from the nucleus [Cottin, H., Bénilan, Y., Gazeau, M.-C., Raulin, F., 2004. Icarus 167, 397-416]. We show that the H₂CO production curve measured in Comet C/1995 O1 (Hale-Bopp) can be accurately reproduced by this mechanism with a few percents by mass of solid POM in grains. The steep heliocentric evolution is explained by the thermal degradation of POM at distances less than 3.5 AU. This study demonstrates that refractory organics present in cometary dust can significantly contribute to the composition of the gaseous coma. POM, or POM-like polymers, might be present in cometary grains. Other molecules, like CO and HNC, might also be produced by a similar process.  相似文献   

Spatio-temporal Variability Sea Level Pressure （SLP） the Mid-to-Low Reaches of Northern Hemipheric and Precipitation over of the Yangtze River   总被引：1，自引：0，他引：1  

韩雪  魏凤英  董文杰 《大气科学进展》2008,25(3):458-466

The spatio-temporal variability of Northern Hemisphere Sea Level Pressure （SLP） and precipitation over the mid-to-low reaches of the Yangtze River （PMLY） is analyzed jointly using the multi-taper/singular value decomposition method （MTM-SVD）. Statistically significant narrow frequency bands are obtained from the local fractional variance （LFV） spectrum. Significant interdecadal （i.e., 16-to-18-year periods） and interannual （i.e., 3-to-6-year periods） signals are identified. Moreover, a significant quasi-biennial signal is identified but only for PMLY data. The spatial joint evolution of patterns obtained for peaks in the LFV spectrum sheds light on relationships between SLP and PMLY： the Arctic Oscillation （AO） modulates the variability of the PMLY while the interannual variability of PMLY is in phase with the Northern Atlantic Oscillation （NAO） and the Northern Pacific Oscillation （NPO）.  相似文献   

Duality properties of Gorringe–Leach equations     

Yves Grandati  Alain Bérard  Hervé Mohrbach 《Celestial Mechanics and Dynamical Astronomy》2009,103(2):133-141

In the category of motions preserving the angular momentum direction, Gorringe and Leach exhibited two classes of differential equations having elliptical orbits. After enlarging slightly these classes, we show that they are related by a duality correspondence of the Arnold–Vassiliev type. The specific associated conserved quantities (Laplace–Runge–Lenz vector and Fradkin–Jauch–Hill tensor) are then dual reflections of each other.  相似文献   

Ab initio quantum mechanical study of γ-AlOOH boehmite: structure and vibrational spectrum     

Yves Noel  Raffaella Demichelis  Fabien Pascale  Piero Ugliengo  Roberto Orlando  Roberto Dovesi 《Physics and Chemistry of Minerals》2009,36(1):47-59

The structure and vibrational spectrum of boehmite have been investigated at the quantum-mechanical level with the CRYSTAL code, using a Gaussian-type basis set and the B3LYP Hamiltonian. Three space groups are considered in this study: Cmcm, Cmc2₁, P2₁/c. Cmcm turns out to correspond to a transition state, whereas Cmc2₁ and P2₁/c are minimum energy structures. The difference among them is the position of H atoms only, the Al-O frame being essentially the same. Harmonic frequencies at the Γ point have been computed. The comparison between calculated and experimental frequencies shows a good agreement for the Al-O part of the spectrum (under 790 cm⁻¹). For the Al-OH bending modes (800–1,300 cm⁻¹) an absolute differences of 50–100 cm⁻¹ is observed; for the OH stretching modes (3,200–3,500 cm⁻¹) it increases to 120–200 cm⁻¹: anharmonicity is large because OH groups are involved in strong hydrogen bonds.  相似文献   

Long-term groundwater resource observatory for Southwestern Madagascar     

Simon D. Carrière  Thomas Health  Pascale F. M. Rakotomandrindra  Chloé Ollivier  Riva E. Rajaomahefasoa  Heritiana A. Rakoto  Jean Lapègue  Yves E. Rakotoarison  Marie Mangin  Jean Kempf  Théodore Razakamanana  Konstantinos Chalikakis 《水文研究》2021,35(3):e14108

Madagascar has one of the highest poverty rates in the world and consequently the long-term monitoring of groundwater resources is not a priority for the authorities. However, groundwater is often the only sustainable resource that has a satisfactory quality to supply the population. This is especially true in the south-west of the country, which is a semi-arid region and a global change hot spot (intense land use and climate changes). In response to the lack of data, the Groundwater Resource Observatory for Southwestern Madagascar (GROSoM) was established to monitor piezometry and meteorology over the longer term as part of a humanitarian response. The first site was setup in 2014 in a catchment located over a carbonate plateau; in 2018, a second site was installed in an alluvial setting within a crystalline basement catchment and a third site will be installed in 2020 to monitor groundwater dynamics in a coastal setting. The three sites, located between Toliara and Taolagnaro cities, are complementary and representative of various hydrogeological systems in Southwestern Madagascar. Each site includes a weather station and between 3 and 6 piezometric probes. The monitoring data indicate a strong inter-annual variability in precipitation, which induces a strong variability in aquifers recharge. One of the driest years in 2016 seems to be consistent with strong El Niño – Southern Oscillation (ENSO) effects observed at the global scale, while years with higher recharge appear to be related to cyclones such as Fundi in 2015 and Eketsang in 2019. Preliminary results of cross-disciplinary studies demonstrated a link between groundwater and health issues (i.e., admissions to basic health centres). This observatory aims to produce long-term data and has two objectives: (i) strengthening the early warning system for humanitarian crises in Madagascar; (ii) contributing to a better understanding of the effects of climate change on groundwater resources in this semi-arid region.  相似文献   

Spectral and geological study of the sulfate-rich region of West Candor Chasma, Mars     

Nicolas Mangold  Aline Gendrin  Stephane LeMouelic  Véronique Ansan  Yves Langevin  Gerhard Neukum 《Icarus》2008,194(2):519-543

Sulfates have been discovered by the OMEGA spectrometer in different locations of the planet Mars. They are strongly correlated to light toned layered deposits in the equatorial regions. West Candor Chasma is the canyon with the thickest stack of layers and one with the largest area covered by sulfates. A detailed study coupling mineralogy derived from OMEGA spectral data and geology derived from HRSC imager and other datasets leads to some straightforward issues. The monohydrated sulfate kieserite is found mainly over heavily eroded scarps of light toned material. It likely corresponds to a mineral present in the initial rock formed either during formation and diagenesis of sediments, or during hydrothermal alteration at depth, because it is typically found on outcrops that are eroded and steep. Polyhydrated sulfates, that match any Ca-, Na-, Fe-, or Mg-sulfates with more than one water molecule, are preferentially present on less eroded and darker outcrops than outcrops of kieserite. These variations can be the result of a diversity in the composition and/or of the rehydration of kieserite on surfaces with longer exposure. The latter possibility of rehydration in the current, or recent, atmosphere suggests the low surface temperatures preserve sulfates from desiccation, and, also can rehydrate part of them. Strong signatures of iron oxides are present on sulfate-rich scarps and at the base of layered deposits scarps. They are correlated with TES gray hematite signature and might correspond to iron oxides present in the rock as sand-size grains, or possibly larger concretions, that are eroded and transported down by gravity at the base of the scarp. Pyroxenes are present mainly on sand dunes in the low lying terrains. Pyroxene is strongly depleted or absent in the layered deposits. When mixed with kieserite, local observations favor a spatial mixing with dunes over layered deposits. Sulfates such as those detected in the studied area require the presence of liquid water to form by precipitation, either in an intermittent lacustrine environment or by hydrothermal fluid circulation. Both possibilities require the presence of sulfur-rich groundwater to explain fluid circulation. The elevation of the uppermost sulfate signatures suggests the presence of aquifers up to 2.5 km above datum, only 1 km below the plateau surface.  相似文献   

Snow cover monitoring in the Northern Patagonia Icefield using MODIS satellite images (2000–2006)     

Paulina Lopez  Pascal Sirguey  Yves Arnaud  Bernard Pouyaud  Pierre Chevallier 《Global and Planetary Change》2008,61(3-4):103-116

The snow cover of the Northern Patagonia Icefield (NPI) was monitored after applying the Normalized Difference Snow Index (NDSI) and the Red/NIR band ratio to 134 Moderate Resolution Imaging Spectroradiometer (MODIS) images captured between 2000 and 2006. The final results show that the snow cover extent of the NPI fluctuates a lot in winter, in addition to its seasonal behaviour. The minimum snow cover extent of the period (3600 km²) was observed in March 2000 and the maximum (11,623 km²) in August 2001. We found that temperature accounts for approximately 76% of the variation of the snow cover extent over the entire icefield. We also show two different regimes of winter snow cover fluctuations corresponding to the eastern and the western sides of the icefield. The seasonality of the snow cover on the western side was determined by temperature rather than precipitation, while on the east side the seasonality of the snow cover was influenced by the seasonal behaviour of both temperature and precipitation. This difference can be explained by the two distinct climates: coastal and continental. The fluctuations in the winter snow cover extent were more pronounced and less controlled by temperature on the western side than on the eastern side of the icefield. Snow cover extent was correlated with temperature R² = 0.75 and R² = 0.74 for the western and eastern sides, respectively. Since limited meteorological data are available in this region, our investigation confirmed that the change in snow cover is an interesting climatic indicator over the NPI providing important insights in mass balance comprehension. Since snow and ice were distinguished snow cover fluctuations can be associated to fluctuations in the snow accumulation area of the NPI. In addition, days with minimum snow covers of summer season can be associated to the period in which Equilibrium Line Altitude (ELA) is the highest.  相似文献   

Detection of C₂HD and the D/H ratio on Titan     

Athena Coustenis  Donald E. Jennings  Yves Bénilan  Sandrine Vinatier  Gordon L. Bjoraker  Ronald C. Carlson 《Icarus》2008,197(2):539-548

We report here the first detection of mono-deuterated acetylene (acetylene-d1, C₂HD) in Titan's atmosphere from the presence of two of its emission bands at 678 and 519 cm⁻¹ as observed in CIRS spectral averages of nadir and limb observations taken between July 2004 and mid-2007. By using new laboratory spectra for this molecule, we were able to derive its abundance at different locations over Titan's disk. We find the C₂HD value () to be roughly constant with latitude from the South to about 45° N and then to increase slightly in the North, as is the case for C₂H₂. Fitting the 678 cm⁻¹ν₅ band simultaneously with the nearby C₂H₂ 729 cm⁻¹ν₅ band, allows us to infer a D/H ratio in acetylene on Titan with an average of the modal values of 2.09±0.45×¹⁰⁻⁴ from the nadir observations, the uncertainties being mainly due to the vertical profile used for the fit of the acetylene band. Although still subject to significant uncertainty, this D/H ratio appears to be significantly larger than the one derived in methane from the CH₃D band (upper limit of 1.5×¹⁰⁻⁴; Bézard, B., Nixon, C.A., Kleiner, I., Jennings, D.E., 2007. Icarus, 191, 397-400; Coustenis, A., Achterberg, R., Conrath, B., Jennings, D., Marten, A., Gautier, D., Bjoraker, G., Nixon, C., Romani, P., Carlson, R., Flasar, M., Samuelson, R.E., Teanby, N., Irwin, P., Bézard, B., Orton, G., Kunde, V., Abbas, M., Courtin, R., Fouchet, Th., Hubert, A., Lellouch, E., Mondellini, J., Taylor, F.W., Vinatier, S., 2007. Icarus 189, 35-62). From the analysis of limb data we infer D/H values of (at 54° S), (at 15° S), (at 54° N) and (at 80° N), which average to a mean value of 1.63±0.27×¹⁰⁻⁴.  相似文献   

Holocene vegetation dynamics and hydrological variability in forested peatlands of the Clay Belt,eastern Canada,reconstructed using a palaeoecological approach     

Gabriel Magnan  loise Le Stum‐Boivin  Michelle Garneau  Pierre Grondin  Nicole Fenton  Yves Bergeron 《Boreas: An International Journal of Quaternary Research》2019,48(1):131-146

Forested peatlands are widespread in boreal regions of Canada, and these ecosystems, which are major terrestrial carbon sinks, are undergoing significant transformations linked to climate change, fires and human activities. This study targets millennial‐scale vegetation dynamics and related hydrological variability in forested peatlands of the Clay Belt south of James Bay, eastern Canada, using palaeoecological data. Changes in peatland vegetation communities were reconstructed using plant macrofossil analyses, and variations in water‐table depths were inferred using testate amoeba analyses. High‐resolution analyses of macroscopic charcoal >0.5 mm were used to reconstruct local fire history. Our data showed two successional pathways towards the development of present‐day forested peatlands influenced by autogenic processes such as vertical peat growth and related drying, and allogenic factors such as the occurrence of local fires. The oldest documented peatland initiated in a wet rich fen around 8000 cal. a BP shortly after land emergence and transformed into a drier forested bog rapidly after peat inception that persisted over millennia. In the second site, peat started to accumulate from ~5200 cal. a BP over a mesic coniferous forest that shifted into a wet forested peatland following a fire that partially consumed the organic layer ~4600 cal. a BP. The charcoal records show that fires rarely occurred in these peatlands, but they have favoured the process of forest paludification and influenced successional trajectories over millennia. The macrofossil data suggest that Picea mariana (black spruce) persisted on the peatlands throughout their development, although there were periods of more open canopy due to local fires in some cases. This study brings new understanding on the natural variability of boreal forested peatlands which may help predict their response to future changes in climate, fire regimes and anthropogenic disturbances.  相似文献