Production and Certification of Synthetic Selenium Isotopic Reference Materials          下载免费PDF全文

Tongxiang Ren  Jun Wang  Hai Lu  Tao Zhou  Yuanjing Zhou 《Geostandards and Geoanalytical Research》2016,40(2):227-238

Due to intensive research into selenium isotopes in recent years, the increasing requirement for reliable and comparable measurement results has created a strong demand for selenium isotopic certified reference materials (iCRM) that were previously not available. To address this, eleven selenium iCRMs were developed, including ten synthetic iCRMs (GBW 04447–GBW 04456) and one natural iCRM (GBW 04457). The synthetic iCRMs were prepared with ⁷⁶Se, ⁷⁸Se, ⁸⁰Se and ⁸²Se solutions and a natural selenium solution; the natural iCRM was prepared with highly pure selenium material. The property values of isotope ratios in these iCRMs were certified by calibrated mass spectrometry with a collision cell multi‐collector ICP‐MS. The mass discrimination effect of the instrument was corrected with corresponding ⁷⁸Se/⁷⁶Se isotope mixtures and ⁸²Se/⁷⁶Se isotope mixtures, which were gravimetrically prepared with purified, isotopically enriched selenium materials. Homogeneity and stability tests were performed, and no significant influences were found. The uncertainty of the property values of the iCRMs was evaluated according to the Guide to the Expression of Uncertainty in Measurement (GUM) of ISO/BIPM and ISO Guide 35. The δ^82/76Se value of GBW 04457 relative to NIST SRM 3149 was also calculated. These iCRMs are intended for use in calibration of instruments and evaluation of methods for the determination of selenium isotope ratios.  相似文献   

Geological formation and geo-hazards during subway construction in Guangzhou     

Dong-Jie Ren  Shui-Long Shen  Wen-Chieh Cheng  Ning Zhang  Zhi-Feng Wang 《Environmental Earth Sciences》2016,75(11):934

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Ten-year change of total phosphorous pollution in the Min River,an upstream tributary of the Three Gorges Reservoir     

Chunping Ren  Lijing Wang  Binghui Zheng  Jun Qian  Hongjin Ton 《Environmental Earth Sciences》2016,75(12):1015

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Mineralization time and tectonic setting of the Zhengguang Au deposit in the Duobaoshan ore field,Heilongjiang Province,NE China     

Yu-Jie Hao  Yun-Sheng Ren  Ming-Xin Duan  Xuan Zhao  Qun Yang  Kuang-Yin Tong  Chao Li 《Arabian Journal of Geosciences》2016,9(15):655

The Zhengguang deposit, a representative large gold deposit in the Duobaoshan ore field in NE China, is located in the northeast of the Central Asian Orogenic Belt (CAOB). Ore body emplacement was structurally controlled and occurs mainly at the contact zone between the strata of Duobaoshan Formation and an Ordovician diorite stock. The diorite rocks have a close genetic relationship with Au mineralization. Re–Os isotope dating of Au-bearing pyrite yields an isochron age of 506 ± 44 Ma (MSWD = 15). Based on present and previous dating results, it can be concluded that the Zhengguang deposit formed at ~480 Ma. The mineralization time of the Zhengguang deposit is nearly identical to those of the Duobaoshan and Tongshan deposits, indicating they are all derived from the same metallogenic system. The Duobaoshan-style porphyry Cu–Mo mineralization may exist at deeper levels at Zhengguang. The geochemical characteristics of the Zhengguang dioritic rocks presented in this paper are similar to those of bajaitic high-Mg andesite, and the magmas originated from a mantle wedge metasomatized by melts from a subducting oceanic slab at an active continental margin setting. The Ordovician magmatic–metallogenic events in the Duobaoshan ore field were caused by the westward subduction of an oceanic slab located between the Xing’an and Songliao blocks. It is worth pointing out that the Zhengguang deposit is the oldest known Phanerozoic Au deposit in NE China. Further studies of this deposit will improve understanding of the regularity of ore formation and aid mineralization forecast across the Duobaoshan region.  相似文献   

基于无人船的大洋中尺度涡观测系统展望     

范聪慧  于非  南峰  魏传杰  任强 《海洋科学集刊》2016,51(51):49-57

中尺度涡在大洋中普遍存在,研究发现其能量比大尺度海洋环流的能量大一个量级,在海洋物质能量输运和全球气候变化中起着重要的作用。受观测条件限制,目前对中尺度涡的观测主要通过卫星高度计实现,只能从海面高度来推算中尺度涡大小、分布、强度及其伴随的水体和能量输送,而卫星高度计对中尺度涡垂直结构特征认识不足,也导致了对中尺度涡所引起的上层海洋能量、热量输送估计误差偏大。目前对中尺度涡三维结构观测认识不足,展望未来将会出现基于无人船平台的大洋中尺度涡三维结构自动观测系统,该平台将集成自动水下剖面观测功能等先进技术,以便观测中尺度涡的垂直结构特征及其时空变化特征,进而可对中尺度涡带来的物质和能量输送进行系统认识。  相似文献   

Geochemistry and geochronology of Late Jurassic and Early Cretaceous intrusions related to some Au (Sb) deposits in southern Anhui: a case study and review     

Qing Hu  Huangling Gu  Xiaoyong Yang  Yisu Ren  Ergen Gao  Zhangxing Nie 《中国地球化学学报》2018,37(3):360-383

Some Au deposits in southern Anhui Province have recently been found to be closely associated with Late Mesozoic intrusions. Typical examples include the Huashan Au (Sb) deposit and Au deposits at Zhaojialing, Wuxi, and Liaojia. In order to understand the mechanisms that led the formation of these Au deposits, we make detailed reviews on the geological characteristics of these Au deposits. Specifically, we present new LA-ICP-MS zircon U–Pb dating, along with elemental and Hf isotopic data from the Huashan Au (Sb) deposit. Our data suggests that the Huashan ore-related intrusions were emplaced during the Late Jurassic and Early Cretaceous periods (144–148 Ma). They are characterized by arc-magma features and high oxygen fugacity and are rich in inherited zircons. Zircon U–Pb ages and Lu–Hf isotopes from intrusions suggest that Proterozoic juvenile lithosphere is the main source of these intrusions. The regional geological history implies that lithosphere beneath southern Anhui was produced during a Proterozoic subduction and was fertilized with Au (Cu) in the process. Integrated with the results of previous studies, we inferred that Late Mesozoic intrusions formed by the remelting of the lithosphere could provide the metal endowment for the Au-rich deposits in southern Anhui.  相似文献   

Deep electrical structure and its geodynamic significance beneath the Middle and Lower Reaches of the Yangtze River metallogenic belt     

Xianying Wang  Lincheng Zhang  Xiao Xiao  Cong Zhou  Zhengyong Ren  Jingtian Tang 《《地质学报》英文版》2018,92(Z1):335-336

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准噶尔盆地腹部地区生烃增压定量化评价——东道海子北凹陷为例          下载免费PDF全文

于春勇郭小文  任战利任文波 杨桂林 《地质科学》2018,(1):207-220

目前准噶尔盆地腹部地区超压演化过程仅提供了相对时间、概念、定性的认识,并未达到定量化。本文以东道海子北凹陷为例,基于流体包裹体、单井一维和剖面二维烃源岩成熟生烃史模拟技术,采用生烃增压模型定量化评价了侏罗纪八道湾组顶部和底部烃源岩的生烃增压演化过程。研究结果表明侏罗纪八道湾组为东道海子北凹陷主力烃源岩,具有幕式排烃的特点。八道湾组底部烃源岩经历了3 次超压增加和两次超压释放的过程,顶部烃源岩经历了两次超压增加和一次超压释放的过程。八道湾底部烃源岩3 次超压增加的时间分别为距今170～70 Ma、55～23 Ma、10～0 Ma,对应最大压力系数均为2.0,最大剩余流体压力50 MPa,两次超压释放的时间分别为70～55 Ma、23～10 Ma;八道湾组顶部烃源岩两次超压增加的时间分别为130～40 Ma、23～0 Ma,对应流体最大压力系数最大亦可达2.0 左右,最大剩余流体压力44 MPa,超压释放的时间为40～23 Ma。  相似文献   

基于GIPL2模型的青藏高原活动层土壤热状况模拟研究   总被引：5，自引：5，他引：0  

秦艳慧  吴通华  李韧  胡国杰  乔永平  朱小凡  杨淑华  余文君  王蔚华 《冰川冻土》2018,40(6):1153-1166

青藏高原活动层土壤热状况,对深入了解高原活动层的厚度变化特征、下垫面的热力作用以及对气候变化预测均有重要意义。利用GIPL2模型模拟青藏高原多年冻土区不同植被状况下活动层土壤热状况。模拟结果表明：模型在高寒草原（QT06）试验点模拟效果较好,高寒沼泽草甸（QT03）试验点的模拟效果较差,高寒草甸（QT01）、高寒荒漠草原（QT05）和高寒草原化草甸（QT04）试验点的模拟效果介于高寒草原试验点和高寒沼泽草甸试验点之间。QT01、QT03、QT04、QT05和QT06的土壤温度模拟值与观测值相比,均方根误差分别为0.67、1.29、0.73、0.7和0.56℃;相关系数分别为0.99、0.87、0.98、0.98和0.96;平均误差分别为0.37、0.61、0.31、0.45和0.16℃。QT06模拟结果较好,原因在于此点土壤质地变化不大,模型的分层与所取的参数更加接近此点的实际状况。QT03模拟结果较差,可能由于此地区土壤中存在砾石,在导热率参数化方案中没有考虑砾石含量,导致模拟结果偏差较大。总体而言,GIPL2模型对青藏高原活动层土壤热状况的模拟具有一定的优势,是一种模拟多年冻土区活动层土壤热状况较为理想的模型。  相似文献   

长春地区粉质黏土导热系数与其物性参数相关性研究     

姚仁  杜立志  吕守航  沈明燮 《世界地质》2018,37(3):976-981

为研究导热系数与影响因素之间的相关关系,建立导热系数的推算公式,以长春地区粉质黏土为研究对象,对原状土样的导热系数与其物理参数之间的相关性进行回归分析。制作9个重塑土样,测其相关的参数值,以验证回归方程的适用性。结果表明,回归分析建立导热系数与2个物理参数之间的关系式不成立;考虑天然密度、含水率和孔隙度为自变量,其分别对应的相关性系数T检验显著值(Sig)都0. 05,复决定系数为0. 886,建立的回归方程成立,自变量能准确解释因变量的变化,且含水率与导热系数呈负相关,天然密度和孔隙度呈正相关。重塑土样相关参数代入回归方程得到的导热系数值与实验实测值之间相对误差低于4%,验证了该回归方程的普遍性和适用性。  相似文献